Surface charge tuning of functionalized silica cross-linked micellar nanoparticles encapsulating a donor–acceptor dye for Fe(iii) sensing

2015 ◽  
Vol 3 (5) ◽  
pp. 2120-2127 ◽  
Author(s):  
Fangyuan Gai ◽  
Tianlei Zhou ◽  
Yunling Liu ◽  
Qisheng Huo
Keyword(s):  
Electron Transfer ◽  
Surface Charge ◽  
Aqueous Media ◽  
Functionalized Silica ◽  
Fluorescent Chemosensors ◽  
Donor Acceptor ◽  
Micellar Nanoparticles

This work demonstrates that a series of electron transfer-based fluorescent chemosensors have been designed by using surface negatively charged silica cross-linked micellar nanoparticles as scaffolds to encapsulate FTA for improving the quantitative Fe3+ sensing ability in aqueous media.

Hybrid nanoparticle based fluorescence switch for recognition of ketoprofen in aqueous media

2020 ◽  
Vol 5 (8) ◽  
pp. 1428-1436
Author(s):  
Anu Saini ◽  
Manpreet Kaur ◽  
Mayank ◽  
Anil Kuwar ◽  
Navneet Kaur ◽  
...  
Keyword(s):  
Aqueous Media ◽  
Fluorescent Chemosensors ◽  
Fluorescence Switch ◽  
Nanomolar Detection ◽  
Hybrid Nanoparticle

Hybrid nanoassembly, fluorescent chemosensors, selective response to ketoprofen, and nanomolar detection.

Photoelectrochemical properties of supramolecular composites of an anionic zinc chlorin and Li+@C60 on SnO2

2014 ◽  
Vol 18 (10n11) ◽  
pp. 982-990 ◽  
Author(s):  
Kei Ohkubo ◽  
Yuki Kawashima ◽  
Kentaro Mase ◽  
Hayato Sakai ◽  
Taku Hasobe ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Photovoltaic Cells ◽  
Lithium Ion ◽  
Transparent Electrode ◽  
Supramolecular Complex ◽  
Photoelectrochemical Properties ◽  
Triplet Excited State ◽  
Optically Transparent ◽  
Donor Acceptor

An electron donor–acceptor supramolecular complex was formed between an anionic zinc chlorin carboxylate ( ZnCh -) and lithium-ion-encapsulated [60]fullerene ( Li +@ C 60) by an electrostatic interaction in benzonitrile ( PhCN ). Photoinduced electron transfer in the supramolecular complex of ZnCh -/ Li +@ C 60 resulted in the formation of the charge-separated state via electron transfer from the triplet excited state of ZnCh - to Li +@ C 60. We report herein photovoltaic cells using ZnCh -/ Li +@ C 60 nanoclusters, which are assembled on the optically transparent electrode (OTE) of nanostructured SnO 2 (OTE/ SnO 2). The photoelectrochemical behavior of the nanostructured SnO 2 film of supramolecular nanoclusters of ZnCh - and Li +@ C 60 denoted as OTE/ SnO 2/( ZnCh -/ Li +@ C 60)n is significantly higher than the single component films of ZnCh - or Li +@ C 60 clusters, denoted as OTE/ SnO 2/( ZnCh -)n or OTE/ SnO 2/( Li +@ C 60)n.

Through-bond modulation of intramolecular electron transfer in rigidly linked donor-acceptor systems

1989 ◽  
Vol 164 (2-3) ◽  
pp. 120-125 ◽  
Author(s):  
James M. Lawson ◽  
Donald C. Craig ◽  
Michael N. Paddon-Row ◽  
Jan Kroon ◽  
Jan W. Verhoeven
Keyword(s):  
Electron Transfer ◽  
Intramolecular Electron Transfer ◽  
Donor Acceptor

scholarly journals Treatment of wastewaters containing acid, reactive and direct dyes using aminosilane functionalized silica

2015 ◽  
Vol 13 (1) ◽  
Author(s):  
Monika Wawrzkiewicz ◽  
Zbigniew Hubicki ◽  
Magdalena Nowacka ◽  
Łukasz Klapiszewski
Keyword(s):  
Langmuir Isotherm ◽  
Aqueous Media ◽  
Reactive Black 5 ◽  
Functionalized Silica ◽  
Acid Orange 7 ◽  
Direct Dyes ◽  
Modified Silica ◽  
Direct Blue ◽  
Langmuir Isotherm Model ◽  
Direct Blue 71

AbstractAminosilane modified silica was prepared and investigated for the adsorption of textile dyes such as C.I. Acid Orange 7 (AO7), C.I. Reactive Black 5 (RB5) and C.I. Direct Blue 71 (DB71) from aqueous media and wastewaters. The values of the sorption capacities obtained from the Langmuir isotherm model were: 5.3 mg g

Electron-transfer reactions in non-aqueous media. VII. Reduction of CoF(NH3)52+ and Co(HCOO)(NH3)52+ by copper(I) in dimethyl sulfoxide-water mixtures

1983 ◽  
Vol 36 (10) ◽  
pp. 1923 ◽  
Author(s):  
JMB Harrowfield ◽  
L Spiccia ◽  
DW Watts
Keyword(s):  
Electron Transfer ◽  
Dimethyl Sulfoxide ◽  
Aqueous Media ◽  
Mixed Solvents ◽  
Transfer Reactions ◽  
Aprotic Solvents ◽  
Aqueous Mixtures ◽  
Electron Transfer Reactions ◽  
Dipolar Aprotic Solvents ◽  
Sphere Mechanism

Previous work on the reduction of a series of cobalt(III) complexes by iron(II) in dipolar aprotic solvents and in aqueous mixtures has been extended to reduction by copper(I). The greater stability of copper(I) to disproportionation in these media has permitted the study of the reduction of CoF(NH3)52+ and Co(HCOO)(NH3)52+ in range of solvents over a number of temperatures with a precision not possible in previous studies in water. The results are consistent with an inner-sphere mechanism in which the copper(I) reductant is preferentially solvated by dimethyl sulfoxide to the exclusion of water in mixed solvents.

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