Programmed synthesis of magnetic mesoporous silica nanotubes with tiny Au nanoparticles: a highly novel catalyst system

2014 ◽  
Vol 2 (27) ◽  
pp. 10485 ◽  
Author(s):  
Xinzhe Li ◽  
Xiao-Hang Zhu ◽  
Yiyun Fang ◽  
Hong-Lei Yang ◽  
Xingchun Zhou ◽  
...  
Keyword(s):  
Mesoporous Silica ◽  
Au Nanoparticles ◽  
Catalyst System ◽  
Silica Nanotubes ◽  
Novel Catalyst ◽  
Magnetic Mesoporous Silica

Pd nanoparticles supported on amino-functionalized magnetic mesoporous silica nanotubes: a highly selective catalyst for the catalytic hydrodechlorination reaction

RSC Advances ◽  
2016 ◽  
Vol 6 (80) ◽  
pp. 76582-76589 ◽  
Author(s):  
Shiling Zhao ◽  
Chang Zhao ◽  
Xinzhe Li ◽  
Feng Li ◽  
Lixin Jiao ◽  
...  
Keyword(s):  
Mesoporous Silica ◽  
Pd Nanoparticles ◽  
Catalytic Performance ◽  
Silica Nanotubes ◽  
Selective Catalyst ◽  
Catalytic Hydrodechlorination ◽  
Amine Functionalized ◽  
Highly Dispersed ◽  
Magnetic Mesoporous Silica

Highly dispersed Pd nanoparticles supported on amine-functionalized magnetic mesoporous silica nanotubes are prepared. This catalyst exhibits remarkable catalytic performance for the HDC reaction.

scholarly journals Fabrication of the magnetic mesoporous silica Fe-MCM-41-A as efficient adsorbent: performance, kinetics and mechanism

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Yige Guo ◽  
Bin Chen ◽  
Ying Zhao ◽  
Tianxue Yang
Keyword(s):  
Mesoporous Silica ◽  
Zero Valent Iron ◽  
Maximum Adsorption Capacity ◽  
Order Kinetic ◽  
Environment And Health ◽  
Transmission Electron ◽  
Order Kinetic Model ◽  
Neutral Conditions ◽  
Magnetic Mesoporous Silica ◽  
Mcm 41

AbstractAntibiotics are emerging pollutants and increasingly present in aquaculture and industrial wastewater. Due to their impact on the environment and health, their removal has recently become a significant concern. In this investigation, we synthesized nano zero-valent iron-loaded magnetic mesoporous silica (Fe-MCM-41-A) via precipitation and applied the adsorption of oxytetracycline (OTC) from an aqueous solution. The effects of competing ions such as Na+, Ca2+ and Cu2+ on the adsorption process under different pH conditions were studied in depth to providing a theoretical basis for the application of nanomaterials. The characterization of the obtained material through transmission electron microscopy demonstrates that the adsorbent possesses hexagonal channels, which facilitate mass transfer during adsorption. The loaded zero-valent iron made the magnetic, and was thus separated under an applied magnetic field. The adsorption of OTC onto Fe-MCM-41-A is rapid and obeys the pseudo-second-order kinetic model, and the maximum adsorption capacity of OTC is 625.90 mg g−1. The reaction between OTC and Fe-MCM-41-A was inner complexation and was less affected by the Na+. The effect of Ca2+ on the adsorption was small under acidic and neutral conditions. However, the promotion effect of Ca2+ increased by the increase of pH. Cu2+ decreased the removal efficiencies continuously and the inhibitory effects decrease varied with the increase of pH. We propose that surface complexing, ion-exchange, cationic π-bonding, hydrogen bonding, and hydrophobicity are responsible for the adsorption of OTC onto Fe-MCM-41-A.

Synthesis of magnetic mesoporous silica composites via a modified Stöber approach

2014 ◽  
Vol 21 (5) ◽  
pp. 513-519 ◽  
Author(s):  
Fei Wang ◽  
Ziheng Li ◽  
Dan Liŭ ◽  
Guoqiang Wang ◽  
Dan Liú
Keyword(s):  
Mesoporous Silica ◽  
Magnetic Mesoporous Silica

A Novel Catalyst System, Antimony(V) Chloride-Lithium Perchlorate (SbCl5-LiClO4), in the Friedel-Crafts Acylation Reaction

1992 ◽  
Vol 21 (3) ◽  
pp. 435-438 ◽  
Author(s):  
Teruaki Mukaiyama ◽  
Kaoru Suzuki ◽  
Jeong Sik Han ◽  
Shu Kobayashi
Keyword(s):  
Lithium Perchlorate ◽  
Catalyst System ◽  
Acylation Reaction ◽  
Novel Catalyst
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