scholarly journals One-step synthesis of a cyclic 2,17-dioxo[3,3](4,4′) biphenylophane and first preparation of a microporous polymer network from a macrocyclic precursor by cyclotrimerization

2015 ◽  
Vol 51 (43) ◽  
pp. 9046-9049 ◽  
Author(s):  
Suman Kalyan Samanta ◽  
Eduard Preis ◽  
Christian W. Lehmann ◽  
Richard Goddard ◽  
Saientan Bag ◽  
...  

Macrocycle 2,17-dioxo[3,3](4,4′)biphenylophane was synthesized and used in the formation of a microporous polymer network.

2014 ◽  
Vol 50 (25) ◽  
pp. 3347-3349 ◽  
Author(s):  
Johannes Schmidt ◽  
Dipti Sankar Kundu ◽  
Siegfried Blechert ◽  
Arne Thomas

2011 ◽  
Vol 353 (17) ◽  
pp. 3101-3106 ◽  
Author(s):  
Christian Bleschke ◽  
Johannes Schmidt ◽  
Dipti S. Kundu ◽  
Siegfried Blechert ◽  
Arne Thomas

2014 ◽  
Vol 20 (31) ◽  
pp. 9543-9548 ◽  
Author(s):  
Hakan Bildirir ◽  
Jens Peter Paraknowitsch ◽  
Arne Thomas

Author(s):  
Lin Sun Tao ◽  
Cui Kunpeng ◽  
Ping Gong Jian

This article reviews the recently developed tough, self-recovery, and self-healing polyampholyte hydrogels. Polyampholyte hydrogels are synthesized using one-step radical copolymerization of cationic and anionic monomers with equal charges at high monomer concentration. The random copolymerization process makes the ionic monomers randomly distributing along the backbones, resulting in the formation of ionic bonds with a wide strength distribution via inter and intra chain complexation in the polymer network, weak bond and strong bonds. The strong bonds serve as permanent cross-linking, integrating the hydrogels to impart the elastic behavior, while the weak bonds can break upon the loading, dissipating energy to give the toughness, and re-form again after unloading to enable the self-recovery behavior. Accordingly, polyampholyte hydrogels have condensed polymers in water (c.a. 40-50 wt%). They are strongly viscoelastic and have a high toughness (fracture energy of 4000 J/m), a wide range of tuning modulus (0.01 to 8 MPa), 100% self-recovery, and a high self-healing efficiency after cutting.


2019 ◽  
Vol 43 (42) ◽  
pp. 16647-16655
Author(s):  
Qiuli Cheng ◽  
Xiaowei Guo ◽  
Jiawei Zou ◽  
Xiaoyu Shi ◽  
Shuxiang Ding ◽  
...  

An interpenetrating polymer network (IPN) structured antibacterial layer was prepared on dental base materials using a one-step photo-crosslinking method.


2015 ◽  
Vol 51 (98) ◽  
pp. 17394-17397 ◽  
Author(s):  
Jing Tan ◽  
Jiaxun Wan ◽  
Jia Guo ◽  
Changchun Wang

Conjugated microporous polymer microcapsules synthesized by virtue of a self-sacrificial polymer template in one step exhibit a shape-dependent enhanced photothermal conversion efficiency for ablation of cancer cells.


2015 ◽  
Vol 51 (20) ◽  
pp. 4283-4286 ◽  
Author(s):  
Daniel Becker ◽  
Nina Heidary ◽  
Marius Horch ◽  
Ulrich Gernert ◽  
Ingo Zebger ◽  
...  

Thin films of microporous polymer networks are covalently attached to SAM functionalized gold electrodes.


2015 ◽  
Vol 300 (11) ◽  
pp. 1116-1122 ◽  
Author(s):  
Omer Suat Taskin ◽  
Baris Kiskan ◽  
Jens Weber ◽  
Yusuf Yagci

2011 ◽  
Vol 332-334 ◽  
pp. 1836-1839 ◽  
Author(s):  
Chen Zhang ◽  
Xiao Yun Liu ◽  
Liu Sheng Zha

The microgels with semi-interpenetrating polymer network (semi-IPN) structure based on cross-linked poly(N-isopropylacrylamide) (PNIPAM) and linear poly(acrylic acid) (PAA) were fabricated by one-step precipitation polymerization technique. The chemical composition of the microgels was determined by Fourier transformation infrared spectroscopy and elemental analysis. It was found that the PAA content inside the microgels decreased as the pH value of reaction media increased. The semi-IPN structure of the microgels was confirmed by transmission electron microscopy using uranyl acetate staining method. The pH dependent hydrodynamic diameters obtained by dynamic light scattering revealed that these microgels can reversibly shrink and swell in the pH range from 4.0 to 6.0. The semi-IPN microgels synthesized at pH 3.0 could undergo about 120 times volume change in the pH range.


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