scholarly journals Complex transition metal hydrides incorporating ionic hydrogen: thermal decomposition pathway of Na2Mg2FeH8 and Na2Mg2RuH8

2015 ◽  
Vol 17 (12) ◽  
pp. 8276-8282 ◽  
Author(s):  
Terry D. Humphries ◽  
Motoaki Matsuo ◽  
Guanqiao Li ◽  
Shin-ichi Orimo
Keyword(s):  
Thermal Decomposition ◽  
Transition Metal ◽  
Metal Hydrides ◽  
Decomposition Step ◽  
Transition Metal Hydrides ◽  
Enthalpy And Entropy ◽  
Decomposition Pathway

The optimised syntheses of Na2Mg2FeH8 and Na2Mg2RuH8 are reported and their thermal decomposition pathways established. The enthalpy and entropy of each decomposition step has been determined by PCI measurements.

scholarly journals Complex transition metal hydrides: linear correlation of countercation electronegativity versus T–D bond lengths

2015 ◽  
Vol 51 (56) ◽  
pp. 11248-11251 ◽  
Author(s):  
T. D. Humphries ◽  
D. A. Sheppard ◽  
C. E. Buckley
Keyword(s):  
Transition Metal ◽  
Bond Length ◽  
Linear Correlation ◽  
Metal Hydrides ◽  
Bond Lengths ◽  
Transition Metal Hydrides ◽  
Complex Hydrides

For homoleptic 18-electron complex hydrides, an inverse linear correlation has been established between the T–deuterium bond length and the average electronegativity of the metal countercations.

Kinetic hydricity of transition-metal hydrides toward trityl cation

1995 ◽  
Vol 14 (9) ◽  
pp. 4031-4033 ◽  
Author(s):  
Tan-Yun Cheng ◽  
R. Morris Bullock
Keyword(s):  
Transition Metal ◽  
Metal Hydrides ◽  
Transition Metal Hydrides ◽  
Trityl Cation

Positive ions of the first‐ and second‐row transition metal hydrides

1987 ◽  
Vol 87 (1) ◽  
pp. 481-492 ◽  
Author(s):  
Lars G. M. Pettersson ◽  
Charles W. Bauschlicher ◽  
Stephen R. Langhoff ◽  
Harry Partridge
Keyword(s):  
Transition Metal ◽  
Metal Hydrides ◽  
Transition Metal Hydrides ◽  
Positive Ions

The Formation and Properties of Rare-Earth and Transition Metal Hydrides

1975 ◽  
pp. 659-674 ◽  
Author(s):  
L. C. Beavis ◽  
R. S. Blewer ◽  
J. W. Guthrie ◽  
E. J. Nowak ◽  
W. G. Perkins
Keyword(s):  
Rare Earth ◽  
Transition Metal ◽  
Metal Hydrides ◽  
Transition Metal Hydrides

Addition of acrylonitrile to anionic transition metal hydrides. An ionic model for homogeneous olefin processes

1989 ◽  
Vol 30 (14) ◽  
pp. 1781-1784 ◽  
Author(s):  
Marcetta Y. Darensbourg ◽  
Barbara Floris ◽  
Kay A. Youngdahl
Keyword(s):  
Transition Metal ◽  
Metal Hydrides ◽  
Ionic Model ◽  
Transition Metal Hydrides

scholarly journals Hydricity of Transition-Metal Hydrides: Thermodynamic Considerations for CO2 Reduction

ACS Catalysis ◽  
2018 ◽  
Vol 8 (2) ◽  
pp. 1313-1324 ◽  
Author(s):  
Kate M. Waldie ◽  
Andrew L. Ostericher ◽  
Mark H. Reineke ◽  
Alissa F. Sasayama ◽  
Clifford P. Kubiak
Keyword(s):  
Transition Metal ◽  
Co2 Reduction ◽  
Metal Hydrides ◽  
Transition Metal Hydrides
Sign in / Sign up

Export Citation Format

Share Document