scholarly journals Visible light photocatalytic reduction of aldehydes by Rh(iii)–H: a detailed mechanistic study

2015 ◽  
Vol 6 (3) ◽  
pp. 2027-2034 ◽  
Author(s):  
T. Ghosh ◽  
T. Slanina ◽  
B. König
Keyword(s):  
Electron Transfer ◽  
Metal Complex ◽  
Visible Light ◽  
Radical Anion ◽  
Photocatalytic Reduction ◽  
Reaction Pathways ◽  
Mechanistic Study ◽  
Solvated Electron ◽  
Visible Light Photocatalytic

The slow visible light mediated generation of a rhodium hydride allows the chemoselective reduction of aldehydes in the presence of ketones. Electron transfer from the chromophore to the metal complex proceeds via a radical anion intermediate or a solvated electron as two competing reaction pathways.

scholarly journals A comprehensive mechanistic study on the visible-light photocatalytic reductive dehalogenation of haloaromatics mediated by Ru(bpy)3Cl2

2017 ◽  
Vol 7 (20) ◽  
pp. 4852-4858 ◽  
Author(s):  
Mireia Marin ◽  
Miguel A. Miranda ◽  
M. Luisa Marin
Keyword(s):  
Visible Light ◽  
Kinetic Data ◽  
Emission Spectroscopy ◽  
Photocatalytic Reduction ◽  
Reductive Dehalogenation ◽  
Mechanistic Study ◽  
Time Resolved ◽  
Fast Kinetic ◽  
Visible Light Photocatalytic

Fast kinetic data from time-resolved emission spectroscopy shine light on the mechanism involved in the Ru(bpy)32+-photocatalytic reduction of halonitrobenzenes.

Visible-Light Photocatalytic Reduction of Sulfonium Salts as a Source of Aryl Radicals

2013 ◽  
Vol 355 (8) ◽  
pp. 1477-1482 ◽  
Author(s):  
Simon Donck ◽  
Abdulkader Baroudi ◽  
Louis Fensterbank ◽  
Jean-Philippe Goddard ◽  
Cyril Ollivier
Keyword(s):  
Visible Light ◽  
Photocatalytic Reduction ◽  
Sulfonium Salts ◽  
Aryl Radicals ◽  
Visible Light Photocatalytic

scholarly journals The synthesis of a BiOClxBr1−x nanostructure photocatalyst with high surface area for the enhanced visible-light photocatalytic reduction of Cr(vi)

RSC Advances ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 4763-4771 ◽  
Author(s):  
Muhammad Bilal Hussain ◽  
Malik Saddam Khan ◽  
Herman Maloko Loussala ◽  
Muhammad Sohail Bashir
Keyword(s):  
Visible Light ◽  
Surface Area ◽  
Room Temperature ◽  
High Surface ◽  
High Surface Area ◽  
Photocatalytic Reduction ◽  
Synthetic Process ◽  
Visible Light Photocatalytic

Cr(vi) reduction is performed by BiOCl0.8Br0.2 composite produced via a facile in situ synthetic process at room temperature while making use of PVP (Mw = 10 000).

Visible‐Light Photocatalytic Reduction of CO 2 to Formic Acid with a Ru Catalyst Supported by N , N ′‐Bis(diphenylphosphino)‐2,6‐diaminopyridine Ligands

ChemSusChem ◽  
2019 ◽  
Vol 12 (15) ◽  
pp. 3453-3457
Author(s):  
Yasmeen Hameed ◽  
Gyandshwar Kumar Rao ◽  
Jeffrey S. Ovens ◽  
Bulat Gabidullin ◽  
Darrin Richeson
Keyword(s):  
Formic Acid ◽  
Visible Light ◽  
Photocatalytic Reduction ◽  
Ru Catalyst ◽  
Visible Light Photocatalytic
Sign in / Sign up

Export Citation Format

Share Document