High-rate performance of a mixed olivine cathode with off-stoichiometric composition

2015 ◽  
Vol 51 (68) ◽  
pp. 13279-13282 ◽  
Author(s):  
Jae Chul Kim ◽  
Xin Li ◽  
Byoungwoo Kang ◽  
Gerbrand Ceder

By controlling off-stoichiometry, LiFe0.6Mn0.4PO4 with non-crystalline surface phases is formed, enabling the material to achieve high power density.

2015 ◽  
Vol 3 (22) ◽  
pp. 11807-11816 ◽  
Author(s):  
Marco Secchiaroli ◽  
Gabriele Giuli ◽  
Bettina Fuchs ◽  
Roberto Marassi ◽  
Margret Wohlfahrt-Mehrens ◽  
...  

Nanostructured Li3V2−xNix(PO4)3 (x = 0, 0.05, and 0.1) cathodes, thanks to their high rate capability and excellent cycle stability, are proposed as excellent candidates for the development of high energy and high power density Li-ion asymmetric supercapacitors.


RSC Advances ◽  
2018 ◽  
Vol 8 (23) ◽  
pp. 12701-12707 ◽  
Author(s):  
Sikan Peng ◽  
Shaojiu Yan ◽  
Nan Wang ◽  
Wenzheng Nan ◽  
Jixian Wang ◽  
...  

Fluorinated graphene (FG)/sulfur hybrid cathode with monoclinic sulfur enables the lithium primary battery exhibiting excellent capacity and rate performance.


Nanoscale ◽  
2019 ◽  
Vol 11 (18) ◽  
pp. 8882-8897 ◽  
Author(s):  
Akshay Kumar Budumuru ◽  
Benadict Rakesh ◽  
Chandran Sudakar

Defects in MoS2 nanosheets improve the rate capability and cycling stability in the intercalation regime. Li adsorbed at defect sites facilitates a high power density.


1978 ◽  
Vol 33 (11) ◽  
pp. 1245-1253 ◽  
Author(s):  
Heinz P. Fritz ◽  
Jürgen O. Besenhard ◽  
Antonios S. Paxinos

Abstract The results presented show the feasibility of a high power density lead acid cell with tubular negatives and positives, operating at 70 °C. Although lead negatives are supposed to deteriorate fast at temperatures above 50 °C, tubular negatives at 70 °C exceed the cycle life of pasted negatives operating at conventional conditions. The high rate discharge capacity of negatives and positives is increasing considerably with temperature. It is concluded that the “temperature gain” of the negative electrode is due to increased mobility of soluble Pb2+ species through the passivating PbSO4 layer and to improved diffusion of H2SO4 in the pore structure.


RSC Advances ◽  
2014 ◽  
Vol 4 (49) ◽  
pp. 25494-25501 ◽  
Author(s):  
Peng Mei ◽  
Xing-Long Wu ◽  
Haiming Xie ◽  
Liqun Sun ◽  
Yanping Zeng ◽  
...  

Much enhanced capacity retention abilities, improved high-rate performance and long-term stability have been attained for LiV3O8 nanorods synthesized by a two-step route using VO2(B) nanosheets as the precursor.


Nano Research ◽  
2020 ◽  
Author(s):  
Ming Chen ◽  
Qinnan Zhou ◽  
Jiantao Zai ◽  
Asma Iqbal ◽  
TsegayeTadesse Tsega ◽  
...  

Abstract Silicon is a low price and high capacity anode material for lithium-ion batteries. The yolk-shell structure can effectively accommodate Si expansion to improve stability. However, the limited rate performance of Si anodes can’t meet people’s growing demand for high power density. Herein, the phosphorus-doped yolk-shell Si@C materials (P-doped Si@C) were prepared through carbon coating on P-doped Si/SiOx matrix to obtain high power and stable devices. Therefore, the as-prepared P-doped Si@C electrodes delivered a rapid increase in Coulombic efficiency from 74.4% to 99.6% after only 6 cycles, high capacity retention of ∼ 95% over 800 cycles at 4 A·g−1, and great rate capability (510 mAh·g−1 at 35 A·g−1). As a result, P-doped Si@C anodes paired with commercial activated carbon and LiFePO4 cathode to assemble lithium-ion capacitor (high power density of ∼ 61,080 W·kg−1 at 20 A·g−1) and lithium-ion full cell (good rate performance with 68.3 mAh·g−1 at 5 C), respectively. This work can provide an effective way to further improve power density and stability for energy storage devices.


2014 ◽  
Vol 2 (19) ◽  
pp. 6870-6878 ◽  
Author(s):  
Jinlong Yang ◽  
Xiaochun Kang ◽  
Lin Hu ◽  
Xue Gong ◽  
Shichun Mu

The nanocrystalline-Li2FeSiO4 with carbon frameworks, possessing high-capacity and high-rate performance, is a promising next-generation cathode material for high-power lithium-ion batteries.


2015 ◽  
Vol 3 (16) ◽  
pp. 8627-8635 ◽  
Author(s):  
Chunfu Lin ◽  
Shu Yu ◽  
Shunqing Wu ◽  
Shiwei Lin ◽  
Zi-Zhong Zhu ◽  
...  

Ru0.01Ti0.99Nb2O7, with a much larger capacity than Li4Ti5O12, fulfils the requirements of high power and energy density for electric vehicles.


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