Iron-containing, high aspect ratio clay as nanoarmor that imparts substantial thermal/flame protection to polyurethane with a single electrostatically-deposited bilayer

2014 ◽  
Vol 2 (41) ◽  
pp. 17609-17617 ◽  
Author(s):  
A. A. Cain ◽  
M. G. B. Plummer ◽  
S. E. Murray ◽  
L. Bolling ◽  
O. Regev ◽  
...  
Keyword(s):  
Thin Films ◽  
Aspect Ratio ◽  
Heat Release ◽  
Polyurethane Foam ◽  
Heat Release Rate ◽  
Release Rate ◽  
High Aspect Ratio ◽  
Peak Heat Release Rate ◽  
Self Assembled ◽  
Flame Protection

Single bilayer polymer/clay nanobrick wall self-assembled thin films, deposited as a continuous coating on open-celled polyurethane foam, cut peak heat release rate in half with only 3.2 wt% addition.

scholarly journals The effect of intumescent mat on post-fire performance of carbon fibre reinforced composites

2019 ◽  
Vol 37 (3) ◽  
pp. 257-272 ◽  
Author(s):  
Chenkai Zhu ◽  
Jingjing Li ◽  
Mandy Clement ◽  
Xiaosu Yi ◽  
Chris Rudd ◽  
...  
Keyword(s):  
Carbon Fibre ◽  
Heat Release ◽  
Heat Release Rate ◽  
Release Rate ◽  
Reinforced Composites ◽  
Fire Performance ◽  
Total Heat Release ◽  
Reinforced Composite ◽  
Peak Heat Release Rate ◽  
Fibre Reinforced Composites

This study investigated the effect of intumescent mats (M1 and M2) with different compositions on the post-fire performance of carbon fibre reinforced composites. The sandwich structure was designed for composites where M1 (carbon fibre reinforced composite-M1) or M2 (carbon fibre reinforced composite-M2) mats were covered on the composite surface. A significant reduction in the peak heat release rate and total heat release was observed from the cone calorimetric data, and carbon fibre reinforced composite-M1 showed the lowest value of 148 kW/m2 and 29 MJ/m2 for peak heat release rate and total heat release, respectively. In addition, a minor influence on mechanical properties was observed due to the variation of composite thickness and resin volume in the composite. The post-fire properties of composite were characterised, and the M1 mat presented better retention of flexural strength and modulus. The feasibility of two-layer model was confirmed to predict the post-fire performance of composites and reduce the reliance on the large amounts of empirical data.

Numerical Simulation on Spreading Characteristic of Coach Fire

2012 ◽  
Vol 518-523 ◽  
pp. 1269-1272 ◽  
Author(s):  
Liang Yi ◽  
Jie Chen
Keyword(s):  
Fluid Dynamics ◽  
Numerical Simulation ◽  
Computational Fluid Dynamics ◽  
Heat Release ◽  
Heat Release Rate ◽  
Fire Protection ◽  
Release Rate ◽  
Software Package ◽  
Maximum Temperature ◽  
Peak Heat Release Rate

The aim of this work is to study the burning characteristics of coach fire. With application of computational fluid dynamics (FDS software package), coach fires caused by arson are simulated under different ventilation conditions. Variation of heat release rate (HRR) and distribution of temperature are analyzed. Peak heat release rate of coach fire caused by arson in passenger carriage can reach about 24 MW and maximum temperature in the carriage is over 1000 °C. Results of this study can be referred for fire protection and rescue design of coach.

Assessing fire-blocking effectiveness of barrier fabrics in the cone calorimeter

2019 ◽  
Vol 37 (4-6) ◽  
pp. 340-376 ◽  
Author(s):  
Shonali Nazare ◽  
William M. Pitts ◽  
John Shields ◽  
Elizabeth Knowlton ◽  
Benito De Leon ◽  
...  
Keyword(s):  
Heat Release ◽  
Polyurethane Foam ◽  
Heat Release Rate ◽  
Release Rate ◽  
Thermal Protection ◽  
Flame Extinction ◽  
Burning Behavior ◽  
Flexible Polyurethane Foam ◽  
Flexible Polyurethane ◽  
Flame Retardant Chemicals

Cone calorimetry experiments of on flexible polyurethane foam and flexible polyurethane foam covered with a variety of fire-blocking barrier fabrics were used to characterize and rank the effectiveness of barrier fabrics with the ultimate goal being an ability to predict the effectiveness of barrier fabrics for reducing the flammability of residential upholstered furniture. The primary measure used to characterize the burning behavior was heat release rate. The effect of the underlying sample substrate was shown to have a large effect on the burning behavior of flexible polyurethane foam samples, and a thermally insulating substrate was used during composite experiments. At times, rapid heat release rate fluctuations were observed, and in such cases approximate corrections were applied to correct for finite cone calorimeter time response. Measurements using thermocouples placed within the flexible polyurethane foam provided insights on flexible polyurethane foam pyrolysis behavior, the collapse rate of flexible polyurethane foam, and the thermal protective properties of barrier materials. Heat release rate temporal profiles for flexible polyurethane foam showed two distinct burning stages with peak values which have been attributed to sequential burning of species (primarily) derived from the diamine ( PHRR1) and polyol components ( PHRR2) used to manufacture the flexible polyurethane foam. When a barrier fabric was added, many of the composites displayed a three-stage burning behavior which was attributed to an initial short, intense burning (termed flash burning) stage associated with the barrier fabric covering followed by the two flexible polyurethane foam stages. Seven out of 16 flexible polyurethane foam/barrier fabric composites exhibited flame extinction prior to fuel burn out. Five out of the seven composites reignited when the spark ignition source was reapplied. Reignition allowed barrier fabric effectiveness to be assessed even for cases with flame extinction. Barrier fabric performance was shown to be consistent with four properties that were previously identified as important barrier fabric properties: barrier fabric flammability, gas permeability, thermal protection, and physical integrity. In addition, the current experiments indicate the presence and effectiveness of gas-phase active flame retardants in the barrier fabric can also play an important role. A limited number of tests were conducted to de-couple the effects of flame-retardant chemicals and physical effects of barrier fabrics on flexible polyurethane foam burning behavior. These tests showed that while flame-retardant chemicals can be effective in quenching and extinguishing the flames, the presence of effective barrier fabric shells is also very important in lowering the heat release rate of burning flexible polyurethane foam. In general, the presence of a barrier fabric was shown to reduce the heat release rate peak values during both flexible polyurethane foam burning stages. The magnitude of the peak associated with second-stage flexible polyurethane foam burning was deemed the most appropriate for characterizing the thermal protection provided by a barrier fabric. Since the times for PHRR2 also varied between composites, a measurement referred to as the peak fire growth rate (PFIGRA) parameter was calculated by dividing the heat release rate by time since time to ignition and PFIGRA2 was also considered for characterizing the barrier fabrics. Three possible classification schemes, each consisting of three classes, were introduced based on composite flame extinction and reignition behavior, PHRR2 values, and PFIGRA2 values. Each scheme provided differentiation between barrier fabric effectiveness. While the schemes were able to assess whether the barrier fabrics were particularly effective or ineffective, there were variations among classes of barrier fabrics having intermediate levels of effectiveness. Further work will be required to assess which, if any, of the classification schemes are most appropriate for predicting barrier fabric performance in residential upholstered furniture.

Impact of Flashover Fire Conditions on Exposed Energized Electrical Cords and Cables

2019 ◽  
Author(s):  
Craig Weinschenk ◽  
◽  
Daniel Madrzykowski ◽  
Paul Courtney
Keyword(s):  
Heat Release ◽  
Heat Release Rate ◽  
Release Rate ◽  
Circuit Breaker ◽  
Thermal Exposure ◽  
Ground Fault ◽  
Peak Heat Release Rate ◽  
Different Types ◽  
Protection Devices ◽  
Fuel Source

A set of experiments was conducted to expose different types of energized electrical cords for lamps, office equipment, and appliances to a developing room fire exposure. All of the cords were positioned on the floor and arranged in a manner to receive a similar thermal exposure. Six types of cords commonly used as power supply cords, extension cords, and as part of residential electrical wiring systems were chosen for the experiments. The non-metallic sheathed cables (NMB) typically found in residential electrical branch wiring were included to provide a link to previous research. The basic test design was to expose the six different types of cords, on the floor of a compartment to a growing fire to determine the conditions under which the cord would trip the circuit breaker and/or undergo an arc fault. All of the cords would be energized and installed on a non-combustible surface. Six cord types (18-2 SPT1, 16-3 SJTW, 12-2 NM-B, 12-3 NM-B, 18-3 SVT, 18-2 NISPT-2) and three types of circuit protection (Molded case circuit breaker (MCCB), combination Arc-fault circuit interrupter (AFCI), Ground-fault circuit interrupter (GFCI)) were exposed to six room-scale fires. The circuit protection was remote from the thermal exposure. The six room fires consisted of three replicate fires with two sofas as the main fuel source, two replicate fires with one sofa as the main fuel source and one fire with two sofas and MDF paneling on three walls in the room. Each fuel package was sufficient to support flashover conditions in the room and as a result, the impact on the cords and circuit protection was not significantly different. The average peak heat release rate of the sofa fueled compartment fires with gypsum board ceiling and walls was 6.8 MW. The addition of vinyl covered MDF wall paneling on three of the compartment walls increased the peak heat release rate to 12 MW, although most of the increased energy release occurred outside of the compartment opening. In each experiment during post flashover exposure, the insulation on the cords ignited and burned through, exposing bare conductor. During this period the circuits faulted. The circuit protection devices are not designed to provide thermal protection, and, thus, were installed remote from the fire. The devices operated as designed in all experiments. All of the circuit faults resulted in either a magnetic trip of the conventional circuit breaker or a ground-fault trip in the GFCI or AFCI capable circuit protection devices. Though not required by UL 1699, Standard for Safety for Arc-Fault Circuit-Interrupters as the solution for detection methodology, the AFCIs used had differential current detection. Examination of signal data showed that the only cord types that tripped with a fault to ground were the insulated conductors in non-metallic sheathed cables (12-2 NM-B and 12-3 NM-B). This was expected due to the bare grounding conductor present. Assessments of both the thermal exposure and physical damage to the cords did not reveal any correlation between the thermal exposure, cord damage, and trip type.

Study on Flame-Retardant Properties of Flame Retardant Asphalt Mixture

2013 ◽  
Vol 438-439 ◽  
pp. 387-390 ◽  
Author(s):  
Da Liang Liu ◽  
Yi Zhong Yan ◽  
Yun Yong Huang ◽  
Jia Liang Yao ◽  
Jian Bo Yuan
Keyword(s):  
Heat Release ◽  
Flame Retardant ◽  
Heat Release Rate ◽  
Release Rate ◽  
Flame Retardants ◽  
Asphalt Mixture ◽  
Modified Asphalt ◽  
Peak Heat Release Rate ◽  
Flame Retardant Properties ◽  
Sbs Modified Asphalt

Flame retardants modified asphalt with SBS flame retardant SMA hybrid material was prepared, flame retardant performances of SMA mixture was studied by the cone calorimeter. The results show that adding 12% flame retardant with SBS modified asphalt in preparation of flame retardant SMA mixture, the peak heat release rate values than the non-flame retardant asphalt mixture decreased by 4.02 kW/m2, and the heat release rate values were significantly reduced, the total heat and the amount of smoke of flame retardant asphalt mixture released less than the non-flame retardant asphalt mixture.

Flame Retardation of Natural Bamboo Fiber/ Polypropylene Fiber Non-Woven Materials

2011 ◽  
Vol 105-107 ◽  
pp. 1723-1726
Author(s):  
Wei Ma ◽  
Wen Bin Yao
Keyword(s):  
Heat Release ◽  
Flame Retardant ◽  
Heat Release Rate ◽  
Release Rate ◽  
Cone Calorimeter ◽  
Polypropylene Fiber ◽  
Bamboo Fiber ◽  
Peak Heat Release Rate ◽  
Natural Bamboo Fiber ◽  
Flame Retardation

According to Natural Bamboo Fiber/ Polypropylene fiber(PP) non-woven materials encountered the problem that its flame retardation is insufficient, this paper tried to add flame retardant to improve its performance, then the cone calorimeter was used to evaluate its flammability. The results show that Peak-Heat Release Rate and Smoke Release Rate etc significantly improved. In accordance with the UL94 ,the flame retardation meet the level V-0 , consistent with the requirements of enterprise.

Estimation of Peak Heat Release Rate of a Forest Fuel Bed in Outdoor Laboratory Conditions

2010 ◽  
Vol 29 (1) ◽  
pp. 53-70 ◽  
Author(s):  
J. Madrigal ◽  
M. Guijarro ◽  
C. Hernando ◽  
C. Díez ◽  
E. Marino
Keyword(s):  
Heat Release ◽  
Heat Release Rate ◽  
Release Rate ◽  
Laboratory Conditions ◽  
Peak Heat Release Rate ◽  
Forest Fuel
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