Facile preparation of MnO2 doped Fe2O3 hollow nanofibers for low temperature SCR of NO with NH3

2014 ◽  
Vol 2 (48) ◽  
pp. 20486-20493 ◽  
Author(s):  
Sihui Zhan ◽  
Mingying Qiu ◽  
Shanshan Yang ◽  
Dandan Zhu ◽  
Hongbing Yu ◽  
...  

MnO2 doped Fe2O3 hollow nanofibers were successfully synthesized by the electrospinning method, which exhibit superior catalytic activity for low temperature NH3-SCR.

2014 ◽  
Vol 633 ◽  
pp. 121-124 ◽  
Author(s):  
Liang Jing Zhang ◽  
Su Ping Cui ◽  
Hong Xia Guo ◽  
Xiao Yu Ma ◽  
Xiao Gen Luo

Catalysts of Mn/TiO2 and Mn-Ce /TiO2 prepared by co-precipitation method for low temperature selective catalytic reduction (SCR) of NO with NH3 were investigated in this study. The experimental results showed that co-precipitation method after improvement, the NO conversion of Mn-Ce/TiO2 catalyst increased sharply. Meanwhile, the addition of cerium has significant effects on the catalytic activity. Characterizations of catalysts were carried out by XRD, BET and H2-TPR. The characterized results indicated that co-precipitation method after improvement, in temperature windows 150 to 300 °C, showed higher NOx conversion.


ACS Catalysis ◽  
2016 ◽  
Vol 6 (9) ◽  
pp. 5807-5815 ◽  
Author(s):  
Shengcai Deng ◽  
Tingting Meng ◽  
Bolian Xu ◽  
Fei Gao ◽  
Yuanhua Ding ◽  
...  

2014 ◽  
Vol 875-877 ◽  
pp. 213-217 ◽  
Author(s):  
Mohd Razali Sohot ◽  
Umi Sarah Jais ◽  
Muhd Rosli Sulaiman

Selective catalytic reduction (SCR) is a well-proven method to reduce NO emission. However, to choose the right catalyst that provides a surface for reaction between NO and ammonia at low temperatures is a challenging task for a catalysts developers. In an earlier study, we prepared V2O5-CeO2-SiO2 catalyst with increasing V2O5 content by sol-gel route and found that the catalytic activity improved with increasing the V2O5 loading up to 0.5%. The catalytic activity, however, dropped when V2O5 loading was about 1% and increased back when the loading of V2O5 was about 5%. In this study, we looked into the microstructural relationship to explain these findings. The microstructures of the catalysts before and after exposure to NO gas revealed that the catalysts with 0.2% and 0.5% V2O5 were more porous after the reduction process possibly due to improved breakdown of (NH4)HCO3 to NH3 by the possible interaction with the V2O5 and CeO2-containing catalysts which consequently resulted in a more efficient NO reduction to N2 and H2O at low temperature. The microstructure of the catalyst with 1% V2O5 content to 5%, improved back the efficiency although clogging by CeVO4 phase still possible due to its presence based on XRD. The well-ordered micropores before exposure to NO and the more efficient breakdown of (NH4)HCO3 could have contributed to increase back the catalytic activity at low temperature.


2018 ◽  
Vol 44 (5) ◽  
pp. 3455-3474 ◽  
Author(s):  
Xiao Sun ◽  
Rui-tang Guo ◽  
Ming-yuan Li ◽  
Peng Sun ◽  
Wei-guo Pan ◽  
...  

2019 ◽  
Vol 97 (S1) ◽  
pp. 1407-1417 ◽  
Author(s):  
Yanqing Niu ◽  
Xiaolu Zhang ◽  
Hao Zhang ◽  
Yang Liang ◽  
Shuaifei Li ◽  
...  

2010 ◽  
Vol 156 (2) ◽  
pp. 321-327 ◽  
Author(s):  
Jin Sun Cha ◽  
Jong-Cheol Choi ◽  
Jeong Huy Ko ◽  
Young-Kwon Park ◽  
Sung Hoon Park ◽  
...  

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