scholarly journals Low cost and environmentally benign crack-blocking structures for long life and high power Si electrodes in lithium ion batteries

2015 ◽  
Vol 3 (5) ◽  
pp. 2036-2042 ◽  
Author(s):  
Min Ling ◽  
Hui Zhao ◽  
Xingcheng Xiaoc ◽  
Feifei Shi ◽  
Mingyan Wu ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
High Power ◽  
Polyacrylic Acid ◽  
Low Cost ◽  
Lithium Ion ◽  
Gum Arabic ◽  
Environmentally Benign ◽  
Composite Binder ◽  
Long Life ◽  
Graphical Illustration

A graphical illustration of the gum arabic (GA) and polyacrylic acid (PAA) composite binder.

Iron Phosphates as Cathodes of Lithium-Ion Batteries

2006 ◽  
Vol 973 ◽  
Author(s):  
Shijun Wang ◽  
M. Stanley Whittingham
Keyword(s):  
Lithium Ion Batteries ◽  
Lithium Iron Phosphate ◽  
Low Cost ◽  
Lithium Ion ◽  
Iron Phosphate ◽  
Environmentally Benign ◽  
Iron Phosphates ◽  
Electrochemical Capacity ◽  
High Theoretical Capacity ◽  
Olivine Structure

ABSTRACTThis study focusses on optimizing the parameters of the hydrothermal synthesis to produce iron phosphates for lithium ion batteries, with an emphasis on pure LiFePO4 with the olivine structure and compounds containing a higher iron:phosphate ratio. Lithium iron phosphate (LiFePO4) is a promising cathode candidate for lithium ion batteries due to its high theoretical capacity, environmentally benign and the low cost of starting materials. Well crystallized LiFePO4 can be successfully synthesized at temperatures above 150 °C. The addition of a reducing agent, such as hydrazine, is essential to minimize the oxidation of ferrous (Fe2+) to ferric (Fe3+) in the final compound. The morphology of LiFePO4 is highly dependent on the pH of the initial solution. This study also investigated the lipscombite iron phosphates of formula Fe1.33PO4OH. This compound has a log-like structure formed by Fe-O octahedral chains. The chains are partially occupied by the Fe3+ sites, and these iron atoms and some of the vacancies can be substituted by other cations. Most of the protons can be ion-exchanged for lithium, and the electrochemical capacity is much increased.

Li4Ti5O12for High-Power, Long-Life, and Safe Lithium-Ion Batteries

2013 ◽  
pp. 277-290
Author(s):  
Zonghai Chen ◽  
I. Belharouak ◽  
Yang-Kook Sun ◽  
Khalil Amine
Keyword(s):  
Lithium Ion Batteries ◽  
High Power ◽  
Lithium Ion ◽  
Long Life

In situ growth of silicon carbide interface enhances the long life and high power of the mulberry-like Si-based anode for lithium-ion batteries

2020 ◽  
Vol 32 ◽  
pp. 101856
Author(s):  
Yuehua Weng ◽  
Guorong Chen ◽  
Fei Dou ◽  
Xianhuan Zhuang ◽  
Qiyu Wang ◽  
...  
Keyword(s):  
Silicon Carbide ◽  
Lithium Ion Batteries ◽  
High Power ◽  
Lithium Ion ◽  
In Situ Growth ◽  
Long Life

scholarly journals A Low-Cost and High-Capacity SiOx/C@graphite Hybrid as an Advanced Anode for High-Power Lithium-Ion Batteries

ACS Omega ◽  
2020 ◽  
Vol 5 (27) ◽  
pp. 16440-16447
Author(s):  
Minghang Xu ◽  
Jiaojiao Ma ◽  
Guiling Niu ◽  
Hongxun Yang ◽  
Mengfei Sun ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
High Power ◽  
Low Cost ◽  
High Capacity ◽  
Lithium Ion

scholarly journals Aqueous Lithium Carboxymethyl Cellulose and Polyacrylic Acid/Acrylate Copolymer Composite Binder for the LiNi0.5Mn0.3Co0.2O2 Cathode of Lithium-Ion Batteries

2022 ◽  
Author(s):  
Yan Cui ◽  
Jiahui Chen ◽  
Jingyang Zhao ◽  
zhen Ma ◽  
Yuming Tan ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Polyacrylic Acid ◽  
Carboxymethyl Cellulose ◽  
Specific Capacity ◽  
Lithium Ion ◽  
Adhesive Force ◽  
Water Soluble ◽  
Retention Capacity ◽  
Composite Binder ◽  
Acrylate Copolymer

Abstract Water-soluble green cathode binders are developed to increase the performance of 18650 type LiNi0.5Mn0.3Co0.2O2 (NMC532) lithium-ion batteries (LIBs). Using four basal substances to prepare the composite binders, it is indicated that the cathode with lithium carboxymethyl cellulose (CMCLi)-polyacrylic acid/acrylate copolymer (type 306F) composite binder (Marked as Binder C) avoids the corrosion of aluminum substrate, and exhibits stronger adhesive force and better electrolyte adsorption capacity compared to other cathodes with PVDF binder and single aqueous binders. In particular, the electrochemical performance of the batteries with Binder C is also improved, initial specific capacity of 161.5 mAh g-1 at 0.2 C and retention capacity of 88.9% at 1 C after 1200 cycles are obtained. The batteries with Binder C also exhibit enhanced high-temperature storage performance, there is 97.9% residual capacity when the fully charged batteries are stored in 60 °C for 14 days. The enhanced performance is mainly attributed to the chemical stability and bonding ability of polyacrylic acid/acrylate copolymer and better conduction at the liquid-solid interface caused by CMCLi. These results indicate that Binder C has promising application prospects in the NMC532 cathode, and also provide a reference for the green production of NMC-based LIBs.

High-power and long-life lithium-ion batteries using lithium titanium oxide anode for automotive and stationary power applications

2013 ◽  
Vol 244 ◽  
pp. 469-475 ◽  
Author(s):  
Norio Takami ◽  
Hiroki Inagaki ◽  
Yoshinao Tatebayashi ◽  
Hidesato Saruwatari ◽  
Keizoh Honda ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Titanium Oxide ◽  
High Power ◽  
Lithium Ion ◽  
Lithium Titanium Oxide ◽  
Long Life ◽  
Lithium Titanium ◽  
Oxide Anode

scholarly journals Physical and chemical dual-confinement of polysulfides within hierarchically meso-microporous nitrogen-doped carbon nanocages for advanced Li–S batteries

RSC Advances ◽  
2017 ◽  
Vol 7 (68) ◽  
pp. 42627-42633 ◽  
Author(s):  
Pan Wu ◽  
Ming-Hui Sun ◽  
Yong Yu ◽  
Zhao Peng ◽  
Shimeles T. Bulbula ◽  
...  
Keyword(s):  
Energy Storage ◽  
Lithium Ion Batteries ◽  
Storage Systems ◽  
Low Cost ◽  
Lithium Ion ◽  
Environmentally Benign ◽  
Nitrogen Doped ◽  
Nitrogen Doped Carbon ◽  
Physical And Chemical ◽  
Lithium Sulfur

Lithium–Sulfur (Li–S) batteries with high theoretical specific energy, environmentally benign and low cost are considered to be one of the most promising next-generation energy-storage systems compared with conventional lithium-ion batteries.

A graphene/PVDF/PP multilayer composite separator for long-life and high power lithium-ion batteries

Carbon ◽  
2017 ◽  
Vol 117 ◽  
pp. 489
Author(s):  
Ai-xiu Bu ◽  
Yong Tan ◽  
Ruo-pian Fang ◽  
Feng Li ◽  
Song-feng Pei ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
High Power ◽  
Lithium Ion ◽  
Multilayer Composite ◽  
Composite Separator ◽  
Long Life

Carbonate coprecipitation preparation of Li-rich layered oxides using the oxalate anion ligand as high-energy, high-power and durable cathode materials for lithium-ion batteries

2015 ◽  
Vol 3 (42) ◽  
pp. 21219-21226 ◽  
Author(s):  
Long Xu ◽  
Peiyu Hou ◽  
Yantao Zhang ◽  
Hongzhou Zhang ◽  
Dawei Song ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
High Power ◽  
Cathode Materials ◽  
Low Cost ◽  
Lithium Ion ◽  
High Energy ◽  
Layered Oxides ◽  
Oxalate Anion ◽  
Highly Efficient

A green, highly efficient and low cost ligand oxalate anion is successfully introduced to prepare spherical precursors for high-energy, high-power and durable cathode materials.

Sign in / Sign up

Export Citation Format

Share Document