The isomeric effect of mercaptobenzoic acids on the preparation and fluorescence properties of copper nanoclusters

2015 ◽  
Vol 51 (60) ◽  
pp. 11983-11986 ◽  
Author(s):  
Yi-Jyun Lin ◽  
Po-Cheng Chen ◽  
Zhiqin Yuan ◽  
Jia-Ying Ma ◽  
Huan-Tsung Chang
Keyword(s):  
Optical Properties ◽  
Copper Nitrate ◽  
Fluorescence Properties ◽  
Copper Nanoclusters ◽  
Isomeric Effect

Copper nanoclusters (Cu NCs) aggregates prepared from copper nitrate and mercaptobenzoic acid (MBA) isomers show differential optical properties.

scholarly journals Coordination Assemblies of Zn(II) Coordination Polymers: Positional Isomeric Effect and Optical Properties

Crystals ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 664 ◽  
Author(s):  
Chang-Jie Liu ◽  
Tong-Tong Zhang ◽  
Wei-Dong Li ◽  
Yuan-Yuan Wang ◽  
Shui-Sheng Chen
Keyword(s):  
Optical Properties ◽  
Infrared Spectroscopy ◽  
Thermogravimetric Analysis ◽  
Quantum Yield ◽  
Coordination Polymers ◽  
Square Lattice ◽  
X Ray Diffraction ◽  
X Ray ◽  
Mixed Ligands ◽  
Isomeric Effect

Two Zn(II) coordination polymers (CPs) [Zn(L)(pphda)] (1) and [Zn(L)(ophda)]·H2O (2) were prepared by reactions of ZnSO4·7H2O based on the N-donor 1,4-di(1H-imidazol-4-yl)benzene (L) ligand and two flexible carboxylic acids isomers of 1,4-phenylenediacetic acid (H2pphda) and 1,2-phenylenediacetic acid (H2ophda) as mixed ligands, respectively. Structures of CPs 1 and 2 were characterized by elemental analysis, Infrared spectroscopy (IR), thermogravimetric analysis and single-crystal X-ray diffraction. The CP 1 is a fourfold interpenetrating 66-diamond (dia) architecture, while 2 is a 2D (4, 4) square lattice (sql) layer based on the Zn2(cis-1,2-ophda2−)2 binuclear Zn(II) subunits. The luminescent property, including luminescence lifetime and quantum yield (QY), have been investigated for CPs 1 and 2.

The Effect of the Cu Source on Optical Properties of Cu-Doped ZnO Films

2014 ◽  
Vol 936 ◽  
pp. 618-623
Author(s):  
Lung Chien Chen ◽  
Xiu Yu Zhang ◽  
Kuan Lin Lee
Keyword(s):  
Optical Properties ◽  
Copper Acetate ◽  
Copper Nitrate ◽  
Zno Films ◽  
X Ray Diffraction ◽  
X Ray ◽  
Ultrasonic Spray ◽  
Spray Method ◽  
Potential Applications ◽  
Doped Zno

Cu-doped ZnO (CZO) films have been widely discussed due to its potential applications in semiconductor devices, such as gas sensors or solar cells, but few articles were reported to show the effect on properties of CZO films by using different Cu sources. The article demonstrates that CZO films have been prepared by using different Cu source via a simple ultrasonic spray method, in which copper nitrate and copper acetate were used as copper sources. Optical properties of CZO films prepared by copper nitrate and copper acetate were investigated by transmittance and photoluminescence measurement. The X-ray diffraction analysis and field emission scanning electron microscopy were used to investigate the composition and the morphology of the films. The CZO films prepared by using copper acetate shows better optical properties by comprehensive analysis.

New barbituric acid derivatives for data encryption and decryption based on the mechanochromic fluorescence effect

The Analyst ◽  
2020 ◽  
Vol 145 (15) ◽  
pp. 5325-5332
Author(s):  
Hanjun Zhang ◽  
Zhen Xu ◽  
Furong Tao ◽  
Yan Li ◽  
Yuezhi Cui ◽  
...  
Keyword(s):  
Optical Properties ◽  
Barbituric Acid ◽  
Data Encryption ◽  
Fluorescence Properties ◽  
Encryption And Decryption ◽  
Encryption Decryption ◽  
Barbituric Acid Derivatives ◽  
Fluorescence Effect

CB-Ph and CB-Me have similar color and fluorescence properties, while they exhibit specific differences under the same stimulus. Based on the unique optical properties of CB-Ph and CB-Me, a new data encryption–decryption technology is developed.

Synthesis, optical properties and applications of light-emitting copper nanoclusters

2017 ◽  
Vol 2 (3) ◽  
pp. 135-146 ◽  
Author(s):  
Zhenguang Wang ◽  
Bingkun Chen ◽  
Andrey L. Rogach
Keyword(s):  
Optical Properties ◽  
Copper Nanoclusters ◽  
Light Emitting ◽  
Earth Abundant ◽  
Metal Nanocluster ◽  
Commercial Sources

Copper is an earth abundant, inexpensive metal readily available from commercial sources, which is increasingly coming into focus for light-emitting metal nanocluster research.

scholarly journals Development of a Nanocluster-Based Platform for Determination of Sofosbuvir

2021 ◽  
Author(s):  
Zahra Karimzadeh ◽  
Abolghasem Jouyban ◽  
Elaheh Rahimpour
Keyword(s):  
Response Surface Methodology ◽  
Limit Of Detection ◽  
Copper Nitrate ◽  
Plasma Samples ◽  
Copper Nanoclusters ◽  
Good Repeatability ◽  
Direct Acting ◽  
Optimized Conditions ◽  
Linear Concentration

Background: Sofosbuvir is a potent direct-acting antivirus agent that has been listed as a promising medicine for the treatment of all genotypes of hepatitis C virus. As antiviral drugs could be metabolized to their associated compounds and toxicologically and pharmacologically interfere with the parent drugs, identifying the therapeutic range of drugs would be notable. Methods: In the current study, copper nanoclusters (Cu NCs) are synthesized during the reduction of copper nitrate with hydrazine hydrate in a protected media and used as a nanoprobe for the determination of sofosbuvir in plasma samples. Herein, synchronous fluorescence spectroscopy (SFS) is used for monitoring of fluorescence variation of nanoprobe owing to the excessive benefits compared with the traditional fluorescence. Results: SFS peak of Cu NCs has appeared at 355 nm with ∆λ=80 nm which is decreased in the presence of sofosbuvir. To optimize the reaction factors, a response surface methodology is used and in the optimized conditions, a linear concentration-response plot is obtained in a range of 0.05-6.0 µg mL−1 with a limit of detection of 0.0147 µg mL−1. Conclusion: The developed method also reveals good repeatability and selectivity for sofosbuvir in plasma samples.

scholarly journals Isomeric Effect of Mercaptobenzoic Acids on the Synthesis, Stability, and Optical Properties of Au25(MBA)18 Nanoclusters

ACS Omega ◽  
2018 ◽  
Vol 3 (11) ◽  
pp. 15635-15642 ◽  
Author(s):  
Franck Bertorelle ◽  
Isabelle Russier-Antoine ◽  
Clothilde Comby-Zerbino ◽  
Fabien Chirot ◽  
Philippe Dugourd ◽  
...  
Keyword(s):  
Optical Properties ◽  
Isomeric Effect
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