Elucidation of the resting state of a rhodium NNN-pincer hydrogenation catalyst that features a remarkably upfield hydride 1H NMR chemical shift

2016 ◽  
Vol 52 (3) ◽  
pp. 586-589 ◽  
Author(s):  
Mikko M. Hänninen ◽  
Matthew T. Zamora ◽  
Connor S. MacNeil ◽  
Jackson P. Knott ◽  
Paul G. Hayes

Rhodium(i) alkene complexes of an NNN-pincer ligand catalyze the hydrogenation of alkenes. The terminal or resting state of the catalyst, which exhibits an unusually upfield Rh–hydride 1H NMR chemical shift, has been identified.

2007 ◽  
Vol 316 (1) ◽  
pp. 31-36 ◽  
Author(s):  
Cristiano Andrade-Dias ◽  
Sérgio Lima ◽  
José J.C. Teixeira-Dias

1991 ◽  
Vol 30 (5) ◽  
pp. 1683-1689 ◽  
Author(s):  
Satoshi Tahara ◽  
John L. Ingham ◽  
Fujinori Hanawa ◽  
Junya Mizutani

2017 ◽  
Vol 676 ◽  
pp. 46-52 ◽  
Author(s):  
Leonardo A. De Souza ◽  
Wagner M.G. Tavares ◽  
Ana Paula M. Lopes ◽  
Malucia M. Soeiro ◽  
Wagner B. De Almeida

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