Functional shakeup of metal–organic frameworks: the rise of the sidekick

CrystEngComm ◽  
2015 ◽  
Vol 17 (48) ◽  
pp. 9254-9263 ◽  
Author(s):  
Jun He ◽  
Matthias Zeller ◽  
Allen D. Hunter ◽  
Zhengtao Xu
Keyword(s):  
Solid State ◽  
Metal Organic Frameworks ◽  
Strong Binding ◽  
Metal Organic ◽  
Solid State Materials

The ever more versatile side groups, from labile weak donors to strong-binding thiol and dendritic functions, sulfur-enabled framework chemistry heralds a rising trend in the design of solid-state materials.

Metal-Organic Frameworks: An Emerging Class of Solid-State Materials

2017 ◽  
pp. 165-193 ◽  
Author(s):  
Joseph E. Mondloch ◽  
Rachel C. Klet ◽  
Ashlee J. Howarth ◽  
Joseph T. Hupp ◽  
Omar K. Farha
Keyword(s):  
Solid State ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Solid State Materials

scholarly journals Spectroelectrochemistry: A Powerful Tool for Studying Fundamental Properties and Emerging Applications of Solid-State Materials Including Metal–Organic Frameworks

2021 ◽  
Vol 74 (2) ◽  
pp. 77
Author(s):  
Deanna M. D'Alessandro ◽  
Pavel M. Usov
Keyword(s):  
Solid State ◽  
Near Infrared ◽  
Metal Organic Frameworks ◽  
Fundamental Property ◽  
Paramagnetic Resonance ◽  
Fundamental Properties ◽  
Metal Organic ◽  
Solid State Materials ◽  
X Ray Absorption

Spectroelectrochemistry (SEC) encompasses a broad suite of electroanalytical techniques where electrochemistry is coupled with various spectroscopic methods. This powerful and versatile array of methods is characterised as in situ, where a fundamental property is measured in real time as the redox state is varied through an applied voltage. SEC has a long and rich history and has proved highly valuable for discerning mechanistic aspects of redox reactions that underpin the function of biological, chemical, and physical systems in the solid and solution states, as well as in thin films and even in single molecules. This perspective article highlights the state of the art in solid-state SEC (ultraviolet–visible–near-infrared, infrared, Raman, photoluminescence, electron paramagnetic resonance, and X-ray absorption spectroscopy) relevant to interrogating solid state materials, particularly those in the burgeoning field of metal–organic frameworks (MOFs). Emphasis is on developments in the field over the past 10 years and prospects for application of SEC techniques to probing fundamental aspects of MOFs and MOF-derived materials, along with their emerging applications in next-generation technologies for energy storage and transformation. Along with informing the already expert practitioner of SEC, this article provides some guidance for researchers interested in entering the field.

Rational strategies for proton-conductive metal–organic frameworks

2021 ◽  
Author(s):  
Dae-Woon Lim ◽  
Hiroshi Kitagawa
Keyword(s):  
Solid State ◽  
Potential Application ◽  
High Performance ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Solid State Electrolytes

Since the transition of energy platforms, the proton-conductive metal–organic frameworks (MOFs) exhibiting high performance have been extensively investigated with rational strategies for their potential application in solid-state electrolytes.

Photoactive Zr and Ti Metal‐Organic‐Frameworks for solid‐state solar cells

ChemPhysChem ◽  
2021 ◽  
Author(s):  
Arianna Melillo ◽  
Rocio Garcia ◽  
Sergio Navalon ◽  
Pedro Atienzar ◽  
Belen Ferrer ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solid State ◽  
Metal Organic Frameworks ◽  
Metal Organic

scholarly journals Mechanochemical and solvent-free assembly of zirconium-based metal–organic frameworks

2016 ◽  
Vol 52 (10) ◽  
pp. 2133-2136 ◽  
Author(s):  
Krunoslav Užarević ◽  
Timothy C. Wang ◽  
Su-Young Moon ◽  
Athena M. Fidelli ◽  
Joseph T. Hupp ◽  
...  
Keyword(s):  
Solid State ◽  
High Temperatures ◽  
Self Assembly ◽  
Metal Organic Frameworks ◽  
Accelerated Aging ◽  
Solvent Free ◽  
Catalytically Active ◽  
Metal Organic ◽  
Strong Acids ◽  
Zirconium Metal

Mechanochemistry and accelerated aging are new routes to zirconium metal–organic frameworks, yielding UiO-66 and catalytically active UiO-66-NH2 accessible on the gram scale through mild solid-state self-assembly, without strong acids, high temperatures or excess reactants.

Phosphorization Engineering on Metal–Organic Frameworks for Quasi‐Solid‐State Asymmetry Supercapacitors

Small ◽  
2020 ◽  
pp. 2007062
Author(s):  
Xijun Wei ◽  
Yingze Song ◽  
Lixian Song ◽  
Xu Dong Liu ◽  
Yanhong Li ◽  
...  
Keyword(s):  
Solid State ◽  
Metal Organic Frameworks ◽  
Metal Organic

Tuning the electrochemical and catalytic ORR performance of C60 by its encapsulation in ZIF-8: a solid-state analogue of dilute fullerene solution

2021 ◽  
Vol 5 (20) ◽  
pp. 7654-7665
Author(s):  
Olivia Basu ◽  
Subhabrata Mukhopadhyay ◽  
Avik De ◽  
Anupam Das ◽  
Samar K. Das
Keyword(s):  
Solid State ◽  
Active Sites ◽  
Metal Organic Frameworks ◽  
Electrochemical Activity ◽  
High Density ◽  
Fullerene Solution ◽  
Metal Organic ◽  
Significant Attention

Hassle-free encapsulation of fullerene C60 in ZIF-8 has been performed to preserve the molecularity and solution-like properties of C60 in solid-state. The resulting composite shows efficient heterogeneous electrocatalytic oxygen reduction reaction.

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