Hierarchically micro/mesoporous activated graphene with a large surface area for high sulfur loading in Li–S batteries

2015 ◽  
Vol 3 (9) ◽  
pp. 4799-4802 ◽  
Author(s):  
Ya You ◽  
Wencong Zeng ◽  
Ya-Xia Yin ◽  
Juan Zhang ◽  
Chun-Peng Yang ◽  
...  
Keyword(s):  
Surface Area ◽  
Pore Volume ◽  
High Surface ◽  
High Surface Area ◽  
Large Surface Area ◽  
Carbon Substrate ◽  
High Sulfur Loading

A hierarchically micro/mesoporous a-MEGO with a high surface area and pore volume was fabricated as a superior carbon substrate in Li–S batteries.

Morphology dependent adsorption of methylene blue on trititanate nanoplates and nanotubes prepared by the hydrothermal treatment of TiO2

2016 ◽  
Vol 75 (2) ◽  
pp. 350-357
Author(s):  
Graham Dawson ◽  
Wei Chen ◽  
Luhua Lu ◽  
Kai Dai
Keyword(s):  
Methylene Blue ◽  
Adsorption Capacity ◽  
Surface Area ◽  
Pore Volume ◽  
Hydrothermal Reaction ◽  
Low Cost ◽  
High Surface ◽  
High Surface Area ◽  
High Capacity ◽  
Adsorption Properties

The adsorption properties of two nanomorphologies of trititanate, nanotubes (TiNT) and plates (TiNP), prepared by the hydrothermal reaction of concentrated NaOH with different phases of TiO2, were examined. It was found that the capacity for both morphologies towards methylene blue (MB), an ideal pollutant, was extremely high, with the TiNP having a capacity of 130 mg/g, higher than the TiNT, whose capacity was 120 mg/g at 10 mg/L MB concentration. At capacity, the well-dispersed powders deposit on the floor of the reaction vessel. The two morphologies had very different structural and adsorption properties. TiNT with high surface area and pore volume exhibited exothermic monolayer adsorption of MB. TiNP with low surface area and pore volume yielded a higher adsorption capacity through endothermic multilayer adsorption governed by pore diffusion. TiNP exhibited a higher negative surface charge of −23 mV, compared to −12 mV for TiNT. The adsorption process appears to be an electrostatic interaction, with the cationic dye attracted more strongly to the nanoplates, resulting in a higher adsorption capacity and different adsorption modes. We believe this simple, low cost production of high capacity nanostructured adsorbent material has potential uses in wastewater treatment.

scholarly journals Ultra-high surface area mesoporous carbons for colossal pre combustion CO2 capture and storage as materials for hydrogen purification

2017 ◽  
Vol 1 (6) ◽  
pp. 1414-1424 ◽  
Author(s):  
Michael Cox ◽  
Robert Mokaya
Keyword(s):  
Surface Area ◽  
Co2 Capture ◽  
Pore Volume ◽  
High Surface ◽  
High Surface Area ◽  
Hydrogen Purification ◽  
Mesoporous Carbons ◽  
Co2 Capture And Storage ◽  
And Storage

Mesoporous carbons (with up to 95% of pore volume from mesopores) with surface area and pore volume of ∼4000 m2 g−1 and ∼3.6 cm3 g−1, respectively, are excellent CO2 absorbers under pre combustion conditions and can store 55 mmol g−1 (i.e., 2.42 g g−1) or 930 g l−1 at 25 °C and 50 bar.

Effect of Activating Agent on the Preparation of Bamboo-Based High Surface Area Activated Carbon by Microwave Heating

2016 ◽  
Vol 35 (6) ◽  
pp. 535-541 ◽  
Author(s):  
Hongying Xia ◽  
Jian Wu ◽  
Chandrasekar Srinivasakannan ◽  
Jinhui Peng ◽  
Libo Zhang
Keyword(s):  
Activated Carbon ◽  
Microwave Heating ◽  
Surface Area ◽  
Pore Volume ◽  
Activated Carbons ◽  
High Surface ◽  
High Surface Area ◽  
Significant Proportion ◽  
Mixture Ratio ◽  
Activating Agent

AbstractThe present work attempts to convert bamboo into a high surface area activated carbon via microwave heating. Different chemical activating agents such as KOH, NaOH, K2CO3 and Na2CO3 were utilized to identify a most suitable activating agent. Among the activating agents tested KOH was found to generate carbon with the highest porosity and surface area. The effect of KOH/C ratio on the porous nature of the activated carbon has been assessed. An optimal KOH/C ratio of 4 was identified, beyond which the surface area as well as the pore volume were found to decrease. At the optimized KOH/C ratio the surface area and the pore volume were estimated to be 3,441 m2/g and 2.093 ml/g, respectively, with the significant proportion of which being microporous (62.3%). Activated carbon prepared under the optimum conditions was further characterized using Fourier transform infrared spectroscopy (FTIR) and scanning electron microscope (SEM). Activated carbons with so high surface area and pore volume are very rarely reported, which could be owed to the nature of the precursor and the optimal conditions of mixture ratio adopted in the present work.

Three-Dimensional Cage Type Mesoporous CN-Based Hybrid Material with Very High Surface Area and Pore Volume

2007 ◽  
Vol 19 (17) ◽  
pp. 4367-4372 ◽  
Author(s):  
Ajayan Vinu ◽  
Pavuluri Srinivasu ◽  
Dhanashri P. Sawant ◽  
Toshiyuki Mori ◽  
Katsuhiko Ariga ◽  
...  
Keyword(s):  
Surface Area ◽  
Hybrid Material ◽  
Pore Volume ◽  
High Surface ◽  
High Surface Area ◽  
Three Dimensional ◽  
Very High

An approach to carbon nanotubes with high surface area and large pore volume

2007 ◽  
Vol 100 (1-3) ◽  
pp. 1-5 ◽  
Author(s):  
Jun Jie Niu ◽  
Jian Nong Wang ◽  
Ying Jiang ◽  
Lian Feng Su ◽  
Jie Ma
Keyword(s):  
Carbon Nanotubes ◽  
Surface Area ◽  
Pore Volume ◽  
High Surface ◽  
High Surface Area ◽  
Large Pore ◽  
Large Pore Volume

Hierarchically Porous Graphitic Carbon with Simultaneously High Surface Area and Colossal Pore Volume Engineered via Ice Templating

ACS Nano ◽  
2017 ◽  
Vol 11 (11) ◽  
pp. 11047-11055 ◽  
Author(s):  
Luis Estevez ◽  
Venkateshkumar Prabhakaran ◽  
Adam L. Garcia ◽  
Yongsoon Shin ◽  
Jinhui Tao ◽  
...  
Keyword(s):  
Surface Area ◽  
Pore Volume ◽  
High Surface ◽  
High Surface Area ◽  
Porous Graphitic Carbon ◽  
Graphitic Carbon ◽  
Hierarchically Porous ◽  
Ice Templating

Cellulose generated-microporous carbon nanosheets with nitrogen doping

RSC Advances ◽  
2014 ◽  
Vol 4 (18) ◽  
pp. 9126-9132 ◽  
Author(s):  
Wenzhong Shen ◽  
Tuoping Hu ◽  
Weibin Fan
Keyword(s):  
Surface Area ◽  
Porous Carbon ◽  
Pore Volume ◽  
Nitrogen Doping ◽  
High Surface ◽  
High Surface Area ◽  
Structural Features ◽  
Carbon Nanosheets ◽  
Nitrogen Doped ◽  
Adsorption Performance

Nanosheet porous carbon with high surface area and pore volume, unique compositional and structural features endow the nitrogen-doped porous carbon nanosheets with superior CO2 adsorption performance.

scholarly journals A facile, green and efficient surfactant-free method for synthesis of aluminum nanooxides with an extraordinary high surface area

2016 ◽  
Vol 45 (15) ◽  
pp. 6329-6333 ◽  
Author(s):  
Gholamhossein Mohammadnezhad ◽  
Oluseun Akintola ◽  
Winfried Plass ◽  
Frank Steiniger ◽  
Martin Westermann
Keyword(s):  
Surface Area ◽  
Pore Volume ◽  
High Surface ◽  
High Surface Area ◽  
Synthesis Method

Nano boehmite with unprecedented high surface area and pore volume (802 m2 g−1, 2.35 cm3 g−1) was prepared using a facile, green and efficient surfactant-free synthesis method.

Novel Preparation of Nano-Sized TiO2 and ZrO2 Particles by Nanocasting with Nanoporous SiO2 and Selective Dissolution

2007 ◽  
Vol 124-126 ◽  
pp. 643-646
Author(s):  
Jun Lee ◽  
Yoshihiro Sugi ◽  
Nam Jo Jeong ◽  
Gon Seo ◽  
Sung June Cho
Keyword(s):  
Metal Oxides ◽  
Surface Area ◽  
Pore Volume ◽  
High Surface ◽  
High Surface Area ◽  
Selective Dissolution ◽  
Metal Alkoxides ◽  
Nanocrystalline Metal

High surface area and uniform nano-sized TiO2 and ZrO2 were prepared readily by the infiltration of metal alkoxides into the nanoporous SiO2, SBA-15 and the following selective dissolution of SiO2. The obtained particles of TiO2 and ZrO2, 8.1 nm were nanocrystalline of which the structure were anatase and tetragonal, respectively. The surface area and pore volume of the nanocrystalline metal oxides can be increased to above 200 m2g-1 and 0.30 cm3g-1, respectively.

A novel mesoporous hydrogen-bonded organic framework with high porosity and stability

2020 ◽  
Vol 56 (1) ◽  
pp. 66-69 ◽  
Author(s):  
Bin Wang ◽  
Xiu-Liang Lv ◽  
Jie Lv ◽  
Li Ma ◽  
Rui-Biao Lin ◽  
...  
Keyword(s):  
Surface Area ◽  
Pore Volume ◽  
High Surface ◽  
High Surface Area ◽  
High Porosity ◽  
Thermally Stable ◽  
Large Pore ◽  
Large Pore Volume ◽  
Organic Framework ◽  
Hydrogen Bonded

A highly chemically and thermally stable mesoporous hydrogen-bonded organic framework with a high surface area and a large pore volume has been rationally designed and constructed.

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