Reductive cleavage of inert aryl C–O bonds to produce arenes

2015 ◽  
Vol 51 (61) ◽  
pp. 12212-12215 ◽  
Author(s):  
Huanjun Xu ◽  
Bo Yu ◽  
Hongye Zhang ◽  
Yanfei Zhao ◽  
Zhenzhen Yang ◽  
...  
Keyword(s):  
Reductive Cleavage ◽  
Aryl Ethers ◽  
High Yields

Reductive cleavage of aryl C–O bonds in phenols and aryl ethers was achieved using LiAlH4–KOtBu, producing arenes in high yields.

AN IMPROVED PREPARATION OF ω-HYDROXY ALIPHATIC ACIDS AND THEIR ESTERS

1960 ◽  
Vol 38 (10) ◽  
pp. 1976-1982 ◽  
Author(s):  
D. G. M. Diaper ◽  
D. L. Mitchell
Keyword(s):  
Sodium Borohydride ◽  
Reductive Cleavage ◽  
Aliphatic Acids ◽  
Aliphatic Esters ◽  
High Yields

Reductive cleavage of the ozonides of aliphatic acids and their esters by sodium borohydride or by hydrogenation produces ω-hydroxy aliphatic acids and ω-hydroxy aliphatic esters, respectively, in high yields.

scholarly journals Nickel-catalyzed reductive cleavage of aryl alkyl ethers to arenes in absence of external reductant

2015 ◽  
Vol 6 (6) ◽  
pp. 3410-3414 ◽  
Author(s):  
Mamoru Tobisu ◽  
Toshifumi Morioka ◽  
Akimichi Ohtsuki ◽  
Naoto Chatani
Keyword(s):  
Nickel Catalyst ◽  
Alkoxy Group ◽  
Reductive Cleavage ◽  
Alkyl Ethers ◽  
Aryl Ethers

A nickel catalyst for reductive cleavage of aryl ethers in the absence of an external reductant is developed. The alkoxy group of the substrate serves as an internal reductant.

Electrostatic and Electrophilic Catalysis in the Reductive Cleavage of Alkyl Aryl Ethers. The Influence of Ion Pairing on the Regioselectivity

2000 ◽  
Vol 65 (2) ◽  
pp. 322-331 ◽  
Author(s):  
Francisco Casado ◽  
Luisa Pisano ◽  
Maria Farriol ◽  
Iluminada Gallardo ◽  
Jordi Marquet ◽  
...  
Keyword(s):  
Ion Pairing ◽  
Reductive Cleavage ◽  
Alkyl Aryl ◽  
Aryl Ethers ◽  
Alkyl Aryl Ethers

scholarly journals Lewis-base silane activation: from reductive cleavage of aryl ethers to selective ortho-silylation

2013 ◽  
Vol 4 (4) ◽  
pp. 1640 ◽  
Author(s):  
Alexey Fedorov ◽  
Anton A. Toutov ◽  
Nicholas A. Swisher ◽  
Robert H. Grubbs
Keyword(s):  
Reductive Cleavage ◽  
Lewis Base ◽  
Aryl Ethers

ChemInform Abstract: Regio- and Stereochemistry of Na-Mediated Reductive Cleavage of Alkyl Aryl Ethers.

ChemInform ◽  
2015 ◽  
Vol 46 (18) ◽  
pp. no-no
Author(s):  
Ugo Azzena ◽  
Massimo Carraro ◽  
Claudia Meloni ◽  
Irene Murgia ◽  
Luisa Pisano ◽  
...  
Keyword(s):  
Reductive Cleavage ◽  
Alkyl Aryl ◽  
Aryl Ethers ◽  
Alkyl Aryl Ethers

scholarly journals Reductive Cleavage of Aryl-O-and Aryl-CI- Bonds by C8K: a Potential Method for the Degradation of Dioxins

1988 ◽  
Vol 43 (9) ◽  
pp. 1211-1212 ◽  
Author(s):  
Manfred Lissel ◽  
Jürgen Kottmann ◽  
Dov Tamarkin ◽  
Mordechai Rabinovitz
Keyword(s):  
Potential Method ◽  
Reductive Cleavage ◽  
Aryl Halides ◽  
Aryl Ethers

Abstract Potassium graphite intercalate in THF is a reagent for the reduction of aryl halides and the reductive cleavage of aryl ethers.

Regio- and stereochemistry of Na-mediated reductive cleavage of alkyl aryl ethers

2014 ◽  
Vol 25 (23) ◽  
pp. 1550-1554 ◽  
Author(s):  
Ugo Azzena ◽  
Massimo Carraro ◽  
Claudia Meloni ◽  
Irene Murgia ◽  
Luisa Pisano ◽  
...  
Keyword(s):  
Reductive Cleavage ◽  
Alkyl Aryl ◽  
Aryl Ethers ◽  
Alkyl Aryl Ethers
Sign in / Sign up

Export Citation Format

Share Document