Enhanced performance in hybrid perovskite solar cell by modification with spinel lithium titanate

2015 ◽  
Vol 3 (16) ◽  
pp. 8882-8889 ◽  
Author(s):  
Jiangwei Li ◽  
Wenzhe Li ◽  
Haopeng Dong ◽  
Nan Li ◽  
Xudong Guo ◽  
...  

Spinel lithium titanate (LTO) was used as a modification material at the perovskite-sensitized TiO2/HTL interface, acting as a Li+separator to prevent Li+intercalation into TiO2and reducing carrier recombination.

2021 ◽  
Vol 2021 ◽  
pp. 1-12
Author(s):  
Syed Sajjad Hussain ◽  
Saira Riaz ◽  
Ghazi Aman Nowsherwan ◽  
Khizer Jahangir ◽  
Akram Raza ◽  
...  

The highest power conversion efficiency (PCE) for organic-inorganic perovskite solar cells based on lead is reported as 25.2% in 2019. Lead-based hybrid perovskite materials are used in several photovoltaics applications, but these are not highly favored due to the toxicity of lead and volatility of organic cations. On the other hand, hybrid lead-free double perovskite has no such harm. In this research study, SCAPS numerical simulation is utilized to evaluate and compare the results of perovskite solar cell based on double perovskite FA 2 BiCuI 6 and standard perovskite CH 3 NH 3 PbI 3 as an active layer. The results show that the power conversion efficiency obtained in the case of FA 2 BiCuI 6 is 24.98%, while in the case of CH 3 NH 3 PbI 3 , it is reported as 26.42%. This indicates that the hybrid organic-inorganic double perovskite FA 2 BiCuI 6 has the ability to replace hybrid organic-inorganic perovskite CH 3 NH 3 PbI 3 to expand next-generation lead-free harmless materials for solar cell applications.


2020 ◽  
Vol 13 (11) ◽  
pp. 4344-4352
Author(s):  
Ning Yang ◽  
Cheng Zhu ◽  
Yihua Chen ◽  
Huachao Zai ◽  
Chenyue Wang ◽  
...  

An in situ cross-linked 1D/3D perovskite heterostructure achieved a perovskite solar cell with a 21.19% PCE and operational stability over 3000 hours.


2014 ◽  
Vol 126 (42) ◽  
pp. 11414-11417 ◽  
Author(s):  
Ian C. Smith ◽  
Eric T. Hoke ◽  
Diego Solis-Ibarra ◽  
Michael D. McGehee ◽  
Hemamala I. Karunadasa

Solar RRL ◽  
2017 ◽  
Vol 1 (8) ◽  
pp. 1770130
Author(s):  
Yingzhuang Ma ◽  
Parth Vashishtha ◽  
Sunil B. Shivarudraiah ◽  
Kai Chen ◽  
Ye Liu ◽  
...  

2017 ◽  
Vol 121 (8) ◽  
pp. 4214-4219 ◽  
Author(s):  
Zhaosheng Hu ◽  
Gaurav Kapil ◽  
Hiromitsu Shimazaki ◽  
Shyam Sudhir Pandey ◽  
Tingli Ma ◽  
...  

Crystals ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 68
Author(s):  
Qinmiao Chen ◽  
Yi Ni ◽  
Xiaoming Dou ◽  
Yamaguchi Yoshinori

The perovskite solar cell (PSC) as an emerging and promising type has been extensively studied. In this study, a model for a PSC prepared in ambient air was established by using SCAPS-1D. After that, it was further analyzed through varying the defect density of the perovskite absorber layer (Nt), the thin film thickness and energy-level matching between the electron transport layer (ETL), the perovskite absorber layer and the hole transport layer (HTL), for a better understanding of the carrier features. The Nt varied from 1.000 × 1011 to 1.000 × 1017 cm−3. The performance of the solar cell is promoted with improved Nt. When Nt is at 1.000 × 1015 cm−3, the carrier diffusion length reaches μm, and the carrier lifetime comes to 200 nm. The thickness of the absorber layer was changed from 200 to 600 nm. It is shown that the absorber layer could be prepared thinner for reducing carrier recombination when at high Nt. The thickness effect of ETL and HTL is weakened, since Nt dominates the solar cell performance. The effect of the affinity of ETL (3.4–4.3 eV) and HTL (2.0–2.7 eV), together with three energy-level matching situations “ETL(4.2)+HTL(2.5)”, “ETL(4.0)+HTL(2.2)” and “ETL(4.0)+HTL(2.5)” on the performance of the solar cell were analyzed. It was found that the HTL with valence band 0.05 eV lower than that of the perovskite absorber layer could have a blocking effect that reduced carrier recombination. The effect of energy-level matching becomes more important with improved Nt. Energy-level matching between the ETL and perovskite absorber layer turns out counterbalance characteristic on Jsc and Voc, and the “ETL(4.0)+HTL(2.5)” case can result in solar cell with Jsc of 27.58 mA/cm2, Voc of 1.0713 V, FF of 66.02% and efficiency of 19.51%. The findings would be very useful for fabricating high-efficiency and low-cost PSC by a large-scale ambient air route.


2014 ◽  
Vol 53 (42) ◽  
pp. 11232-11235 ◽  
Author(s):  
Ian C. Smith ◽  
Eric T. Hoke ◽  
Diego Solis-Ibarra ◽  
Michael D. McGehee ◽  
Hemamala I. Karunadasa

2016 ◽  
Vol 6 (1) ◽  
Author(s):  
Fedwa El-Mellouhi ◽  
El Tayeb Bentria ◽  
Sergey N. Rashkeev ◽  
Sabre Kais ◽  
Fahhad H. Alharbi

2016 ◽  
Vol 117 ◽  
pp. 573-578 ◽  
Author(s):  
Yu-Yun Pan ◽  
Yen-Hsun Su ◽  
Chuang-Han Hsu ◽  
Li-Wen Huang ◽  
Chao-Cheng Kaun

RSC Advances ◽  
2017 ◽  
Vol 7 (68) ◽  
pp. 42973-42978 ◽  
Author(s):  
Yanqing Yao ◽  
Gang Wang ◽  
Fei Wu ◽  
Debei Liu ◽  
Chunyan Lin ◽  
...  

The light beam induced current (LBIC) method was adopted to nondestructively map the photoresponse of real planar organic–inorganic hybrid perovskite solar cells (PSCs).


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