Ligand design for Rh(iii)-catalyzed C–H activation: an unsymmetrical cyclopentadienyl group enables a regioselective synthesis of dihydroisoquinolones

Todd K. Hyster; Derek M. Dalton; Tomislav Rovis

doi:10.1039/c4sc02590c

Ligand design for Rh(iii)-catalyzed C–H activation: an unsymmetrical cyclopentadienyl group enables a regioselective synthesis of dihydroisoquinolones

Chemical Science ◽

10.1039/c4sc02590c ◽

2015 ◽

Vol 6 (1) ◽

pp. 254-258 ◽

Cited By ~ 96

Author(s):

Todd K. Hyster ◽

Derek M. Dalton ◽

Tomislav Rovis

Keyword(s):

Ligand Design ◽

Regioselective Synthesis ◽

Cyclopentadienyl Ligand

A modified cyclopentadienyl ligand greatly improves regioselectivity in Rh(iii) catalyzed alkene insertion/C–H activation.

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Correction: Ligand design for Rh(iii)-catalyzed C–H activation: an unsymmetrical cyclopentadienyl group enables a regioselective synthesis of dihydroisoquinolones

Chemical Science ◽

10.1039/c6sc90080a ◽

2017 ◽

Vol 8 (2) ◽

pp. 1666-1666

Author(s):

Todd K. Hyster ◽

Derek M. Dalton ◽

Tomislav Rovis

Keyword(s):

Ligand Design ◽

Regioselective Synthesis

Correction for ‘Ligand design for Rh(iii)-catalyzed C–H activation: an unsymmetrical cyclopentadienyl group enables a regioselective synthesis of dihydroisoquinolones’ by Todd K. Hyster et al., Chem. Sci., 2015, 6, 254–258.

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Correction: Ligand design for Rh(iii)-catalyzed C–H activation: an unsymmetrical cyclopentadienyl group enables a regioselective synthesis of dihydroisoquinolones

Chemical Science ◽

10.1039/c8sc90195c ◽

2018 ◽

Vol 9 (41) ◽

pp. 8024-8024 ◽

Cited By ~ 5

Author(s):

Todd K. Hyster ◽

Derek M. Dalton ◽

Tomislav Rovis

Keyword(s):

Ligand Design ◽

Regioselective Synthesis

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Corrigendum: Rhodium(III) Complex with a Bulky Cyclopentadienyl Ligand as a Catalyst for Regioselective Synthesis of Dihydroisoquinolones through C−H Activation of Arylhydroxamic Acids

Chemistry - A European Journal ◽

10.1002/chem.202003068 ◽

2020 ◽

Author(s):

Evgeniya A. Trifonova ◽

Nikita M. Ankudinov ◽

Maxim V. Kozlov ◽

Mikhail Y. Sharipov ◽

Yulia V. Nelyubina ◽

...

Keyword(s):

Regioselective Synthesis ◽

Cyclopentadienyl Ligand ◽

Arylhydroxamic Acids

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Frontispiece: Rhodium(III) Complex with a Bulky Cyclopentadienyl Ligand as a Catalyst for Regioselective Synthesis of Dihydroisoquinolones through C−H Activation of Arylhydroxamic Acids

Chemistry - A European Journal ◽

10.1002/chem.201886264 ◽

2018 ◽

Vol 24 (62) ◽

Author(s):

Evgeniya A. Trifonova ◽

Nikita M. Ankudinov ◽

Maxim V. Kozlov ◽

Mikhail Y. Sharipov ◽

Yulia V. Nelyubina ◽

...

Keyword(s):

Regioselective Synthesis ◽

Cyclopentadienyl Ligand ◽

Arylhydroxamic Acids

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ChemInform Abstract: Ligand Design for Rh(III)-Catalyzed C-H Activation: An Unsymmetrical Cyclopentadienyl Group Enables a Regioselective Synthesis of Dihydroisoquinolones.

ChemInform ◽

10.1002/chin.201523175 ◽

2015 ◽

Vol 46 (23) ◽

pp. no-no

Author(s):

Todd K. Hyster ◽

Derek M. Dalton ◽

Tomislav Rovis

Keyword(s):

Ligand Design ◽

Regioselective Synthesis

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Rhodium(III) Complex with a Bulky Cyclopentadienyl Ligand as a Catalyst for Regioselective Synthesis of Dihydroisoquinolones through C−H Activation of Arylhydroxamic Acids

Chemistry - A European Journal ◽

10.1002/chem.201804050 ◽

2018 ◽

Vol 24 (62) ◽

pp. 16570-16575 ◽

Cited By ~ 22

Author(s):

Evgeniya A. Trifonova ◽

Nikita M. Ankudinov ◽

Maxim V. Kozlov ◽

Mikhail Y. Sharipov ◽

Yulia V. Nelyubina ◽

...

Keyword(s):

Regioselective Synthesis ◽

Cyclopentadienyl Ligand ◽

Arylhydroxamic Acids

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2-O-Acyl-3-O-(1-Acyloxyalkyl) Prodrugs of 5,6-Isopropylidene-L-Ascorbic Acid and L-Ascorbic Acid: Regioselective Synthesis, Antioxidant Activity, and Ability to Permeate Silicone Membranes

10.26226/morressier.57d6b2b5d462b8028d88ddf1 ◽

2016 ◽

Author(s):

Kenneth Sloan

Keyword(s):

Antioxidant Activity ◽

Ascorbic Acid ◽

Regioselective Synthesis ◽

Silicone Membranes

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OnePot Regioselective Synthesis of Heterocyclic Compounds by the Application of Sonogashira Reaction as One of the Steps: A Review

Journal of Chemistry and Chemical Sciences ◽

10.29055/jccs/576 ◽

2018 ◽

Vol 8 (2) ◽

pp. 212-230

Author(s):

Sanjay Nath

Keyword(s):

Heterocyclic Compounds ◽

Regioselective Synthesis ◽

Sonogashira Reaction ◽

One Pot

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Faculty Opinions recommendation of Ligand Design to Acquire Specificity to Intended G-Quadruplex Structures.

Faculty Opinions – Post-Publication Peer Review of the Biomedical Literature ◽

10.3410/f.733716143.793557206 ◽

2019 ◽

Author(s):

Jonathan Chaires

Keyword(s):

Ligand Design ◽

G Quadruplex

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Class A GPCRs: Structure, Function, Modeling and Structure-based Ligand Design

Current Pharmaceutical Design ◽

10.2174/1381612823666170710151255 ◽

2017 ◽

Vol 23 (29) ◽

Cited By ~ 13

Author(s):

Xiaojing Cong ◽

Jeremie Topin ◽

Jerome Golebiowski

Keyword(s):

Structure Function ◽

Ligand Design ◽

Class A

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Ligand design for Rh(iii)-catalyzed C–H activation: an unsymmetrical cyclopentadienyl group enables a regioselective synthesis of dihydroisoquinolones

Correction: Ligand design for Rh(iii)-catalyzed C–H activation: an unsymmetrical cyclopentadienyl group enables a regioselective synthesis of dihydroisoquinolones

Correction: Ligand design for Rh(iii)-catalyzed C–H activation: an unsymmetrical cyclopentadienyl group enables a regioselective synthesis of dihydroisoquinolones

Corrigendum: Rhodium(III) Complex with a Bulky Cyclopentadienyl Ligand as a Catalyst for Regioselective Synthesis of Dihydroisoquinolones through C−H Activation of Arylhydroxamic Acids

Frontispiece: Rhodium(III) Complex with a Bulky Cyclopentadienyl Ligand as a Catalyst for Regioselective Synthesis of Dihydroisoquinolones through C−H Activation of Arylhydroxamic Acids

ChemInform Abstract: Ligand Design for Rh(III)-Catalyzed C-H Activation: An Unsymmetrical Cyclopentadienyl Group Enables a Regioselective Synthesis of Dihydroisoquinolones.

Rhodium(III) Complex with a Bulky Cyclopentadienyl Ligand as a Catalyst for Regioselective Synthesis of Dihydroisoquinolones through C−H Activation of Arylhydroxamic Acids

2-O-Acyl-3-O-(1-Acyloxyalkyl) Prodrugs of 5,6-Isopropylidene-L-Ascorbic Acid and L-Ascorbic Acid: Regioselective Synthesis, Antioxidant Activity, and Ability to Permeate Silicone Membranes

OnePot Regioselective Synthesis of Heterocyclic Compounds by the Application of Sonogashira Reaction as One of the Steps: A Review

Faculty Opinions recommendation of Ligand Design to Acquire Specificity to Intended G-Quadruplex Structures.

Class A GPCRs: Structure, Function, Modeling and Structure-based Ligand Design

OnePot Regioselective Synthesis of Heterocyclic Compounds by the Application of Sonogashira Reaction as One of the Steps: A Review