The unique synthesis and energetic properties of a novel fused heterocycle: 7-nitro-4-oxo-4,8-dihydro-[1,2,4]triazolo[5,1-d][1,2,3,5]tetrazine 2-oxide and its energetic salts

2015 ◽  
Vol 3 (7) ◽  
pp. 3594-3601 ◽  
Author(s):  
Chengming Bian ◽  
Xiao Dong ◽  
Xiuhui Zhang ◽  
Zhiming Zhou ◽  
Man Zhang ◽  
...  

The unique and facile synthesis of 7-nitro-4-oxo-4,8-dihydro-[1,2,4]triazolo[5,1-d][1,2,3,5]tetrazine 2-oxide (HBCM) and a proposed mechanism for its formation are described.

2015 ◽  
Vol 39 (7) ◽  
pp. 5265-5271 ◽  
Author(s):  
Jin-Ting Wu ◽  
Jian-Guo Zhang ◽  
Xin Yin ◽  
Zi-Yuan Cheng ◽  
Cai-Xia Xu

A series of energetic salts based on 3,4-diamino-1,2,4-triazole with promising detonation performances have been synthesized using a metathesis reaction method or a protonation reaction method.


CrystEngComm ◽  
2020 ◽  
Vol 22 (29) ◽  
pp. 4842-4852 ◽  
Author(s):  
Ramling S. Mathpati ◽  
Srinivas Dharavath ◽  
Nikhil Kumar ◽  
Vikas D. Ghule ◽  
Avijit Kumar Paul ◽  
...  

Eight energetic salts combining N-bases with picrate ion were synthesized in high yields. The structures and energetic properties were regulated by the variation of N-base molecules and the concentration of the picric acid in the reaction mixture.


2020 ◽  
Vol 49 (2) ◽  
pp. 368-374 ◽  
Author(s):  
Chengming Bian ◽  
Wenjing Feng ◽  
Qunying Lei ◽  
Haifeng Huang ◽  
Xia Li ◽  
...  

Promising high-energy-density materials: energetic salts based on fully nitroamino-functionalized [1,2,4]triazolo[4,3-b][1,2,4]triazole.


RSC Advances ◽  
2019 ◽  
Vol 9 (45) ◽  
pp. 26442-26449 ◽  
Author(s):  
Xiao-Hong Li ◽  
Cong Zhang ◽  
Xue-Hai Ju

We designed four series of energetic anions by replacing nitro group (NO2) with trinitromethyl group (C(NO2)3) or by inserting N-bridging groups (–NH–, –NH–NH–, –NN–, –NN(O)–) into the bistriazole frameworks.


2016 ◽  
Vol 4 (4) ◽  
pp. 1514-1519 ◽  
Author(s):  
Ping Yin ◽  
Chunlin He ◽  
Jean'ne M. Shreeve

Fused heterocycle-based salts consisting of pyrazole and 1,2,3-triazole were synthesized, characterized and their energetic properties were studied.


2018 ◽  
Vol 6 (5) ◽  
pp. 2239-2248 ◽  
Author(s):  
Zhen Xu ◽  
Guangbin Cheng ◽  
Shunguan Zhu ◽  
Qiuhan Lin ◽  
Hongwei Yang

Twenty-one high performance monoanionic and dianionic energetic salts based on the combination of 1,2,4-triazole and 1,2,3-triazole rings were studied.


CrystEngComm ◽  
2019 ◽  
Vol 21 (40) ◽  
pp. 6093-6099 ◽  
Author(s):  
Yang Liu ◽  
Yuangang Xu ◽  
Qi Sun ◽  
Ming Lu

Mononitroamino-diamino and dinitramino-monoamino furazan–triazoles were designed and synthesized by a flexible method and showed excellent stability and high performance, respectively.


2019 ◽  
Vol 14 (8) ◽  
pp. 828-830 ◽  
Author(s):  
Weihua Meng ◽  
Weihong Wu ◽  
Weiwei Zhang ◽  
Luyao Cheng ◽  
Yunhong Jiao ◽  
...  

Synlett ◽  
1991 ◽  
Vol 1991 (09) ◽  
pp. 725-727 ◽  
Author(s):  
Takeshi Shimizu ◽  
Sayoko Hiranuma ◽  
Zhao-hui Qian ◽  
Hirosuke Yoshioka

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