High efficiency thermally activated delayed fluorescence based on 1,3,5-tris(4-(diphenylamino)phenyl)-2,4,6-tricyanobenzene

2015 ◽  
Vol 51 (24) ◽  
pp. 5028-5031 ◽  
Author(s):  
Masatsugu Taneda ◽  
Katsuyuki Shizu ◽  
Hiroyuki Tanaka ◽  
Chihaya Adachi
Keyword(s):  
High Efficiency ◽  
Delayed Fluorescence ◽  
Acceptor Molecule ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Donor Acceptor

A trigonal donor–acceptor molecule of 1,3,5-tris(4-(diphenylamino)phenyl)-2,4,6-tricyanobenzene (3DPA3CN) was synthesized to exhibit efficient thermally activated delayed fluorescence.

scholarly journals High-efficiency blue thermally activated delayed fluorescence from donor–acceptor–donor systems via the through-space conjugation effect

2019 ◽  
Vol 10 (21) ◽  
pp. 5556-5567 ◽  
Author(s):  
Feifei Gao ◽  
Ruiming Du ◽  
Chunmiao Han ◽  
Jing Zhang ◽  
Ying Wei ◽  
...  
Keyword(s):  
High Efficiency ◽  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Conjugation Effect ◽  
Highly Efficient ◽  
Donor Acceptor

Highly efficient sky-blue TADF donor–acceptor–donor molecules were demonstrated, in which 5,10-diphenyl-5,10-dihydrophosphanthrene oxide (DPDPO2A) with the feature of homoconjugation was used as the acceptor to bridge four carbazolyl or 3,6-di-t-butyl-carbazolyl groups.

scholarly journals Intramolecular Through-Space Charge-Transfer Emitters Featuring Thermally Activated Delayed Fluorescence for High-Efficiency Electroluminescent Devices

2021 ◽  
Author(s):  
Yongjun song ◽  
lei he ◽  
Mingxing Tian ◽  
Renyou Yu
Keyword(s):  
Charge Transfer ◽  
Space Charge ◽  
High Efficiency ◽  
Theoretical Calculations ◽  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Light Emitting ◽  
Thermally Activated ◽  
Donor Acceptor ◽  
First Time

Through-space charge-transfer (TSCT) emitters have been extensively explored for thermally activated delayed fluorescence (TADF), but arranging various donors and acceptors into rigid cofacial conformations for various efficient TSCT TADF emitters has still remained a challenge. Here we report for the first time a “fixing acceptor” design to reach various efficient TSCT TADF emitters. By chemically fixing the acceptor (benzophenone) with a rigid spiro structure and cofacially aligning various donors with the fixed acceptor, a series of efficient TSCT TADF emitters have been developed. Single-crystal structures and theoretical calculations have verified closely-packed cofacial donor/acceptor conformations and favorable TSCT in the emitters. The emitters afford sky-blue to yellow TADF emission in doped films, with high photoluminescent efficiencies of up to 0.92 and reverse intersystem crossing rates of up to 1.0×106 s−1. Organic light-emitting diodes using the emitters afford sky-blue to yellow electroluminescence with high external quantum efficiencies of up to 20.9%. The work opens a new avenue toward a wide variety of efficient TSCT TADF emitters.

scholarly journals Pyrimidine-based twisted donor–acceptor delayed fluorescence molecules: a new universal platform for highly efficient blue electroluminescence

2017 ◽  
Vol 8 (2) ◽  
pp. 953-960 ◽  
Author(s):  
In Seob Park ◽  
Hideaki Komiyama ◽  
Takuma Yasuda
Keyword(s):  
High Efficiency ◽  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Highly Efficient ◽  
Deep Blue ◽  
Donor Acceptor

High-efficiency deep blue thermally activated delayed fluorescence (TADF) emitters consisting of acridan–pyrimidine donor–acceptor motifs are developed.

The effect of a heavy atom on the radiative pathways of an emitter with dual conformation, thermally-activated delayed fluorescence and room temperature phosphorescence

2019 ◽  
Vol 7 (34) ◽  
pp. 10481-10490 ◽  
Author(s):  
Daniel de Sa Pereira ◽  
Dong Ryun Lee ◽  
Nadzeya A. Kukhta ◽  
Kyung Hyung Lee ◽  
Cho Long Kim ◽  
...  
Keyword(s):  
Room Temperature ◽  
Heavy Atom ◽  
Delayed Fluorescence ◽  
Acceptor Molecule ◽  
Room Temperature Phosphorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Donor Acceptor

This study focuses on the photophysics of a donor–acceptor molecule with 2,4,6-triphenyl-1,3,5-triazine and phenoselenazine acceptor and donor units.

Exploring mechanisms for generating spin-orbital coupling through donor–acceptor design to realize spin flipping in thermally activated delayed fluorescence

2020 ◽  
Vol 8 (10) ◽  
pp. 3395-3401 ◽  
Author(s):  
Miaosheng Wang ◽  
Tanmay Chatterjee ◽  
Camera Janelle Foster ◽  
Ting Wu ◽  
Chih-Lun Yi ◽  
...  
Keyword(s):  
High Efficiency ◽  
Delayed Fluorescence ◽  
Coupling Effects ◽  
Optical Studies ◽  
Spin Orbital ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Donor Acceptor ◽  
Dependent Processes ◽  
Spin Orbital Coupling

Spin-orbital coupling effects and the underlying spin-dependent processes to achieve high-efficiency TADF are revealed based on magneto-optical studies.

New hole transport styrene polymers bearing highly π-extended conjugated side-chain moieties for high-performance solution-processable thermally activated delayed fluorescence OLEDs

2021 ◽  
Vol 12 (11) ◽  
pp. 1692-1699
Author(s):  
Ji Hye Lee ◽  
Jinhyo Hwang ◽  
Chai Won Kim ◽  
Amit Kumar Harit ◽  
Han Young Woo ◽  
...  
Keyword(s):  
High Performance ◽  
High Efficiency ◽  
Delayed Fluorescence ◽  
Hole Transport ◽  
Side Chain ◽  
Solution Processed ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Turn On ◽  
Solution Processable

New polystyrene-based polymers with high π-extended hole transport pendants were synthesized to obtain a low turn-on voltage and high efficiency in solution-processed green TADF-OLEDs.

Novel thermally activated delayed fluorescence materials by high-throughput virtual screening: going beyond donor–acceptor design

2021 ◽  
Vol 9 (9) ◽  
pp. 3324-3333 ◽  
Author(s):  
Ke Zhao ◽  
Ömer H. Omar ◽  
Tahereh Nematiaram ◽  
Daniele Padula ◽  
Alessandro Troisi
Keyword(s):  
Virtual Screening ◽  
Quantum Chemistry ◽  
High Throughput ◽  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Quantum Chemistry Calculations ◽  
Donor Acceptor ◽  
Molecular Semiconductors ◽  
High Throughput Virtual Screening

125 potential TADF candidates are identified through quantum chemistry calculations of 700 molecules derived from a database of 40 000 molecular semiconductors. Most of them are new and some do not belong to the class of donor–acceptor molecules.

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