Carbon nanotubes implanted manganese-based MOFs for simultaneous detection of biomolecules in body fluids

The Analyst ◽  
2016 ◽  
Vol 141 (4) ◽  
pp. 1279-1285 ◽  
Author(s):  
Min-Qiang Wang ◽  
Cui Ye ◽  
Shu-Juan Bao ◽  
Yan Zhang ◽  
Ya-Nan Yu ◽  
...  

Metal–organic frameworks (MOFs) have recently attracted much interest in electrochemical fields due to their controlled porosity, large internal surface area, and countless structural topologies.

Author(s):  
Jiangyan Yuan ◽  
Jie Dong ◽  
Sheng-Bin Lei ◽  
Wenping Hu

As a new type of inorganic-organic hybrid materials with adjustable structures, high internal surface area and unique optical characteristics, Metal-Organic Frameworks (MOFs) with long afterglow behavior have attract more attention....


2015 ◽  
Vol 17 (18) ◽  
pp. 11962-11973 ◽  
Author(s):  
Yi Bao ◽  
Richard L. Martin ◽  
Maciej Haranczyk ◽  
Michael W. Deem

Metal–organic frameworks (MOFs) offer unprecedented atom-scale design and structural tunability, largely due to the vast number of possible organic linkers which can be utilized in their assembly.


Author(s):  
Dengsong Zhang ◽  
Liyi Shil ◽  
Jianhui Fang ◽  
Kai Dai

Modified multiwall carbon nanotubes (MWCNTs) were used as the electrodes of flow–through capacitor for the desalination, which were cost–cutting, energy–saving, and enviromnent–friendly and could be expected to be an altemative technology for reverse osmosis membrane for sea water desalination. Investigated by transmission electron microscope (TEM) and nitrogen adsorption/desorption for modified MWCNTs, it was confirmed that after modification treatment by immersion in diluted HNO3 solution with ultrasonic and then milling by ball at a high velocity, the metal catalyst particles at the tip of MWCNTs disappeared, the MWCNT length became short, the cap at the tip of nanotube was opened, the internal surface area could be effectively used, leading to the increase of the specific surface area and pore volume, and thus MWCNTs modified by that method had the best desalination performance. This modification technique is simple and the efficiency is high.


2021 ◽  
Vol 33 (2) ◽  
pp. 245-252
Author(s):  
ABHINANDAN RANA

Metal-organic frameworks (MOFs) are inorganic-organic hybrid porous materials that are composed of positively charged metal ions and organic linkers. The metal ions form nodes that connect the arms of the linkers together to form one-, two-, or three-dimensional structures. Due to this void structure, MOFs have an unusually large internal surface area. They have received enormous interest in recent years particularly as newly developed porous materials. They possess a wide range of potential applications like gas storage, catalysis, sensors, drug delivery, adsorption, etc. In present review article, synthetic methods and applications of MOFs have been discussed.


Energies ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 964
Author(s):  
Thomas Steiner ◽  
Daniel Neurauter ◽  
Peer Moewius ◽  
Christoph Pfeifer ◽  
Verena Schallhart ◽  
...  

This study investigates geometric parameters of commercially available or recently published models of catalyst substrates for passenger vehicles and provides a numerical evaluation of their influence on heat-up behavior. Parameters considered to have a significant impact on the thermal economy of a monolith are: internal surface area, heat transfer coefficient, and mass of the converter, as well as its heat capacity. During simulation experiments, it could be determined that the primary role is played by the mass of the monolith and its internal surface area, while the heat transfer coefficient only has a secondary role. Furthermore, an optimization loop was implemented, whereby the internal surface area of a commonly used substrate was chosen as a reference. The lengths of the thin wall and high cell density monoliths investigated were adapted consecutively to obtain the reference internal surface area. The results obtained by this optimization process contribute to improving the heat-up performance while simultaneously reducing the valuable installation space required.


Sensors ◽  
2021 ◽  
Vol 21 (5) ◽  
pp. 1679
Author(s):  
Roberta Puglisi ◽  
Anna L. Pellegrino ◽  
Roberto Fiorenza ◽  
Salvatore Scirè ◽  
Graziella Malandrino

Gadolinium metal-organic frameworks (Gd-MOFs) and Eu-doped Gd-MOFs have been synthesized through a one-pot green approach using commercially available reagents. The 1,4-benzenedicarboxylic acid (H2-BDC) and 2,6-naphthalenedicarboxylic acid (H2-NDC) were chosen as ditopic organic linkers to build the 3D structure of the network. The Gd-MOFs were characterized using powder X-ray diffraction (XRD), FT-IR spectroscopy, field emission scanning electron microscopy (FE-SEM) and N2 adsorption–desorption analysis. The Gd-MOF structures were attributed comparing the XRD patterns, supported by the FT-IR spectra, with data reported in the literature for Ln-MOFs of similar lanthanide ionic radius. FE-SEM characterization points to the effect of the duration of the synthesis to a more crystalline and organized structure, with grain dimensions increasing upon increasing reaction time. The total surface area of the MOFs has been determined from the application of the Brunauer–Emmett–Teller method. The study allowed us to correlate the processing conditions and ditopic linker dimension to the network surface area. Both Gd-MOF and Eu-doped Gd-MOF have been tested for sensing of the inorganic ions such as Fe3+ and Cr2O72−.


2021 ◽  
Author(s):  
Hexiang Li ◽  
Fawei Zhu ◽  
Jun Xiang ◽  
Fangbin Wang ◽  
Qi Liu ◽  
...  

We herein report a facile and scalable strategy for fabrication of the metal organic frameworks (MOFs) based composite by in-situ growing ZIF-8 on the gold nanoparticles (AuNPs) loaded magnetic carbon...


The Analyst ◽  
2018 ◽  
Vol 143 (18) ◽  
pp. 4221-4229 ◽  
Author(s):  
Qi Zhang ◽  
Chen-Feng Wang ◽  
Yun-Kai Lv

The applications of MOFs-based luminescent sensors for biomolecules sensing via a “turn on” or “turn off” response have been reviewed.


CrystEngComm ◽  
2021 ◽  
Author(s):  
Jiaqi Wang ◽  
Yiling Quan ◽  
Guoxiang Wang ◽  
Dazhi Wang ◽  
Jie Xiao ◽  
...  

Metal–organic frameworks (MOFs) attracted considerable attention through their large specific surface area and excellent adjustable voids. A one-step solvothermal method is proposed herein to fabricate the 3D hollow cage copper-cobalt...


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