Copper-catalyzed, hypervalent iodine mediated CC bond activation of enaminones for the synthesis of α-keto amides

2016 ◽  
Vol 52 (6) ◽  
pp. 1270-1273 ◽  
Author(s):  
Jie-Ping Wan ◽  
Yunfang Lin ◽  
Xiaoji Cao ◽  
Yunyun Liu ◽  
Li Wei
Keyword(s):  
Double Bond ◽  
Bond Activation ◽  
Hypervalent Iodine ◽  
General Synthesis

An unprecedented approach toward the general synthesis of α-keto amides has been established by tailoring the CC double bond of enaminones in the presence of CuI and hypervalent iodine.

Hypervalent Iodine Mediated C–C Double Bond Activation: A Cascade Access to α-Keto Diacetates from Readily Available Cinnamic Acids

Synthesis ◽  
2015 ◽  
Vol 47 (19) ◽  
pp. 2924-2930 ◽  
Author(s):  
Yunfei Du ◽  
Kang Zhao ◽  
Le Liu ◽  
Daisy Zhang-Negrerie
Keyword(s):  
Double Bond ◽  
Bond Activation ◽  
Hypervalent Iodine ◽  
Cinnamic Acids

scholarly journals Iodine(III)-mediated halogenations of acyclic monoterpenoids

2018 ◽  
Vol 14 ◽  
pp. 1103-1111 ◽  
Author(s):  
Laure Peilleron ◽  
Tatyana D Grayfer ◽  
Joëlle Dubois ◽  
Robert H Dodd ◽  
Kevin Cariou
Keyword(s):  
Double Bond ◽  
Hypervalent Iodine ◽  
Halide Salt ◽  
Trisubstituted Double Bond ◽  
Excellent Selectivity

Five different halofunctionalizations of acyclic monoterpenoids were performed using a combination of a hypervalent iodine(III) reagent and a halide salt. In this manner, the dibromination, the bromo(trifluoro)acetoxylation, the bromohydroxylation, the iodo(trifluoro)acetoxylation or the ene-type chlorination of the distal trisubstituted double bond occurred with excellent selectivity and moderate to good yields.

The IX (X=O,N,C) Double Bond in Hypervalent Iodine Compounds: Is it Real?

2014 ◽  
Vol 53 (36) ◽  
pp. 9617-9621 ◽  
Author(s):  
Alexander S. Ivanov ◽  
Ivan A. Popov ◽  
Alexander I. Boldyrev ◽  
Viktor V. Zhdankin
Keyword(s):  
Double Bond ◽  
Hypervalent Iodine ◽  
Iodine Compounds

Metal-Free CH Bond Activation of Branched Aldehydes with a Hypervalent Iodine(III) Catalyst under Visible-Light Photolysis: Successful Trapping with Electron-Deficient Olefins

2014 ◽  
Vol 126 (41) ◽  
pp. 11240-11244 ◽  
Author(s):  
Shin A. Moteki ◽  
Asuka Usui ◽  
Sermadurai Selvakumar ◽  
Tiexin Zhang ◽  
Keiji Maruoka
Keyword(s):  
Visible Light ◽  
Bond Activation ◽  
Hypervalent Iodine ◽  
Metal Free

scholarly journals Correction: Copper-catalyzed, hypervalent iodine mediated CC bond activation of enaminones for the synthesis of α-keto amides

2016 ◽  
Vol 52 (23) ◽  
pp. 4393-4393 ◽  
Author(s):  
Jie-Ping Wan ◽  
Yunfang Lin ◽  
Xiaoji Cao ◽  
Yunyun Liu ◽  
Li Wei
Keyword(s):  
Bond Activation ◽  
Hypervalent Iodine

Correction for ‘Copper-catalyzed, hypervalent iodine mediated CC bond activation of enaminones for the synthesis of α-keto amides’ by Jie-Ping Wan et al., Chem. Commun., 2016, 52, 1270–1273.

ChemInform Abstract: Copper-Catalyzed, Hypervalent Iodine Mediated C=C Bond Activation of Enaminones for the Synthesis of α-Keto Amides.

ChemInform ◽  
2016 ◽  
Vol 47 (19) ◽  
Author(s):  
Jie-Ping Wan ◽  
Yunfang Lin ◽  
Xiaoji Cao ◽  
Yunyun Liu ◽  
Li Wei
Keyword(s):  
Bond Activation ◽  
Hypervalent Iodine
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