scholarly journals Smart polymer inverse-opal photonic crystal films by melt-shear organization for hybrid core–shell architectures

2015 ◽  
Vol 3 (10) ◽  
pp. 2204-2214 ◽  
Author(s):  
C. G. Schäfer ◽  
T. Winter ◽  
S. Heidt ◽  
C. Dietz ◽  
T. Ding ◽  
...  
Keyword(s):  
Optical Properties ◽  
Photonic Crystal ◽  
Core Shell ◽  
Inverse Opal ◽  
Stimuli Responsive ◽  
Large Area ◽  
Smart Polymer ◽  
Stimuli Responsive Polymers ◽  
Responsive Polymers ◽  
Crystal Films

Large-area inverse opal structures based on stimuli-responsive polymers with reversibly switchable and distinct optical properties are prepared by melt-shear organization.

Amino-functional polyethers: versatile, stimuli-responsive polymers

2020 ◽  
Vol 11 (24) ◽  
pp. 3940-3950 ◽  
Author(s):  
Patrick Verkoyen ◽  
Holger Frey
Keyword(s):  
Ring Opening ◽  
Review Article ◽  
Stimuli Responsive ◽  
New Class ◽  
Stimuli Responsive Polymers ◽  
Responsive Polymers

Amino-functional polyethers have emerged as a new class of “smart”, i.e. pH- and thermoresponsive materials. This review article summarizes the synthesis and applications of these materials, obtained from ring-opening of suitable epoxide monomers.

Smart Drug Release Systems Based on Stimuli-Responsive Polymers

2013 ◽  
Vol 13 (9) ◽  
pp. 1369-1380 ◽  
Author(s):  
Guangyan Qing ◽  
Minmin Li ◽  
Lijing Deng ◽  
Ziyu Lv ◽  
Peng Ding ◽  
...  
Keyword(s):  
Drug Release ◽  
Stimuli Responsive ◽  
Stimuli Responsive Polymers ◽  
Responsive Polymers ◽  
Smart Drug

scholarly journals Thermo- and Photoresponsive Behaviors of Dual-Stimuli-Responsive Organogels Consisting of Homopolymers of Coumarin-Containing Methacrylate

Polymers ◽  
2021 ◽  
Vol 13 (3) ◽  
pp. 329
Author(s):  
Seidai Okada ◽  
Eriko Sato
Keyword(s):  
Functional Group ◽  
Solution Temperature ◽  
Stimuli Responsive ◽  
Critical Solution Temperature ◽  
Equilibrium Degree ◽  
Stimuli Responsive Polymers ◽  
Responsive Polymers ◽  
Dual Functional ◽  
Wide Range ◽  
Increasing Temperature

Coumarin-containing vinyl homopolymers, such as poly(7-methacryloyloxycoumarin) (P1a) and poly(7-(2′-methacryloyloxyethoxy)coumarin) (P1b), show a lower critical solution temperature (LCST) in chloroform, which can be controlled by the [2 + 2] photochemical cycloaddition of the coumarin moiety, and they are recognized as monofunctional dual-stimuli-responsive polymers. A single functional group of monofunctional dual-stimuli-responsive polymers responds to dual stimuli and can be introduced more uniformly and densely than those of dual-functional dual-stimuli-responsive polymers. In this study, considering a wide range of applications, organogels consisting of P1a and P1b, i.e., P1a-gel and P1b-gel, respectively, were synthesized, and their thermo- and photoresponsive behaviors in chloroform were investigated in detail. P1a-gel and P1b-gel in a swollen state (transparent) exhibited phase separation (turbid) through a temperature jump and reached a shrunken state (transparent), i.e., an equilibrium state, over time. Moreover, the equilibrium degree of swelling decreased non-linearly with increasing temperature. Furthermore, different thermoresponsive sites were photopatterned on the organogel through the photodimerization of the coumarin unit. The organogels consisting of homopolymers of coumarin-containing methacrylate exhibited unique thermo- and photoresponsivities and behaved as monofunctional dual-stimuli-responsive organogels.

scholarly journals Metal-Organic Framework-Based Stimuli-Responsive Polymers

2021 ◽  
Vol 5 (4) ◽  
pp. 101
Author(s):  
Menglian Wei ◽  
Yu Wan ◽  
Xueji Zhang
Keyword(s):  
Metal Organic Framework ◽  
Chemical Properties ◽  
Stimuli Responsive ◽  
Guest Molecules ◽  
Stimuli Responsive Polymers ◽  
Responsive Polymers ◽  
Reversible Phase Transition ◽  
Metal Organic ◽  
External Stimuli ◽  
Organic Framework

Metal-organic framework (MOF) based stimuli-responsive polymers (coordination polymers) exhibit reversible phase-transition behavior and demonstrate attractive properties that are capable of altering physical and/or chemical properties upon exposure to external stimuli, including pH, temperature, ions, etc., in a dynamic fashion. Thus, their conformational change can be imitated by the adsorption/desorption of target analytes (guest molecules), temperature or pressure changes, and electromagnetic field manipulation. MOF-based stimuli responsive polymers have received great attention due to their advanced optical properties and variety of applications. Herein, we summarized some recent progress on MOF-based stimuli-responsive polymers (SRPs) classified by physical and chemical responsiveness, including temperature, pressure, electricity, pH, metal ions, gases, alcohol and multi-targets.

Chemically Responsive Polymer Inverse-Opal Photonic Crystal Films Created by a Self-Assembly Method

2016 ◽  
Vol 120 (22) ◽  
pp. 11938-11946 ◽  
Author(s):  
Huilin Zhao ◽  
Jianping Gao ◽  
Zeng Pan ◽  
Guanbo Huang ◽  
Xiaoyang Xu ◽  
...  
Keyword(s):  
Photonic Crystal ◽  
Self Assembly ◽  
Inverse Opal ◽  
Assembly Method ◽  
Responsive Polymer ◽  
Crystal Films

Stimuli-Responsive Polymers for Soft Robotics

2021 ◽  
Vol 5 (1) ◽  
Author(s):  
Yusen Zhao ◽  
Mutian Hua ◽  
Yichen Yan ◽  
Shuwang Wu ◽  
Yousif Alsaid ◽  
...  
Keyword(s):  
Autonomous Systems ◽  
Soft Robotics ◽  
Annual Review ◽  
Liquid Crystal Polymers ◽  
Publication Date ◽  
Stimuli Responsive ◽  
Stimuli Responsive Polymers ◽  
Responsive Polymers ◽  
Evaluation Of Performance ◽  
Robotic Applications

This article reviews recent progress in the use of stimuli-responsive polymers for soft robotics. First, we introduce different types of representative stimuli-responsive polymers, which include liquid crystal polymers and elastomers, hydrogels, shape memory polymers, magnetic elastomers, electroactive polymers, and thermal expansion actuators. We focus on the mechanisms of actuation and the evaluation of performance and discuss strategies for improvements. We then present examples of soft robotic applications based on stimuli-responsive polymers for bending, grasping, walking, swimming, flying, and sensing control. Finally, we discuss current opportunities and challenges of stimuli-responsive soft robots for future study. Expected final online publication date for the Annual Review of Control, Robotics, and Autonomous Systems, Volume 5 is May 2022. Please see http://www.annualreviews.org/page/journal/pubdates for revised estimates.

Flexible construction of cellulose photonic crystal optical sensing nano-materials detecting organic solvents

The Analyst ◽  
2019 ◽  
Vol 144 (6) ◽  
pp. 1892-1897 ◽  
Author(s):  
Dan Yan ◽  
Renbin Li ◽  
Wei Lu ◽  
Chunmei Piao ◽  
Lili Qiu ◽  
...  
Keyword(s):  
Photonic Crystal ◽  
Polymethyl Methacrylate ◽  
Organic Solvents ◽  
Efficient Method ◽  
Carboxymethyl Cellulose ◽  
Optical Sensing ◽  
Inverse Opal ◽  
Nano Materials ◽  
Crystal Films ◽  
Colloidal Arrays

We developed a simple and efficient method to construct 3D and 2D opal and inverse opal cellulose photonic crystal films (CPCF) by embedding 3D or 2D polymethyl methacrylate (PMMA) colloidal arrays into carboxymethyl cellulose (CMC), respectively.

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