Removal of chlorine gas by an amine functionalized metal–organic framework via electrophilic aromatic substitution

2015 ◽  
Vol 51 (62) ◽  
pp. 12474-12477 ◽  
Author(s):  
Jared B. DeCoste ◽  
Matthew A. Browe ◽  
George W. Wagner ◽  
Joseph A. Rossin ◽  
Gregory W. Peterson
Keyword(s):  
Substitution Reaction ◽  
Metal Organic Framework ◽  
Electrophilic Aromatic Substitution ◽  
Aromatic Substitution ◽  
Amine Functionalized ◽  
Chlorine Gas ◽  
Metal Organic ◽  
Organic Framework

Chlorine gas is removed from airstreams with an amine functionalized metal–organic framework via an electrophilic aromatic substitution reaction producing HCl, which is subsequently neutralized by the substrate.

Amine-functionalized metal-organic framework integrated bismuth tungstate (Bi2WO6/NH2-UiO-66) composites for the enhanced solar-driven photocatalytic degradation of ciprofloxacin molecules

2021 ◽  
Author(s):  
Rokesh Karuppannan ◽  
Sakar Mohan ◽  
Trong-On Do
Keyword(s):  
Photocatalytic Degradation ◽  
Photocatalytic Performance ◽  
Metal Organic Framework ◽  
In Situ Growth ◽  
Hydrothermal Technique ◽  
Bismuth Tungstate ◽  
Amine Functionalized ◽  
Metal Organic ◽  
Organic Framework

Amine-functionalized metal-organic framework integrated bismuth tungstate (Bi2WO6/NH2-UiO-66) nanocomposite has been developed by in-situ growth of NH2-UiO-66 on Bi2WO6 micro/nanoflower via hydrothermal technique and studied their photocatalytic performance towards ciprofloxacin degradation...

Guest-Switchable Multi-Step Spin Transitions in an Amine-Functionalized Metal-Organic Framework

2017 ◽  
Vol 56 (47) ◽  
pp. 14982-14986 ◽  
Author(s):  
Wei Liu ◽  
Yuan-Yuan Peng ◽  
Si-Guo Wu ◽  
Yan-Cong Chen ◽  
Md. Najbul Hoque ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Amine Functionalized ◽  
Metal Organic ◽  
Spin Transitions ◽  
Organic Framework

scholarly journals Efficient One-Pot Synthesis of a Hexamethylenetetramine-Doped Cu-BDC Metal-Organic Framework with Enhanced CO2 Adsorption

Nanomaterials ◽  
2019 ◽  
Vol 9 (8) ◽  
pp. 1063 ◽  
Author(s):  
Aisha Asghar ◽  
Naseem Iqbal ◽  
Tayyaba Noor ◽  
Majid Ali ◽  
Timothy L. Easun
Keyword(s):  
Co2 Adsorption ◽  
Low Cost ◽  
Metal Organic Framework ◽  
Single Step ◽  
Co2 Uptake ◽  
One Pot ◽  
Amine Functionalized ◽  
Metal Organic ◽  
Thermogravimetric Studies ◽  
Organic Framework

Herein we report a facile, efficient, low cost, and easily scalable route for an amine-functionalized MOF (metal organic framework) synthesis. Cu-BDC⊃HMTA (HMTA = hexamethylenetetramine) has high nitrogen content and improved thermal stability when compared with the previously reported and well-studied parent Cu-BDC MOF (BDC = 1,4-benzenedicarboxylate). Cu-BDC⊃HMTA was obtained via the same synthetic method, but with the addition of HMTA in a single step synthesis. Thermogravimetric studies reveal that Cu-BDC⊃HMTA is more thermally stable than Cu-BDC MOF. Cu-BDC⊃HMTA exhibited a CO2 uptake of 21.2 wt % at 273 K and 1 bar, which compares favorably to other nitrogen-containing MOF materials.

scholarly journals The Chemistry of CO2 Capture in an Amine-Functionalized Metal–Organic Framework under Dry and Humid Conditions

2017 ◽  
Vol 139 (35) ◽  
pp. 12125-12128 ◽  
Author(s):  
Robinson W. Flaig ◽  
Thomas M. Osborn Popp ◽  
Alejandro M. Fracaroli ◽  
Eugene A. Kapustin ◽  
Markus J. Kalmutzki ◽  
...  
Keyword(s):  
Co2 Capture ◽  
Metal Organic Framework ◽  
Amine Functionalized ◽  
Metal Organic ◽  
Organic Framework
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