PO43− polyanion-doping for stabilizing Li-rich layered oxides as cathode materials for advanced lithium-ion batteries

2014 ◽  
Vol 2 (20) ◽  
pp. 7454-7460 ◽  
Author(s):  
H. Z. Zhang ◽  
Q. Q. Qiao ◽  
G. R. Li ◽  
X. P. Gao
Keyword(s):  
Energy Density ◽  
Transition Metal ◽  
Lithium Ion Batteries ◽  
Cathode Materials ◽  
Lithium Ion ◽  
Metal Cations ◽  
Layered Oxides ◽  
Transition Metal Cations

PO43− polyanion-doped Li-rich layered oxides offer excellent energy density retention during long cycling due to the stronger anion bonding of PO43− polyanions to transition metal cations.

Tailoring atomic distribution in micron-sized and spherical Li-rich layered oxides as cathode materials for advanced lithium-ion batteries

2016 ◽  
Vol 4 (20) ◽  
pp. 7689-7699 ◽  
Author(s):  
Peiyu Hou ◽  
Guoran Li ◽  
Xueping Gao
Keyword(s):  
Thermal Stability ◽  
Energy Density ◽  
Lithium Ion Batteries ◽  
Cathode Materials ◽  
Concentration Gradient ◽  
Lithium Ion ◽  
Cycle Life ◽  
Layered Oxides ◽  
Long Cycle ◽  
Long Cycle Life

A concentration-gradient doping strategy is introduced into micron-sized spherical Li-rich layered oxides. As a result, they exhibit high volumetric energy density, long cycle life and enhanced thermal stability.

Self-assembly and Li-ion storage performance of three new Nb/W mixed-addendum polyoxometalates based on the {SiNb3W9O40} clusters and transition-metal cations

CrystEngComm ◽  
2019 ◽  
Vol 21 (12) ◽  
pp. 1862-1866 ◽  
Author(s):  
Hai-Yang Wu ◽  
Min Huang ◽  
Chao Qin ◽  
Xin-Long Wang ◽  
Hai Hu ◽  
...  
Keyword(s):  
Transition Metal ◽  
Lithium Ion Batteries ◽  
Self Assembly ◽  
Anode Materials ◽  
Lithium Ion ◽  
Metal Cations ◽  
Transition Metal Cations ◽  
Storage Performance ◽  
Ion Storage ◽  
Li Ion

Three polyoxometalates have been synthesized to be utilized as anode materials for lithium ion batteries.

Li- and Mn-rich layered oxide cathode materials for lithium-ion batteries: a review from fundamentals to research progress and applications

2018 ◽  
Vol 3 (5) ◽  
pp. 748-803 ◽  
Author(s):  
Hongge Pan ◽  
Shiming Zhang ◽  
Jian Chen ◽  
Mingxia Gao ◽  
Yongfeng Liu ◽  
...  
Keyword(s):  
Energy Density ◽  
Lithium Ion Batteries ◽  
Cathode Materials ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Research Progress ◽  
Layered Oxides ◽  
Layered Oxide ◽  
Oxide Cathode

Li- and Mn-rich layered oxides (LMRO) have drawn much attention for application as cathode materials for lithium-ion batteries due to their high-energy density of over 1000 W h kg−1.

Boosting Cycling Stability of Ni-rich Layered Oxide Cathode by Dry Coating of Ultrastable Li3V2(PO4)3 Nanoparticles

Nanoscale ◽  
2021 ◽  
Author(s):  
Dongdong Wang ◽  
Qizhang Yan ◽  
Mingqian Li ◽  
Hongpeng Gao ◽  
Jianhua Tian ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Cathode Materials ◽  
Lithium Ion ◽  
High Energy ◽  
Cycling Stability ◽  
Next Generation ◽  
Layered Oxides ◽  
Dry Coating ◽  
Layered Oxide ◽  
Oxide Cathode

Nickel (Ni)-rich layered oxides such as LiNi0.6Co0.2Mn0.2O2 (NCM622) represent one of the most promising candidates for the next-generation high-energy lithium-ion batteries (LIBs). However, the pristine Ni-rich cathode materials usually suffer...

Nanorod-like Ni-rich layered cathode with enhanced Li+ diffusion pathway for high-performance lithium-ion batteries

2021 ◽  
Author(s):  
Fangkun Li ◽  
Zhengbo Liu ◽  
Jiadong Shen ◽  
Xijun Xu ◽  
Liyan Zeng ◽  
...  
Keyword(s):  
Energy Density ◽  
Lithium Ion Batteries ◽  
Cathode Materials ◽  
High Performance ◽  
Low Cost ◽  
Lithium Ion ◽  
Layered Oxide ◽  
Diffusion Pathway ◽  
Oxide Cathodes ◽  
Layered Oxide Cathodes

Ni-rich LiNixCoyMn1-x-yO2 (x 0.6) layered oxide cathodes are one of the most promising cathode materials for lithium-ion batteries owing to their superior capacity, prominent energy density and low cost. However,...

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