Tailoring the photocatalytic activity of layered perovskites by opening the interlayer vacancy via ion-exchange reactions

CrystEngComm ◽  
2015 ◽  
Vol 17 (45) ◽  
pp. 8703-8709 ◽  
Author(s):  
Yingqi Wang ◽  
Xiaofang Lai ◽  
Xujie Lü ◽  
Yanting Li ◽  
Qinglong Liu ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Ion Exchange ◽  
Exchange Reaction ◽  
Underlying Mechanism ◽  
Effective Model ◽  
Layered Perovskite ◽  
Exchange Reactions ◽  
Ion Exchange Reaction ◽  
Improved Performance ◽  
Layered Perovskites

The photocatalytic activity of the layered perovskite K2La2Ti3O10 was regulated by an ion-exchange reaction with a series of cations – Ca2+, Sr2+, and Ba2+. The underlying mechanism of the improved performance and an effective model for designing the photocatalyst were discussed.

scholarly journals Possibility of Superconductivity in a Layered Perovskite Niobate, KCa2Nb3O10, Synthesized by an Ion Exchange Reaction

2006 ◽  
Vol 114 (1334) ◽  
pp. 861-865 ◽  
Author(s):  
Sachi TAKEZAWA ◽  
Takashi TERANISHI ◽  
Hironori ISHIKAWA ◽  
Toshiaki TOKUMITSU ◽  
Kenji TODA ◽  
...  
Keyword(s):  
Ion Exchange ◽  
Exchange Reaction ◽  
Layered Perovskite ◽  
Ion Exchange Reaction

Facile Hydrothermal-Ion-Exchange Synthesis and Enhanced Visible Light Photocatalytic Activity of Bi4Ti3O12/Bi2S3 Heterostructure

NANO ◽  
2018 ◽  
Vol 13 (01) ◽  
pp. 1850012 ◽  
Author(s):  
Na Cao ◽  
Huiling Du ◽  
Jun Liu ◽  
Lianli Wang
Keyword(s):  
Photocatalytic Activity ◽  
Ion Exchange ◽  
Visible Light ◽  
Exchange Reaction ◽  
Sol Gel ◽  
Practical Application ◽  
Visible Light Photocatalytic Activity ◽  
Ion Exchange Reaction ◽  
Excellent Property ◽  
Visible Light Photocatalytic

Bi4Ti3O[Formula: see text]/Bi2S3 heterostructures with enhanced visible light photocatalytic activity are successfully synthesized via a two-step synthesis route based on a sol–gel hydrothermal method and a subsequent hydrothermal-ion exchange reaction technique. The structures, composition, morphologies and light absorption capability of Bi4Ti3O[Formula: see text]/Bi2S3 heterostructures are verified by XRD, XPS, SEM, TEM and UV-Vis diffuse reflectance spectra, respectively. Results indicated that Bi2S3 nanorods are grown on the surface of the spherical structure assembled by criss-cross nanosheets of Bi4Ti3O[Formula: see text] after ion exchange reaction. The photocatalytic tests reveal that the Bi4Ti3O[Formula: see text]/Bi2S3 heterostructures showed much higher photocatalytic activity than pure Bi4Ti3O[Formula: see text] or Bi2S3. The tight interconnection between the two semiconductors will facilitate the photoinduced carriers’ separation. Owing to the easy preparation and excellent property, the obtained Bi4Ti3O[Formula: see text]/Bi2S3 heterostructures may be promising photocatalysts for practical application.

scholarly journals Thermodynamics of Uni-Univalent H+/K+ and Uni-Bivalent H+/Ca2+ Ion Exchange Reactions Using Nuclear Grade Resin Indion-223

2014 ◽  
Vol 33 ◽  
pp. 190-198
Author(s):  
Pravin U. Singare ◽  
Akmal L. Khan Mohammed ◽  
N.N. Dixit
Keyword(s):  
Ion Exchange ◽  
Exchange Reaction ◽  
Exchange Resin ◽  
Anion Exchange Resin ◽  
Equilibrium Constants ◽  
Ionic Species ◽  
Nuclear Grade ◽  
Exchange Reactions ◽  
Efficient Separation ◽  
Ion Exchange Reaction

The present paper deals with the thermodynamic of uni-univalent and uni-bivalent ion exchange reactions using nuclear grade anion exchange resin Indion-223. It was observed that with rise in temperature the equilibrium constants K values for H+/K+ uni-univalet ion exchange reaction increases from 0.01710 to 0.02374. Similarly for H+/Ca2+ uni-bivalet ion exchange reaction the equilibrium constants K values increases from 0.000397 to 0.000639. The increase in K values with rise in temperature for both the reactions indicates its endothermic nature having the enthalpy change values of 22.72 and 38.92 kJ/ mol respectively. The technique used here can be extended further to standardise the process parameters in order to bring about the efficient separation of the desired ionic species from the solution

scholarly journals Study on Halide Ions Selectivity of Industrial Grade Anion Exchange Resin Auchlite A-378

2014 ◽  
Vol 30 ◽  
pp. 44-50 ◽  
Author(s):  
P.U. Singare ◽  
A.N. Patange
Keyword(s):  
Ion Exchange ◽  
Exchange Reaction ◽  
Anion Exchange ◽  
Exchange Resin ◽  
Anion Exchange Resin ◽  
Equilibrium Constants ◽  
Exchange Reactions ◽  
Ion Exchange Reaction ◽  
Industrial Grade ◽  
Bromide Ions

The thermodynamic approach was applied to predict the trend selectivity of industrial grade anion exchange resin Auchlite A-378 in chloride form towards iodide and bromide ions in the solution. The study was conducted by performing the Clˉ/Iˉ and Clˉ/Brˉ uni-univalent ion exchange reactions under gradually increasing temperature conditions. The thermodynamic equilibrium constants K values were used to calculate the enthalpies of the two uni-univalent ion exchange reactions. It was observed that the K values for Clˉ/Iˉ ion exchange reaction were higher than Clˉ/Brˉ exchange reaction under identical experimental conditions. Also the enthalpy values for the two uni-univalent ion exchange reactions were calculated as -39.51 and -18.38 kJ/mol respectively. The high K and low enthalpy values obtained for Clˉ/Iˉ ion exchange reaction is responsible for higher selectivity of the resin towards iodide ions as compared to that towards bromide ions, when both the ions are present in the same solution.

scholarly journals Thermodynamics of Ion-Exchange Reaction in Predicting the Ionic Selectivity of Auchlite ARA-9366 and Auchlite A-378 Anion Exchange Resins

2014 ◽  
Vol 25 ◽  
pp. 1-7 ◽  
Author(s):  
P.U. Singare ◽  
A.N. Patange
Keyword(s):  
Ion Exchange ◽  
Exchange Reaction ◽  
Anion Exchange ◽  
Ion Selectivity ◽  
Exchange Reactions ◽  
Ionic Selectivity ◽  
Iodide Ions ◽  
Ion Exchange Reaction ◽  
Anion Exchange Resins ◽  
Exchange Resins

The paper deals with predicting the iodide ion selectivity of nuclear and non-nuclear grade anion exchange resins. The ionic selectivity prediction was made on the basis of thermodynamic data of Clˉ/I ˉ ion exchange reaction. It was observed that with rise in temperature from 30.0°C to 45.0 °C, the equilibrium constant (K) values were observed to decreases from 59.77x10-2 to 23.77x10-2 for Auchlite ARA-9366 resins and from 9.01x10-2 to 4.05x10-2 for Auchlite A-378 resins. The decrease in K values with rise in temperature, indicate exothermic ion exchange reactions having enthalpy values of -47.87 and -39.51 kJ/mol respectively. The high K and low enthalpy values obtained for Auchlite ARA-9366 resins indicate their greater selectivity for the iodide ions in the solution as compared to Auchlite A-378 resins, when both the resins are present in chloride form.

Self-Assembly of Perovskite Nanosheet Colloid at Room Temperature

2006 ◽  
Vol 301 ◽  
pp. 227-230
Author(s):  
Kenji Toda ◽  
Hiroki Sato ◽  
Akira Sugawara ◽  
Saori Tokuoka ◽  
Kazuyoshi Uematsu ◽  
...  
Keyword(s):  
Ion Exchange ◽  
Exchange Reaction ◽  
Self Assembly ◽  
Room Temperature ◽  
Spectroscopic Studies ◽  
Layered Perovskite ◽  
X Ray Diffraction ◽  
X Ray ◽  
Ion Exchange Reaction ◽  
Perovskite Materials

We present a new method for soft chemical synthesis of perovskite materials. Perovskite K1-xLixNbO3 powders are produced by an ion-exchange reaction of layered perovskite precursor, K2NbO3F, with lithium chloride in water at room temperature. X-ray diffraction and X-ray fluorescent spectroscopic studies show that a mechanism of the ion-exchange reaction is a self-assembly between the perovskite nanosheets in aqueous solution.

Synthesis of (H3O)TiNbO5·0.26H2O via hydronium (H3O+) ion-exchange reaction and its photocatalytic activity for H2 evolution from aqueous methanol solution

2000 ◽  
Vol 2 (19) ◽  
pp. 4461-4464 ◽  
Author(s):  
Hiroyuki Takahashi ◽  
Masato Kakihana ◽  
Yohichi Yamashita ◽  
Kiyohide Yoshida ◽  
Sigeru Ikeda ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Ion Exchange ◽  
Exchange Reaction ◽  
Methanol Solution ◽  
H2 Evolution ◽  
Aqueous Methanol ◽  
Ion Exchange Reaction

scholarly journals Comparative Study of Uni-Univalent H+/Na+ and Uni-Bivalent H+/Ca2+ Ion Exchange Reactions Using Nuclear Grade Resin Indion-223

2014 ◽  
Vol 33 ◽  
pp. 127-135
Author(s):  
Pravin U. Singare ◽  
Akmal L. Khan Mohammed ◽  
N.N. Dixit
Keyword(s):  
Ion Exchange ◽  
Exchange Reaction ◽  
Exchange Resin ◽  
Anion Exchange Resin ◽  
Equilibrium Constants ◽  
Nuclear Grade ◽  
Exchange Equilibrium ◽  
Exchange Reactions ◽  
Equilibrium Studies ◽  
Ion Exchange Reaction

The present paper deals with the ion exchange equilibrium studies of uni-univalent and uni-bivalent ion exchange reactions using nuclear grade anion exchange resin Indion-223 in H+ form towards Na+ and Ca2+ ions in the solution. It was observed that with rise in temperature the equilibrium constants K values for H+/Na+ uni-univalet ion exchange reaction increases from 0.01389 to 0.01855. Similarly for H+/Ca2+ uni-bivalet ion exchange reaction the equilibrium constants K values increases from 0.000397 to 0.000639. The increase in equilibrium constant values with rise in temperature indicate endothermic ion exchange reactions having the enthalpy change values of 25.55 and 38.92 kJ/ mol respectively.

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