A water-based and high space-time yield synthetic route to MOF Ni2(dhtp) and its linker 2,5-dihydroxyterephthalic acid

2014 ◽  
Vol 2 (42) ◽  
pp. 17757-17763 ◽  
Author(s):  
Stéphane Cadot ◽  
Laurent Veyre ◽  
Dominique Luneau ◽  
David Farrusseng ◽  
Elsje Alessandra Quadrelli

Highway to MOF Ni2(dhtp)! 1 hour in boiling water under atmospheric pressure; a cheap synthesis of the linker is also reported.

Author(s):  
Lejian Zhang ◽  
Xiaoxiao Zhu ◽  
Xinping Wang ◽  
Chuan Shi

Anatase-free titanium silicalite-1 (TS-1) zeolite with high framework titanium content is highly required for catalysing selective oxidation reactions, while its synthesis generally suffers from cost, efficiency and environmental issues. Herein,...


RSC Advances ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 2325-2331 ◽  
Author(s):  
Yitong Chen ◽  
Baodi Ma ◽  
Songshuang Cao ◽  
Xiaomei Wu ◽  
Yi Xu

A simple and efficient process for the synthesis of optically active (S)-N-boc-3-hydroxy piperidine was developed using the “designer cells” co-expressing alcohol dehydrogenase and glucose dehydrogenase.


BioResources ◽  
2020 ◽  
Vol 15 (4) ◽  
pp. 8689-8695
Author(s):  
Huan Liu ◽  
Xiaolan Huang ◽  
Qi Xiao ◽  
Yue Yu ◽  
Li Deng ◽  
...  

Cellulase is a compound enzyme that catalyzes cellulose into monosaccharides or oligosaccharides. Large amounts of cellulase are needed with the development of the lignocellulose processing industry, which necessitates faster methods to produce cellulase. In this work, the marine bacterium Microbulbifer hydrolyticus IRE-31-192 was selected to produce cellulase, due to its fast growth rate and short high space-time yield. Co-fermentation of glucose and xylose to produce cellulase was investigated on the basis of previous work. When the ratio of glucose/xylose was 2:1 (w/w), 294 U/L cellulase activity with highest space-time yield of 12.2 U/L h was obtained. The hydrolytic liquid of lignocellulose prepared from dried distiller’s grains with solubles (DDGS) with the similar ratio of glucose/xylose was used as medium to produce cellulase. The efficiency of cellulase production from processed and unprocessed hydrolysates of DDGS was compared. Unprocessed hydrolysates were more beneficial for the production of cellulase, such that its activity was 261 U/L with a space-time yield of 14.5 U/L h. Thus, commonly used pure glucose and xylose could be replaced by hydrolysates of DDGS, and marine bacteria has potential application for cellulase production.


2015 ◽  
Vol 3 (41) ◽  
pp. 20819-20826 ◽  
Author(s):  
L. Garzón-Tovar ◽  
A. Carné-Sánchez ◽  
C. Carbonell ◽  
I. Imaz ◽  
D. Maspoch

The stepwise optimisation of the room temperature, water-based synthesis of several porous CPO-27/MOF-74 materials allows fabricating them with BET surfaces areas up to 1603 m2 g−1 and space-time-yields as high as 18 720 kg m−3 per day.


2013 ◽  
Vol 1 (48) ◽  
pp. 15220 ◽  
Author(s):  
Jia Huo ◽  
Mark Brightwell ◽  
Samir El Hankari ◽  
Ashesh Garai ◽  
Darren Bradshaw

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