The facile synthesis of single crystalline palladium arrow-headed tripods and their application in formic acid electro-oxidation

2015 ◽  
Vol 51 (33) ◽  
pp. 7195-7198 ◽  
Author(s):  
Na Su ◽  
Xueying Chen ◽  
Yuanhang Ren ◽  
Bin Yue ◽  
Han Wang ◽  
...  
Keyword(s):  
Formic Acid ◽  
Surface Diffusion ◽  
Concentration Gradient ◽  
Formic Acid Oxidation ◽  
Acid Oxidation ◽  
Reduction Kinetics ◽  
Facile Synthesis ◽  
One Pot ◽  
Single Crystalline ◽  
Electro Oxidation

Single-crystalline palladium arrow-headed tripods exhibiting high electro-activity in formic acid oxidation were prepared via a simple one-pot strategy by manipulating the reduction kinetics, concentration gradient and surface diffusion of atoms.

scholarly journals Facile Synthesis of Pd Nanocubes with Assistant of Iodide and Investigation of Their Electrocatalytic Performances Towards Formic Acid Oxidation

Nanomaterials ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 375 ◽  
Author(s):  
Xuan Liu ◽  
Zichao Li ◽  
Kuankuan Wang ◽  
Luming Zhou ◽  
Xihui Zhao ◽  
...  
Keyword(s):  
Formic Acid ◽  
Sodium Iodide ◽  
Pd Nanoparticles ◽  
Formic Acid Oxidation ◽  
Acid Oxidation ◽  
Capping Agent ◽  
Synthesis System ◽  
Facile Synthesis ◽  
High Quality ◽  
One Pot

This article presents a facile, one-pot method using the aqueous phase for the synthesis of high-quality Pd nanocubes. In this study, Pd chloride was used as the precursor, sodium iodide as capping agent, and poly(vinylpyrrolidone) as surfactant and reducing agent. The effects of different halogens on the morphology of Pd nanocrystals were investigated. The results showed that, in this synthesis system, the selection and proper amount of sodium iodide was essential to the preparation of high-quality Pd nanocubes. When iodide was replaced by other halogens (such as bromide and chloride), Pd nanocrystals with cubic morphology could not be obtained. In addition, we have found that NaBH4 can be used to efficiently remove inorganic covers, such as iodide, from the surface of Pd nanoparticles as synthesized. The Pd nanoparticles obtained were employed as electro-catalysts for formic acid oxidation, and they exhibited excellent catalytic activity and good stability towards this reaction.

Single-crystalline Pd square nanoplates enclosed by {100} facets on reduced graphene oxide for formic acid electro-oxidation

2016 ◽  
Vol 52 (99) ◽  
pp. 14204-14207 ◽  
Author(s):  
Yi Jiang ◽  
Yucong Yan ◽  
Wenlong Chen ◽  
Yousaf Khan ◽  
Jianbo Wu ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Formic Acid ◽  
Reduced Graphene Oxide ◽  
Catalytic Properties ◽  
Formic Acid Oxidation ◽  
Acid Oxidation ◽  
Single Crystalline ◽  
Reduced Graphene ◽  
Electro Oxidation

{100} faceted Pd nanoplates were prepared on reduced graphene oxide and exhibited substantially enhanced catalytic properties towards formic acid oxidation.

Carbon-loaded ultrafine fully crystalline phase palladium-based nanoalloy PdCoNi/C: facile synthesis and high activity for formic acid oxidation

Nanoscale ◽  
2019 ◽  
Vol 11 (37) ◽  
pp. 17334-17339 ◽  
Author(s):  
Yu Pan ◽  
Yihua Zhu ◽  
Jianhua Shen ◽  
Ying Chen ◽  
Chunzhong Li
Keyword(s):  
Formic Acid ◽  
High Activity ◽  
Crystalline Phase ◽  
Formic Acid Oxidation ◽  
Acid Oxidation ◽  
Facile Synthesis ◽  
Coordination Sites

Ultrafine fully crystalline PdCoNi/C with abundant low coordination sites and remarkable performance as a formic acid oxidation electrocatalyst.

Surface diffusion of poisoning species during CO and formic acid oxidation on PtAu surface. The key role of the active site

2021 ◽  
Vol 483 ◽  
pp. 229189
Author(s):  
Daniela Minudri ◽  
Alvaro Y. Tesio ◽  
Florencia Fungo ◽  
Rodrigo E. Palacios ◽  
Paula S. Cappellari ◽  
...  
Keyword(s):  
Formic Acid ◽  
Surface Diffusion ◽  
Active Site ◽  
Formic Acid Oxidation ◽  
Acid Oxidation

The in situ growth of ultrathin Fcc-NiPt nanocrystals on graphene for methanol and formic acid oxidation

2018 ◽  
Vol 47 (42) ◽  
pp. 15131-15140 ◽  
Author(s):  
Liu Lin ◽  
Mengwei Yuan ◽  
Zemin Sun ◽  
Huifeng Li ◽  
Caiyun Nan ◽  
...  
Keyword(s):  
Formic Acid ◽  
Formic Acid Oxidation ◽  
Acid Oxidation ◽  
In Situ Growth ◽  
One Pot ◽  
Electrocatalytic Properties ◽  
In Suit

One-pot strategy to in-suit anchor NiPt nanocrystals on the graphene substrates which show outstanding bifunctional electrocatalytic properties in DMFC and DFAFC.

One-pot synthesis of lotus-shaped Pd–Cu hierarchical superstructure crystals for formic acid oxidation

RSC Advances ◽  
2016 ◽  
Vol 6 (98) ◽  
pp. 96079-96083 ◽  
Author(s):  
Li Xu ◽  
Kai Wang ◽  
Qiang Yuan
Keyword(s):  
Aqueous Solution ◽  
Formic Acid ◽  
Solution Method ◽  
Formic Acid Oxidation ◽  
Acid Oxidation ◽  
One Pot ◽  
Electrocatalytic Properties ◽  
One Pot Synthesis ◽  
Aqueous Solution Method

Lotus-shaped Pd–Cu hierarchical superstructure crystals with enhanced electrocatalytic properties toward HCOOH oxidation were successfully synthesized through an aqueous solution method.

Graphene Decorated with PtAu Alloy Nanoparticles: Facile Synthesis and Promising Application for Formic Acid Oxidation

2011 ◽  
Vol 23 (5) ◽  
pp. 1079-1081 ◽  
Author(s):  
Sheng Zhang ◽  
Yuyan Shao ◽  
Hong-gang Liao ◽  
Jun Liu ◽  
Ilhan A. Aksay ◽  
...  
Keyword(s):  
Formic Acid ◽  
Formic Acid Oxidation ◽  
Acid Oxidation ◽  
Alloy Nanoparticles ◽  
Facile Synthesis ◽  
Promising Application

Facile synthesis of Pd/PDDA-GN/PMo11Co composite and its enhanced catalytic performance for formic acid oxidation

RSC Advances ◽  
2016 ◽  
Vol 6 (109) ◽  
pp. 107370-107378 ◽  
Author(s):  
Lijuan Le ◽  
Xiaofeng Zhang ◽  
Ai Ma ◽  
Yi Zhang ◽  
Huodi Huang ◽  
...  
Keyword(s):  
Formic Acid ◽  
Formic Acid Oxidation ◽  
Catalytic Performance ◽  
Acid Oxidation ◽  
Intermediate Species ◽  
Facile Synthesis

The PMo11Co into the composite Pd/PDDA-GN/PMo11Co contributes to converting intermediate species CO into CO2 for formic acid oxidation.

Facile synthesis based on novel carbon-supported cyanogel of structurally ordered Pd3Fe/C as electrocatalyst for formic acid oxidation

Nano Research ◽  
2018 ◽  
Vol 11 (9) ◽  
pp. 4686-4696 ◽  
Author(s):  
Zhenyuan Liu ◽  
Gengtao Fu ◽  
Jiahui Li ◽  
Zhenqi Liu ◽  
Lin Xu ◽  
...  
Keyword(s):  
Formic Acid ◽  
Formic Acid Oxidation ◽  
Acid Oxidation ◽  
Facile Synthesis
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