Multifunctional water-soluble luminescent carbon dots for imaging and Hg2+ sensing

2014 ◽  
Vol 2 (40) ◽  
pp. 6995-6999 ◽  
Author(s):  
Yanling Zhai ◽  
Zhijun Zhu ◽  
Chengzhou Zhu ◽  
Jiangtao Ren ◽  
Erkang Wang ◽  
...  

We propose an ingenious method for large-scale fabrication of water-soluble photoluminescent carbon dots (CDs) by a one-step microwave route in the presence of citric acid and ethylenediamine.

2016 ◽  
Vol 18 (1) ◽  
pp. 243-250 ◽  
Author(s):  
Jeremy B. Essner ◽  
Charles H. Laber ◽  
Sudhir Ravula ◽  
Luis Polo-Parada ◽  
Gary A. Baker

We have demonstrated an easy, economic, one-step synthetic route to water-soluble fluorescent carbon dots derived from the thermal upcycling of urine.


RSC Advances ◽  
2015 ◽  
Vol 5 (115) ◽  
pp. 95054-95060 ◽  
Author(s):  
Qingyan Zhang ◽  
Caihong Zhang ◽  
Zengbo Li ◽  
Jinyin Ge ◽  
Chenzhong Li ◽  
...  

A facile, economical and green one-step hydrothermal method for N-doped CDs was presented by using citric acid as carbon source and urea as nitrogen source. The fluorescence of N-doped CDs quenched dramatically from curcumin via inner filter effect.


RSC Advances ◽  
2018 ◽  
Vol 8 (36) ◽  
pp. 20016-20024 ◽  
Author(s):  
Chunjin Wei ◽  
Jun Li ◽  
Xincai Xiao ◽  
Tong Yue ◽  
Dan Zhao

This paper reports the synthesis of high-quality green-emission carbon dots based on the synergistic effect between the deactivator (polyethyleneimine) and the reducing reagent (citric acid).


2021 ◽  
Author(s):  
Shuang Liu ◽  
Yu He ◽  
Yu Liu ◽  
Shuaibin Wang ◽  
Yajun Jian ◽  
...  

Chiral carbon dots is prepared by a simple and one-step hydrothermal reaction at 180 °C for 2 h using citric acid and D-proline as precursors, which show high asymmetric catalytic...


2014 ◽  
Vol 38 (3) ◽  
pp. 906 ◽  
Author(s):  
Jumeng Wei ◽  
Xin Zhang ◽  
Yingzhuo Sheng ◽  
Jianmin Shen ◽  
Peng Huang ◽  
...  

RSC Advances ◽  
2019 ◽  
Vol 9 (15) ◽  
pp. 8290-8299 ◽  
Author(s):  
Dandan Xu ◽  
Fang Lei ◽  
Haohong Chen ◽  
Luqiao Yin ◽  
Ying Shi ◽  
...  

Blue CDs with a quantum yield of 30.21% were successfully synthesized by a simple one-pot hydrothermal treatment using citric acid (carbon source) and polyvinyl pyrrolidone (nitrogen source) as the raw materials towards fluorescent ink and as nanosensors for Fe3+ detection.


Author(s):  
Mai Xuan Dung ◽  
Mai Van Tuan ◽  
Pham Truong Long ◽  
Nguyen Thi Mai

Water-soluble, biocompatible, and highly luminescence carbon quantum dots (CQDs) have synthesized successfully from a citric acid (CA) and ethylenediamine (EDA) by using different approaches. Although the emission quantum yield of CQDs could be as high as 80% their emission spectrum is usually dominated by surface fluorophore groups and maximized at about 450 nm. Herein, we examined the effects of acid and amine precursors on the photoluminescence (PL) of resulting CQDs by systematic comparison the optical properties of CQDs obtained from CA, PA (phthalic acid) and EDA, ANL (aniline). UV-vis and PL spectroscopic studies revealed that the absorption onset varied from 325 nm to 400 nm while PL maximum changed from 390 nm to 450 nm by engineering acid and amine precursors. The emission quantum yield was also changed from 9 to 70%, depending on the used acid-amine precursors.  Keywords Carbon quantum dots, hydrothermal synthesis, color tuning, photoluminescence, acid, amine References K. Wang, Z. Gao, G. Gao, Y. Wo, Y. Wang, G. Shen, D. Cui, Systematic safety evaluation on photoluminescent carbon dots, Nanoscale Res. Lett. 8 (2013) 1–9. doi:10.1186/1556-276X-8-122.[2] K. Jiang, S. Sun, L. Zhang, Y. Lu, A. Wu, C. Cai, H. Lin, Red, Green, and Blue Luminescence by Carbon Dots: Full-Color Emission Tuning and Multicolor Cellular Imaging, Angew. Chemie Int. Ed. 54 (2015) 5360–5363. doi:10.1002/anie.201501193.[3] M.X. Dung, P. Mohapatra, J.K. Choi, J.H. Kim, S. Jeong, H.D. Jeong, InP quantum dot-organosilicon nanocomposites, Bull. Korean Chem. Soc. 33 (2012) 1491–1504. doi:10.5012/bkcs.2012.33.5.1491.[4] X. Mai, Q. Hoang, The Large-Scale Synthesis of Vinyl-Functionalized Silicon Quantum Dot and Its Application in Miniemulsion Polymerization, J. Nanomater. 2016 (2016).[5] M.X. Dung, D.D. Tung, S. Jeong, H.D. Jeong, Tuning optical properties of Si quantum dots by ??-conjugated capping molecules, Chem. - An Asian J. 8 (2013) 653–664. doi:10.1002/asia.201201099.[6] M.X. Dung, H.D. Jeong, Synthesis of styryl-terminated silicon quantum dots: Reconsidering the use of methanol, Bull. Korean Chem. Soc. 33 (2012) 4185–4187.doi:10.5012/bkcs.2012.33.12.4185.[7] V.-T. Mai, N.H. Duong, X.-D. Mai, Surface Polarity Controls the Optical Properties of One-Pot Synthesized Silicon Quantum Dots, Chem. Phys. (2018).doi:10.1016/j.chemphys.2018.11.012.[8] V.-T. Mai, Q. Hoang, X. Mai, Enhanced Red Emission in Ultrasound-Assisted Sol-Gel Derived ZnO/PMMA Nanocomposite, Adv. Mater. Sci. Eng. 2018 (2018) 1–8. doi:10.1155/2018/7252809.[9] J. Schneider, C.J. Reckmeier, Y. Xiong, M. Von Seckendorff, A.S. Susha, P. Kasak, A.L. Rogach, Molecular fluorescence in citric acid-based carbon dots, J. Phys. Chem. C. 121 (2017) 2014–2022. doi:10.1021/acs.jpcc.6b12519.[10] F. Ehrat, S. Bhattacharyya, J. Schneider, A. Löf, R. Wyrwich, A.L. Rogach, J.K. Stolarczyk, A.S. Urban, J. Feldmann, Tracking the Source of Carbon Dot Photoluminescence: Aromatic Domains versus Molecular Fluorophores, Nano Lett. 17 (2017) 7710–7716. doi:10.1021/acs.nanolett.7b03863.[11] M. Shamsipur, A. Barati, A.A. Taherpour, M. Jamshidi, Resolving the Multiple Emission Centers in Carbon Dots: From Fluorophore Molecular States to Aromatic Domain States and Carbon-Core States, J. Phys. Chem. Lett. 9 (2018) 4189–4198. doi:10.1021/acs.jpclett.8b02043.[12] T.H.T. Xuan-Dung Mai, Quang-Bac Hoang, Hong Quan To, Phuong Le Thi, The synthesis of highly luminescent carbon quantum dots, (2017) (47)20-26.[13] M.X.D. Lê Thị Phượng, Lê Quang Trung, Đỗ Thị Thu Hòa, Doãn Diệu Thúy, Ảnh hưởng của tỷ lệ Acid/Amine đến cấu trúc bề mặt và hiệu suất phát xạ của chấm lượng tử carbon, (2018) (55) 67-74.[14] M.V.T. Hoàng Quang Bắc, Trần Thu Hương, Đinh Thị Châm, Nguyễn Thị Loan, Nguyễn Thị Quỳnh, Bùi Thị Huệ, Lê Thị Thùy Hương, Mai Xuân Dũng, Nghiên cứu tổng hợp hạt nano huỳnh quang từ một số rau củ quả, (2017) 4(40), 70-73.[15] Y. Song, S. Zhu, S. Zhang, Y. Fu, L. Wang, X. Zhao, B. Yang, Investigation from chemical structure to photoluminescent mechanism: a type of carbon dots from the pyrolysis of citric acid and an amine, J. Mater. Chem. C. 3 (2015) 5976–5984. doi:10.1039/C5TC00813A.[16] T.H. Ngà, B.T. Hạnh, M.X. Dũng, Tính toán lượng tử làm rõ tính chất quang học của chấm lượng tử carbon, Tạp Chí KHoa Học - Đại Học Sư Phạm Hà Nội 2. 56 (2018).[17] S. Zhu, Q. Meng, L. Wang, J. Zhang, Y. Song, H. Jin, K. Zhang, H. Sun, H. Wang, B. Yang, Highly photoluminescent carbon dots for multicolor patterning, sensors, and bioimaging, Angew. Chemie - Int. Ed. 52 (2013) 3953–3957. doi:10.1002/anie.201300519.[18] Q.-B. Hoang, V.-T. Mai, D.-K. Nguyen, D.Q. Truong, X.-D. Mai, Crosslinking induced photoluminescence quenching in polyvinyl alcohol-carbon quantum dot composite, Mater. Today Chem. 12 (2019) 166–172. doi:10.1016/j.mtchem.2019.01.003.


Sign in / Sign up

Export Citation Format

Share Document