Structure and photoluminescence properties of novel Ca2NaSiO4F:Re (Re = Eu2+, Ce3+, Tb3+) phosphors with energy transfer for white emitting LEDs

2014 ◽  
Vol 2 (21) ◽  
pp. 4304-4311 ◽  
Author(s):  
Mengmeng Jiao ◽  
Yongchao Jia ◽  
Wei Lü ◽  
Wenzhen Lv ◽  
Qi Zhao ◽  
...  

The Eu2+, Ce3+ and Tb3+ doped Ca2NaSiO4F phosphors were prepared, and their luminescence properties have been investigated systematically.

RSC Advances ◽  
2016 ◽  
Vol 6 (37) ◽  
pp. 30886-30894 ◽  
Author(s):  
Yang Zhang ◽  
Weitao Gong ◽  
Jingjie Yu ◽  
Zhiyuan Cheng ◽  
Guiling Ning

A series of host-sensitized and color-tunable CaWO4:Tb3+,Eu3+phosphors have been successfully synthesizedviathe high-temperature solid-state reaction route and their photoluminescence properties and energy transfer mechanism have been carefully investigated.


2021 ◽  
pp. 118082
Author(s):  
Hai Ma ◽  
Xiaodan Wang ◽  
Feifei Chen ◽  
Jiafan Chen ◽  
Xionghui Zeng ◽  
...  

Optik ◽  
2021 ◽  
Vol 238 ◽  
pp. 166774
Author(s):  
Huan Duan ◽  
Ruirui Cui ◽  
Min Zhang ◽  
Chaoyong Deng

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2753
Author(s):  
Bartosz Fetliński ◽  
Sebastian Turczyński ◽  
Michał Malinowski ◽  
Paweł Szczepański

In this work, we investigate Ce3+ to Yb3+ energy transfer in Y4Al2O9 (YAM) for potential application in solar spectrum down-converting layers for photovoltaic devices. Photoluminescence properties set, of 10 samples, of the YAM host activated with Ce3+ and Yb3+ with varying concentrations are presented, and the Ce3+ to Yb3+ energy transfer is proven. Measurement of highly non-exponential luminescence decays of Ce3+ 5d band allowed for the calculation of maximal theoretical quantum efficiency, of the expected down-conversion process, equal to 123%. Measurements of Yb3+ emission intensity, in the function of excitation power, confirmed the predominantly single-photon downshifting character of Ce3+ to Yb3+ energy transfer. Favorable location of the Ce3+ 5d bands in YAM makes this system a great candidate for down-converting, and down-shifting, luminescent layers for photovoltaics.


2008 ◽  
Vol 2008 ◽  
pp. 1-6 ◽  
Author(s):  
Stefan Lis ◽  
Krzysztof Staninski ◽  
Tomasz Grzyb

The europium (III) complex of coumarin-3-carboxylic acid (C3CA) has been prepared and characterized on the basis of elemental analysis, IR, and emission (photoluminescence and electrochemiluminescence) spectroscopy. The synthesised complex having a formula Eu was photophysically characterized in solution and in the solid state. Electrochemiluminescence, ECL, of the system containing the Eu(III)/C3CA complex was studied using an oxide-covered aluminium electrode. The goal of these studies was to show the possibility of the use of electrochemical excitation of the Eu(III) ion in aqueous solution for emission generation. The generated ECL emission was very weak, and therefore its measurements and spectral analysis were carried out with the use of cut-off filters method. The studies proved a predominate role of the ligand-to-metal energy transfer (LMET) in the generated ECL.


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