Electrochemical and physicochemical properties of small phosphonium cation ionic liquid electrolytes with high lithium salt content

2015 ◽  
Vol 17 (14) ◽  
pp. 8706-8713 ◽  
Author(s):  
G. M. A. Girard ◽  
M. Hilder ◽  
H. Zhu ◽  
D. Nucciarone ◽  
K. Whitbread ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Physicochemical Properties ◽  
Lithium Battery ◽  
Lithium Salt ◽  
Salt Content ◽  
Potential Candidate ◽  
Liquid Electrolytes ◽  
Phosphonium Ionic Liquid

A novel phosphonium ionic liquid as potential candidate for lithium battery electrolytes.

scholarly journals Modeling and Simulation in Capacity Degradation and Control of All-Solid-State Lithium Battery Based on Time-Aging Polymer Electrolyte

Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1206
Author(s):  
Xuansen Fang ◽  
Yaolong He ◽  
Xiaomin Fan ◽  
Dan Zhang ◽  
Hongjiu Hu
Keyword(s):  
Solid State ◽  
Lithium Battery ◽  
Lithium Salt ◽  
Operating Temperature ◽  
Discharge Rate ◽  
Salt Content ◽  
Lithium Ion ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Capacity Degradation

The prediction of electrochemical performance is the basis for long-term service of all-solid-state-battery (ASSB) regarding the time-aging of solid polymer electrolytes. To get insight into the influence mechanism of electrolyte aging on cell fading, we have established a continuum model for quantitatively analyzing the capacity evolution of the lithium battery during the time-aging process. The simulations have unveiled the phenomenon of electrolyte-aging-induced capacity degradation. The effects of discharge rate, operating temperature, and lithium-salt concentration in the electrolyte, as well as the electrolyte thickness, have also been explored in detail. The results have shown that capacity loss of ASSB is controlled by the decrease in the contact area of the electrolyte/electrode interface at the initial aging stage and is subsequently dominated by the mobilities of lithium-ion across the aging electrolyte. Moreover, reducing the discharge rate or increasing the operating temperature can weaken this cell deterioration. Besides, the thinner electrolyte film with acceptable lithium salt content benefits the durability of the ASSB. It has also been found that the negative effect of the aging electrolytes can be relieved if the electrolyte conductivity is kept being above a critical value under the storage and using conditions.

Additive-containing ionic liquid electrolytes for secondary lithium battery

2006 ◽  
Vol 160 (1) ◽  
pp. 621-626 ◽  
Author(s):  
Jinqiang Xu ◽  
Jun Yang ◽  
Yanna NuLi ◽  
Jiulin Wang ◽  
Zongshuang Zhang
Keyword(s):  
Ionic Liquid ◽  
Lithium Battery ◽  
Liquid Electrolytes ◽  
Secondary Lithium Battery

N-Alkyl-N-ethylpyrrolidinium cation-based ionic liquid electrolytes for safer lithium battery systems

2016 ◽  
Vol 191 ◽  
pp. 624-630 ◽  
Author(s):  
Judith Serra Moreno ◽  
Yuki Deguchi ◽  
Stefania Panero ◽  
Bruno Scrosati ◽  
Hiroyuki Ohno ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Lithium Battery ◽  
Liquid Electrolytes ◽  
Battery Systems

Molecular Environment and Enhanced Diffusivity of Li+ Ions in Lithium-Salt-Doped Ionic Liquid Electrolytes

2011 ◽  
Vol 2 (3) ◽  
pp. 153-157 ◽  
Author(s):  
Franca Castiglione ◽  
Enzio Ragg ◽  
Andrea Mele ◽  
Giovanni Battista Appetecchi ◽  
Maria Montanino ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Lithium Salt ◽  
Liquid Electrolytes

scholarly journals Impact of Lithium Salt Addition to Ionic Liquid Electrolytes for High-performance Electric Double-layer Capacitors

2013 ◽  
Vol 81 (10) ◽  
pp. 857-862 ◽  
Author(s):  
Masaki YAMAGATA ◽  
Masaya HIRAYAMA ◽  
Satoshi NISHISHITA ◽  
Daisuke HORIKAWA ◽  
Masashi ISHIKAWA
Keyword(s):  
Ionic Liquid ◽  
Double Layer ◽  
Electric Double Layer ◽  
High Performance ◽  
Lithium Salt ◽  
Liquid Electrolytes ◽  
Salt Addition ◽  
Double Layer Capacitors ◽  
Electric Double Layer Capacitors

Properties and application of ether-functionalized trialkylimidazolium ionic liquid electrolytes for lithium battery

2013 ◽  
Vol 226 ◽  
pp. 210-218 ◽  
Author(s):  
Yide Jin ◽  
Shaohua Fang ◽  
Ming Chai ◽  
Li Yang ◽  
Kazuhiro Tachibana ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Lithium Battery ◽  
Liquid Electrolytes

Mechanisms of Ion Transport in Lithium Salt-Doped Polymeric Ionic Liquid Electrolytes

2020 ◽  
Vol 53 (16) ◽  
pp. 6995-7008 ◽  
Author(s):  
Zidan Zhang ◽  
Amir T. Nasrabadi ◽  
Dipak Aryal ◽  
Venkat Ganesan
Keyword(s):  
Ionic Liquid ◽  
Ion Transport ◽  
Lithium Salt ◽  
Polymeric Ionic Liquid ◽  
Liquid Electrolytes
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