Controlled emission colors and singlet–triplet energy gaps of dihydrophenazine-based thermally activated delayed fluorescence emitters

2015 ◽  
Vol 3 (10) ◽  
pp. 2175-2181 ◽  
Author(s):  
Jiyoung Lee ◽  
Katsuyuki Shizu ◽  
Hiroyuki Tanaka ◽  
Hajime Nakanotani ◽  
Takuma Yasuda ◽  
...  
Keyword(s):  
Delayed Fluorescence ◽  
Triplet Energy ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Energy Gaps

We have developed thermally activated delayed fluorescence emitters with wide ranges of emission colors and singlet–triplet energy gaps.

Why Triage the Materials with Low Luminescence Quantum Efficiency: The Use of 35Cbz4BzCN as a Universal Host for Organic Light Emitting Diode through Effective Triplet Energy Transfer

2021 ◽  
Author(s):  
Yi-Mei Huang ◽  
Tse-Ying Chen ◽  
Deng-Gao Chen ◽  
Hsuan-Chi Liang ◽  
Cheng-Ham Wu ◽  
...  
Keyword(s):  
Light Emitting Diode ◽  
Delayed Fluorescence ◽  
Triplet Energy ◽  
Thermally Activated Delayed Fluorescence ◽  
Light Emitting ◽  
Organic Light Emitting Diode ◽  
Thermally Activated ◽  
Triplet Energy Transfer ◽  
Triplet Lifetime ◽  
Triplet Excitons

35Cbz4BzCN, a novel universal host with long triplet lifetime, has been developed. The triplet excitons in 35Cbz4BzCN can be effectively harvested by phosphorescence and thermally activated delayed fluorescence emitters. In...

Lowest unoccupied molecular orbital managing function of CN-substituted dibenzofuran in high triplet energy hosts for blue thermally-activated delayed fluorescent organic light-emitting diodes

2021 ◽  
Author(s):  
Sung Yong Byun ◽  
Kyung Hyung Lee ◽  
Jun Yeob Lee
Keyword(s):  
Molecular Orbital ◽  
Light Emitting Diodes ◽  
Delayed Fluorescence ◽  
Organic Light Emitting Diodes ◽  
Triplet Energy ◽  
Thermally Activated Delayed Fluorescence ◽  
Light Emitting ◽  
Thermally Activated ◽  
Organic Light ◽  
Lowest Unoccupied Molecular Orbital

The effect of lowest unoccupied molecular orbital (LUMO) management of high triplet energy electron transport type hosts on the device performance of blue thermally-activated delayed fluorescence (TADF) organic light-emitting diodes...

Controlling the exciton lifetime of blue thermally activated delayed fluorescence emitters using a heteroatom-containing pyridoindole donor moiety

2017 ◽  
Vol 4 (4) ◽  
pp. 619-624 ◽  
Author(s):  
Gyeong Heon Kim ◽  
Raju Lampande ◽  
Joon Beom Im ◽  
Jung Min Lee ◽  
Ju Young Lee ◽  
...  
Keyword(s):  
Molecular Design ◽  
Delayed Fluorescence ◽  
Energy Splitting ◽  
Triplet Energy ◽  
High Quantum Efficiency ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Exciton Lifetime ◽  
Low Efficiency ◽  
Donor Moiety

We demonstrate a promising molecular design approach to achieve short exciton lifetime, small singlet and triplet energy splitting and high photoluminescence quantum yield in thermally activated delayed fluorescence emitters for high quantum efficiency and low efficiency roll-off characteristics in OLEDs.

scholarly journals A Novel Design Strategy for Suppressing Efficiency Roll-Off of Blue Thermally Activated Delayed Fluorescence Molecules through Donor–Acceptor Interlocking by C–C Bonds

Nanomaterials ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 1735 ◽  
Author(s):  
Tae Hui Kwon ◽  
Soon Ok Jeon ◽  
Masaki Numata ◽  
Hasup Lee ◽  
Yeon Sook Chung ◽  
...  
Keyword(s):  
Energy Gap ◽  
Delayed Fluorescence ◽  
Triplet Energy ◽  
Design Synthesis ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Donor And Acceptor ◽  
Donor Acceptor ◽  
Display Performance ◽  
Commercial Applications

The short material lifetime of thermally activated delayed fluorescence (TADF) technology is a major obstacle to the development of economically feasible, highly efficient, and durable devices for commercial applications. TADF devices are also hampered by insufficient operational stability. In this paper, we report the design, synthesis, and evaluation of new TADF molecules possessing a sterically twisted skeleton by interlocking donor and acceptor moieties through a C–C bond. Compared to C–N-bond TADF molecules, such as CPT2, the C–C-bond TADF molecules showed a large dihedral angle increase by more than 30 times and a singlet–triplet energy-gap decrease to less than 0.22 eV because of the steric hindrance caused by the direct C–C bond connection. With the introduction of a dibenzofuran core structure, devices comprising BMK-T317 and BMK-T318 exhibited a magnificent display performance, especially their external quantum efficiencies, which were as high as 19.9% and 18.8%, respectively. Moreover, the efficiency roll-off of BMK-T318 improved significantly (26.7%). These results indicate that stability of the material can be expected through the reduction of their singlet–triplet splitting and the precise adjustment of dihedral angles between the donor–acceptor skeletons.

Overcome energy loss of thermally activated delayed fluorescence sensitized-OLEDs by developing fluorescence dopant with a small singlet-triplet energy splitting

2022 ◽  
Author(s):  
XinYe Wang ◽  
YiFan Zhang ◽  
Ze Yu ◽  
Yuan Wu ◽  
Dongdong Wang ◽  
...  
Keyword(s):  
Energy Loss ◽  
State Energy ◽  
Radiative Transition ◽  
Delayed Fluorescence ◽  
Energy Splitting ◽  
Triplet Energy ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated

TADF-sensitizing-fluorescence (TSF) strategy suffered a disturbing energy loss causing by the T1 states of fluorescence dopant (FD) due to its low T1-state energy and forbidden of radiative transition. We supposed...

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