scholarly journals The pentafluorophenyl group as π-acceptor for anions: a case study

2015 ◽  
Vol 6 (1) ◽  
pp. 354-359 ◽  
Author(s):  
Michael Giese ◽  
Markus Albrecht ◽  
Arto Valkonen ◽  
Kari Rissanen
Keyword(s):  
Solid State ◽  
Structural Study ◽  
Structural Differences ◽  
Solid State Structures

A unique structural study investigates the variability of anion–π bonding in the solid state structures of pentafluorophenyl arenes. The hapticity concept is used as tool to describe the structural differences of various anion–π complexes.

Do Solid-State Structures Reflect Lewis Acidity Trends of Heavier Group 13 Trihalides? Experimental and Theoretical Case Study

2012 ◽  
Vol 51 (21) ◽  
pp. 11602-11611 ◽  
Author(s):  
Alexey Y. Timoshkin ◽  
Michael Bodensteiner ◽  
Tatiana N. Sevastianova ◽  
Anna S. Lisovenko ◽  
Elena I. Davydova ◽  
...  
Keyword(s):  
Solid State ◽  
Lewis Acidity ◽  
Group 13 ◽  
Solid State Structures

A comparative structural study of alkane- α,ω-diphosphonic acids

2015 ◽  
Vol 230 (7) ◽  
Author(s):  
Martin van Megen ◽  
Walter Frank ◽  
Guido J. Reiss
Keyword(s):  
Solid State ◽  
Structural Study ◽  
Homologous Series ◽  
Diphosphonic Acids ◽  
Solid State Structures

AbstractIn a comparative structural study, the solid state structures within the homologous series of alkane-

Atom Assignment in Solid-State Structures on the Basis of X-ray Crystallography and DFT Calculations – A Case Study on a Molecular Cu–Sb Alloy

2006 ◽  
Vol 2006 (6) ◽  
pp. 1127-1129 ◽  
Author(s):  
Reinhart Ahlrichs ◽  
Dieter Fenske ◽  
Alexander Rothenberger ◽  
Claudia Schrodt ◽  
Stephan Wieber
Keyword(s):  
Solid State ◽  
Dft Calculations ◽  
X Ray ◽  
X Ray Crystallography ◽  
Solid State Structures

Dual approach for concomitant monitoring of dissolution and transformation at solid-state. Mebendazole salts case study

2020 ◽  
Vol 55 ◽  
pp. 101344 ◽  
Author(s):  
Gerardo E. Camí ◽  
Elena V. Brusau ◽  
Griselda E. Narda ◽  
Rubén M. Maggio
Keyword(s):  
Solid State ◽  
Dual Approach

scholarly journals Switching-On Fluorescence by Copper (II) and Basic Anions: A Case Study with a Pyrene-Functionalized Squaramide

Molecules ◽  
2021 ◽  
Vol 26 (5) ◽  
pp. 1301
Author(s):  
Giacomo Picci ◽  
Jessica Milia ◽  
Maria Carla Aragoni ◽  
Massimiliano Arca ◽  
Simon J. Coles ◽  
...  
Keyword(s):  
Solid State ◽  
Copper Complex ◽  
Receptor Complex ◽  
Emission Properties ◽  
Naked Eye ◽  
Intense Emission ◽  
Uv Lamp

The new symmetric acyclic N,N’-bis(1-pyrenyl) squaramide (H2L) functionalized with the pyrene moiety as a fluorogenic fragment has been designed and its ability to selectively detect specific anions and metals investigated. H2L selectively binds Cl− both in solution (DMSO 0.5% H2O and MeCN) and in the solid state, and allows to selectively detect Cu2+ in MeCN with the formation of a 2:1 metal-receptor complex, with a green intense emission appreciable by naked eye under the UV lamp. The H2L copper complex preserves its emission properties in the presence of Cl−. The addition of basic anions (OH−, CN−, and F−) up to 10 equivalents caused the deprotonation of the squaramide NHs and a dramatic change of the emission properties of the H2L copper complex.

Synthesis and solid state structures of macromolecular cylindrical brushes with varying side chain length

Polymer ◽  
2004 ◽  
Vol 45 (12) ◽  
pp. 4009-4015 ◽  
Author(s):  
Bin Zhang ◽  
Shanju Zhang ◽  
Lidia Okrasa ◽  
Tadeusz Pakula ◽  
Tim Stephan ◽  
...  
Keyword(s):  
Solid State ◽  
Chain Length ◽  
Side Chain ◽  
Side Chain Length ◽  
Solid State Structures
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