scholarly journals γ-Al2O3 supported Pd@CeO2 core@shell nanospheres: salting-out assisted growth and self-assembly, and their catalytic performance in CO oxidation

2015 ◽  
Vol 6 (5) ◽  
pp. 2877-2884 ◽  
Author(s):  
Xiao Wang ◽  
Dapeng Liu ◽  
Junqi Li ◽  
Jiangman Zhen ◽  
Fan Wang ◽  
...  

Highly active Pd@CeO2 core@shell nanospheres with tunable Pd core sizes for catalytic CO oxidation.

RSC Advances ◽  
2016 ◽  
Vol 6 (79) ◽  
pp. 75126-75132 ◽  
Author(s):  
Weining Zhang ◽  
Qingguo Zhao ◽  
Xiaohong Wang ◽  
Xiaoxia Yan ◽  
Sheng Han ◽  
...  

Au@CuxO core–shell nanoparticles and Au@CuxO/Al2O3 used for CO oxidation at low temperature are prepared. CO conversion on Au@CuxO/Al2O3 can reach to 38% at room temperature and the catalytic activity remains unchanged after 108 hours reaction.


NANO ◽  
2017 ◽  
Vol 12 (03) ◽  
pp. 1750039 ◽  
Author(s):  
Ling Liu ◽  
Jingjing Shi ◽  
Hongxia Cao ◽  
Ruiyu Wang

Rational design and fabrication of heterogeneous core–shell nanostructures is of great significance because their two-phase interface could render hybrid junctions with rich redox reactions, which are beneficial for improving catalytic performance. Herein, hierarchical CeO2 yolk-shell nanospheres@MnO2 nanosheets core–shell nanostructures were fabricated by a multistep wet chemical synthetic strategy. The resulting CeO2@MnO2 core–shell nanospheres exhibited high catalytic activity toward CO oxidation in comparison with pure CeO2 and MnO2 structures and their physical and chemical mixture. The enhanced catalytic performance should be attributed to the formation of core–shell structure and the possible synergistic effects between the two components of MnO2 and CeO2, which facilitates materials with promoted redox properties and enhanced oxidation activity. In addition, this synthetic method is expected to extend to fabricate other multi-composite core–shell structures for a broad range of technical applications.


Carbon ◽  
2020 ◽  
Vol 156 ◽  
pp. 463-469
Author(s):  
Liyun Zhang ◽  
Yuxiao Ding ◽  
Yoobin Esther Koh ◽  
Bongjin Simon Mun ◽  
Kuang-Hsu Wu ◽  
...  

2016 ◽  
Vol 4 (8) ◽  
pp. 943-949 ◽  
Author(s):  
Dong Pi ◽  
Wen Zhi Li ◽  
Qi Zhao Lin ◽  
Qi Fu Huang ◽  
Hui Qing Hu ◽  
...  

2019 ◽  
Vol 4 (5) ◽  
pp. 1232-1238 ◽  
Author(s):  
Sang-Il Choi ◽  
Allison Young ◽  
Sujin R. Lee ◽  
Cheng Ma ◽  
Ming Luo ◽  
...  

The Pd@Rh core-shell nanocrystals exhibit enhanced CO oxidation reaction kinetics relative to the monometallic counterparts.


Surfaces ◽  
2020 ◽  
Vol 3 (2) ◽  
pp. 251-264
Author(s):  
Antony Ananth ◽  
Rak Hyun Jeong ◽  
Jin-Hyo Boo

This research dealt with the preparation and characterization of silver oxide (SLO) nanomaterials (NMs) and their composite catalysts (i.e., silver and ruthenium oxide (SLORUO)). The prepared materials were tested for their catalytic performance in carbon monoxide (CO) oxidation. Generally, silver in its pure state is not widely used for CO oxidation due to stability and structural issues. However, the usage of subsurface oxygen and oxygen-induced reconstruction could be effective as an oxidation catalyst at a slightly high temperature. The low-temperature reaction of highly active RuO2 (RUO) is a well-known phenomenon. Thus, the possibility of using it with SLO to observe the combined catalytic behavior was investigated. The wet chemically prepared SLO and SLORUO NMs exhibited spherical and rods in spherical aggregate-type surface morphology belonging to cubic and rutile crystalline structures, respectively. The NMs and catalysts (i.e., the NMs on γ-Al2O3 catalyst support at 0.5 and 1.0 wt.% ranges) showed good thermal stability. The dry and wet CO oxidation using RUO and SLO showed concentration-dependent catalytic activity. The RUO, SLO, and SLORUO composites using 0.5 wt.% showed full CO oxidation at 200, 300, and 225 °C, respectively. The reasons for the observed activity of the catalysts are explained based on the pore characteristics, chemical composition, and dispersion using H2 temperature-programmed reduction (TPR) behaviors.


2012 ◽  
Vol 294 ◽  
pp. 29-36 ◽  
Author(s):  
Lequan Liu ◽  
Botao Qiao ◽  
Yude He ◽  
Feng Zhou ◽  
Benqun Yang ◽  
...  

2001 ◽  
Vol 211 (2) ◽  
pp. 167-174 ◽  
Author(s):  
A.M Venezia ◽  
L.F Liotta ◽  
G Deganello ◽  
Z Schay ◽  
D Horváth ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document