A cryo-generated ferrous–superoxo porphyrin: EPR, resonance Raman and DFT studies

2015 ◽  
Vol 51 (62) ◽  
pp. 12407-12410 ◽  
Author(s):  
Takehiro Ohta ◽  
Jin-Gang Liu ◽  
Perumandla Nagaraju ◽  
Takashi Ogura ◽  
Yoshinori Naruta
Keyword(s):  
Raman Spectroscopy ◽  
Dft Calculations ◽  
Resonance Raman Spectroscopy ◽  
Resonance Raman ◽  
Dft Studies ◽  
Heme Enzymes

Cryo-generated ferrous–superoxy heme was studied by EPR, resonance Raman spectroscopy and DFT calculations, providing new insights into the structure–reactivity correlation of O2 activating heme enzymes and catalysts.

scholarly journals 3P101 Red-Excited Resonance Raman Spectroscopy of Reaction Intermediates of Heme Enzymes

2005 ◽  
Vol 45 (supplement) ◽  
pp. S229
Author(s):  
K. Ikemura ◽  
H. Shimada ◽  
K. Shinzawa-Ito ◽  
S. Yoshikawa ◽  
T. Ogura
Keyword(s):  
Raman Spectroscopy ◽  
Resonance Raman Spectroscopy ◽  
Resonance Raman ◽  
Reaction Intermediates ◽  
Heme Enzymes ◽  
Excited Resonance
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