A fast route for synthesizing nano-sized ZSM-5 aggregates

2014 ◽  
Vol 2 (48) ◽  
pp. 20667-20675 ◽  
Author(s):  
Feng Pan ◽  
Xuchen Lu ◽  
Qingshan Zhu ◽  
Zhimin Zhang ◽  
Yan Yan ◽  
...  

Nano-sized ZSM-5 aggregates have been rapidly synthesized from leached metakaolin by solid-like state conversion. Compared with the conventional hydrothermal route, the nano-sized ZSM-5 aggregates obtained by this method showed more excellent catalytic performance, C2–C4 olefin selectivity and longer lifetime to endure coke deposition.

2019 ◽  
Vol 48 (8) ◽  
pp. 2606-2616 ◽  
Author(s):  
Syed ul Hasnain Bakhtiar ◽  
Sher Ali ◽  
Xiaotong Wang ◽  
Fulong Yuan ◽  
Zhibin Li ◽  
...  

SAPO-34 with a sub-micrometer crystal size was synthesized by a double hydrothermal treatment employing cost-effective morpholine as a structure directing agent, which presented an enhanced catalytic lifetime (nearly 3 times the conventional one) in the reaction of methanol to olefins with a higher light olefin selectivity (total selectivity of 97.1%).


2017 ◽  
Vol 50 ◽  
pp. 72-77
Author(s):  
Xiao Fei Niu ◽  
Fu Rong Tu

The almost monodisperse cobble-like CeO2 nanostructures with many pores and a diameter of 50-100 nm have been successfully synthesized by a smart hydrothermal route. XRD, SEM, XPS, BET, and in situ DRIFT were employed to characterize the samples. The results showed that the cobble-like CeO2 owned a fluorite cubic structure and there are Ce3+ ions and oxygen vacancies in surface of samples. Its catalytic activity was investigated by selective catalytic reduction of NOx with NH3. The results showed that cobble-like CeO2 nanostructures exhibit excellent catalytic performance, which can be attributed to the much larger surface areas, novel morphology and the best redox behaviour of surface oxygen on the CeO2 surface.


2014 ◽  
Vol 29 (2) ◽  
pp. 124-130 ◽  
Author(s):  
Yu-Cheng DU ◽  
Guang-Wei ZHENG ◽  
Qi MENG ◽  
Li-Ping WANG ◽  
Hai-Guang FAN ◽  
...  

Author(s):  
Cui‐Ping Wu ◽  
Zhao Jin ◽  
Kai Xu ◽  
Wei‐Wei Wang ◽  
Chun‐Jiang Jia

Author(s):  
Yangyang Ren ◽  
Chuanliang Li ◽  
Baosong Li ◽  
Fan Gao ◽  
Xinghua Zhang ◽  
...  

PtPd nanoframes with excellent catalytic properties were obtained by etching Pd@PdPt core–shell RDs with Fe3+ in an acid environment.


Author(s):  
Yafei Liang ◽  
Beibei Gao ◽  
Lipeng Zhou ◽  
Xiaomei Yang ◽  
Tianliang Lu ◽  
...  

A facile approach has been developed to fabricate hierarchical SAPO-34 with large intracrystalline meso/macropores and excellent catalytic performance in the MTO reaction.


Catalysts ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 974
Author(s):  
Bing Han ◽  
Haihong Meng ◽  
Fengyu Li ◽  
Jingxiang Zhao

Under the current double challenge of energy and the environment, an effective nitrogen reduction reaction (NRR) has become a very urgent need. However, the largest production of ammonia gas today is carried out by the Haber–Bosch process, which has many disadvantages, among which energy consumption and air pollution are typical. As the best alternative procedure, electrochemistry has received extensive attention. In this paper, a catalyst loaded with Fe3 clusters on the two-dimensional material C2N (Fe3@C2N) is proposed to achieve effective electrochemical NRR, and our first-principles calculations reveal that the stable Fe3@C2N exhibits excellent catalytic performance for electrochemical nitrogen fixation with a limiting potential of 0.57 eV, while also suppressing the major competing hydrogen evolution reaction. Our findings will open a new door for the development of non-precious single-cluster catalysts for effective nitrogen reduction reactions.


2019 ◽  
Vol 6 (5) ◽  
pp. 1152-1157 ◽  
Author(s):  
Xia Wang ◽  
Xiurong Zhang ◽  
Kai Zhang ◽  
Xiaokang Wang ◽  
Yutong Wang ◽  
...  

Amino-functionalized Cu-MOF for the efficient purification of methane from light hydrocarbons and excellent catalytic performance.


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