Highly activated K-doped iron carbide nanocatalysts designed by computational simulation for Fischer–Tropsch synthesis

2014 ◽  
Vol 2 (35) ◽  
pp. 14371-14379 ◽  
Author(s):  
Ji Chan Park ◽  
Sang Chul Yeo ◽  
Dong Hyun Chun ◽  
Jung Tae Lim ◽  
Jung-Il Yang ◽  
...  

Highly activated K-doped Hägg-carbide/charcoal nanocatalyst at K/Fe = 0.075 showed the highest FTY value, the best hydrocarbon yield, and a good gasoline selectivity for the high-temperature Fischer–Tropsch reaction.

Nanoscale ◽  
2015 ◽  
Vol 7 (40) ◽  
pp. 16616-16620 ◽  
Author(s):  
Seok Yong Hong ◽  
Dong Hyun Chun ◽  
Jung-Il Yang ◽  
Heon Jung ◽  
Ho-Tae Lee ◽  
...  

A novel Fe5C2@C catalyst bearing small iron carbide particles ∼10 nm in diameter was prepared using a simple thermal treatment of iron oxalate dihydrate cubes, employed in high-temperature Fischer–Tropsch synthesis.


ChemCatChem ◽  
2015 ◽  
Vol 7 (21) ◽  
pp. 3594-3594
Author(s):  
Hunmin Park ◽  
Duck Hyun Youn ◽  
Jae Young Kim ◽  
Won Yong Kim ◽  
Yo Han Choi ◽  
...  

2019 ◽  
Vol 58 (47) ◽  
pp. 21350-21362 ◽  
Author(s):  
Xian Wu ◽  
Hongfang Ma ◽  
Haitao Zhang ◽  
Weixin Qian ◽  
Dianhua Liu ◽  
...  

ACS Catalysis ◽  
2018 ◽  
Vol 9 (2) ◽  
pp. 1264-1273 ◽  
Author(s):  
Yijia Li ◽  
Zheshen Li ◽  
Ali Ahsen ◽  
Lutz Lammich ◽  
Gilbère J. A. Mannie ◽  
...  

ChemCatChem ◽  
2015 ◽  
Vol 7 (21) ◽  
pp. 3488-3494 ◽  
Author(s):  
Hunmin Park ◽  
Duck Hyun Youn ◽  
Jae Young Kim ◽  
Won Yong Kim ◽  
Yo Han Choi ◽  
...  

2020 ◽  
Vol 13 (04) ◽  
pp. 2041001
Author(s):  
Elena Yu. Zakharova ◽  
Anastasiya Yu. Makhaneva ◽  
Maya V. Kulikova ◽  
Maria V. Chudakova ◽  
Mikhail I. Ivantsov ◽  
...  

A series of solid solutions in the PdTe–PdBi system with general formula [Formula: see text]Bix ([Formula: see text], 0.5, 0.67) with the structure based on the NiAs type were synthesized by a high-temperature ampoule technique. These compounds, along with their parent binaries, PdTe and PdBi, were tested as promoters for the standard Co/Al2O3 catalytic system in the Fischer–Tropsch synthesis. It is shown that the addition of PdTe and [Formula: see text]Bix to the standard catalyst increases both yield and selectivity with respect to the liquid phase. At the same time, the addition of PdBi does not only improve catalytic activity, but also slightly inhibits it. Another positive effect of the PdTe and [Formula: see text]Bix addition is the shift in the conversion products toward the diesel and wax fractions. Chemical bonding analysis in orbital and direct space indicates that the addition of Bi to PdTe might increase the localized bonding.


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