Influence of halogen substitutions on rates of charge tunneling across SAM-based large-area junctions

2015 ◽  
Vol 17 (21) ◽  
pp. 13804-13807 ◽  
Author(s):  
Gyu Don Kong ◽  
Miso Kim ◽  
Hyeon-Jae Jang ◽  
Kung-Ching Liao ◽  
Hyo Jae Yoon

The role of halogenation in charge transport across molecular junctions was investigated.

2020 ◽  
Vol 12 (3) ◽  
pp. 333-336
Author(s):  
Jungmoon Lim ◽  
Gahyun Ahn ◽  
Inho Jeong ◽  
Hyunwook Song

We report on the temperature-dependent transport behaviors of large-area molecular junctions fabricated with poly-(3,4-ethylene-dioxythiophene) stabilized with polystyrene sulphonic acid (PEDOT:PSS) interlayer electrodes and the archetypal benzenethiol molecules. In this study, we investigated two different benzenethiol molecules: 4-methylbenzenethiol (MBT) and 1,4-benzenedithiol (BDT), which have the identical backbone structure but different top end-groups. The charge transport through the molecular junctions was dominated by distinct interfacial contact properties between the PEDOT:PSS electrodes and the component molecules. We also observed that the electrical characteristics of the MBT junctions are influenced by the PEDOT grain size, particularly depending on the annealing temperature.


Small ◽  
2011 ◽  
Vol 7 (11) ◽  
pp. 1593-1598 ◽  
Author(s):  
Auke J. Kronemeijer ◽  
Ilias Katsouras ◽  
Eek H. Huisman ◽  
Paul A. van Hal ◽  
Tom C. T. Geuns ◽  
...  

Nanoscale ◽  
2013 ◽  
Vol 5 (20) ◽  
pp. 9882 ◽  
Author(s):  
Ilias Katsouras ◽  
Claudia Piliego ◽  
Paul W. M. Blom ◽  
Dago M. de Leeuw

2018 ◽  
Vol 20 (7) ◽  
pp. 4864-4878 ◽  
Author(s):  
Jiahao Chen ◽  
Thomas J. Giroux ◽  
Yen Nguyen ◽  
Atte A. Kadoma ◽  
Boyce S. Chang ◽  
...  

Charge transport across large area molecular tunneling junctions is widely studied due to its potential in the development of quantum electronic devices.


2018 ◽  
Vol 140 (38) ◽  
pp. 12303-12307 ◽  
Author(s):  
Gyu Don Kong ◽  
Junji Jin ◽  
Martin Thuo ◽  
Hyunsun Song ◽  
Joonyoung F. Joung ◽  
...  

2010 ◽  
Vol 114 (37) ◽  
pp. 15806-15815 ◽  
Author(s):  
Adam Johan Bergren ◽  
Richard L. McCreery ◽  
Stanislav R. Stoyanov ◽  
Sergey Gusarov ◽  
Andriy Kovalenko

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