scholarly journals Merging of the photocatalysis and copper catalysis in metal–organic frameworks for oxidative C–C bond formation

2015 ◽  
Vol 6 (2) ◽  
pp. 1035-1042 ◽  
Author(s):  
Dongying Shi ◽  
Cheng He ◽  
Bo Qi ◽  
Cong Chen ◽  
Jingyang Niu ◽  
...  
Keyword(s):  
Bond Formation ◽  
Metal Organic Frameworks ◽  
Copper Catalysis ◽  
New Approach ◽  
Metal Organic

A new approach to merge Cu-catalysis/Ru-photocatalysis within one single MOF was achieved by incorporating [SiW11O39Ru(H2O)]5− into Cu–BPY MOFs.

scholarly journals A novel route to size-controlled MIL-53(Fe) metal–organic frameworks for combined chemodynamic therapy and chemotherapy for cancer

RSC Advances ◽  
2021 ◽  
Vol 11 (18) ◽  
pp. 10540-10547
Author(s):  
Anxia Li ◽  
Xiaoxin Yang ◽  
Juan Chen
Keyword(s):  
Drug Delivery ◽  
Therapeutic Approach ◽  
Metal Organic Frameworks ◽  
Ionic Surfactant ◽  
Controlled Synthesis ◽  
New Approach ◽  
Metal Organic ◽  
Size Controlled

In this study, we reported a new approach for the size-controlled synthesis of uniform iron(iii)-based MIL-53 nanocrystals using the non-ionic surfactant PVP. A combinational therapeutic approach was presented for drug delivery and ROS therapy.

scholarly journals Post-synthetic modification of zinc metal-organic frameworks through palladium-catalysed carbon–carbon bond formation

2015 ◽  
Vol 792 ◽  
pp. 134-138 ◽  
Author(s):  
Andrew D. Burrows ◽  
Laura C. Fisher ◽  
Timothy J. Mays ◽  
Sean P. Rigby ◽  
Sharon E. Ashbrook ◽  
...  
Keyword(s):  
Bond Formation ◽  
Metal Organic Frameworks ◽  
Carbon Bond ◽  
Zinc Metal ◽  
Carbon Carbon Bond ◽  
Metal Organic

Tunable titanium metal–organic frameworks with infinite 1D Ti–O rods for efficient visible-light-driven photocatalytic H2 evolution

2019 ◽  
Vol 7 (19) ◽  
pp. 11928-11933 ◽  
Author(s):  
Changqing Li ◽  
Hui Xu ◽  
Junkuo Gao ◽  
Wenna Du ◽  
Liqing Shangguan ◽  
...  
Keyword(s):  
Visible Light ◽  
Metal Organic Frameworks ◽  
Titanium Metal ◽  
H2 Evolution ◽  
New Approach ◽  
Visible Light Driven ◽  
Metal Organic ◽  
Photocatalytic H2 Evolution

A new approach for the synthesis of infinite Ti–O rod-based MOFs with superior photocatalytic H2 evolution performances was developed.

Magnetic coordination clusters and networks: synthesis and topological description

2010 ◽  
Vol 368 (1915) ◽  
pp. 1509-1536 ◽  
Author(s):  
George E. Kostakis ◽  
Ian J. Hewitt ◽  
Ayuk M. Ako ◽  
Valeriu Mereacre ◽  
Annie K. Powell
Keyword(s):  
Magnetic Properties ◽  
Coordination Chemistry ◽  
Single Molecule ◽  
Metal Organic Frameworks ◽  
New Approach ◽  
Topological Description ◽  
Metal Organic ◽  
Paramagnetic Ions

With the discovery of the phenomenon of single-molecule magnetism, coordination chemists have turned their attention to synthesizing cluster aggregates of paramagnetic ions. This has led to a plethora of coordination clusters with various topologies and diverse magnetic properties. In this paper, we present ways of describing and understanding such compounds as well as outlining a new approach, which we have recently developed, to describing cluster topology. Our approach is based upon and pays tribute to the huge contribution made to coordination chemistry through the development of the Schläfli symbols for describing architectures. To illustrate the developments that are taking place in modern coordination chemistry, we start with some basic definitions of relevance to what follows. Then we describe approaches to discovering new magnetically interesting 3d/4f clusters, assigning their topological descriptions. Finally, we show how the concepts behind the construction of metal–organic frameworks can be extended to using clusters as nodes in the frameworks to give super metal–organic frameworks.

A covalent modification strategy for di-alkyne tagged metal-organic frameworks to access efficient heterogeneous catalysts toward C-C bond formation

2022 ◽  
Author(s):  
Qianqian Liang ◽  
Hua Cheng ◽  
Chengwen Li ◽  
Liangmin Ning ◽  
Liming Shao
Keyword(s):  
Heterogeneous Catalysts ◽  
Bond Formation ◽  
Metal Organic Frameworks ◽  
Building Blocks ◽  
Covalent Modification ◽  
Metal Organic

Organic and inorganic building blocks construct a class of metal-organic frameworks (MOFs) that exhibit tremendous chemical tunability. In this study, a novel Zirconium-based MOF UiO-66-(alkyne)2 with a di-alkyne tag was...

scholarly journals Selective One-Pot Two-Step C−C Bond Formation using Metal-Organic Frameworks with Mild Basicity as Heterogeneous Catalysts

ChemCatChem ◽  
2017 ◽  
Vol 9 (21) ◽  
pp. 4019-4023 ◽  
Author(s):  
Francisco G. Cirujano ◽  
Elena López-Maya ◽  
Marleny Rodríguez-Albelo ◽  
Elisa Barea ◽  
Jorge A. R. Navarro ◽  
...  
Keyword(s):  
Heterogeneous Catalysts ◽  
Bond Formation ◽  
Metal Organic Frameworks ◽  
One Pot ◽  
Metal Organic

scholarly journals Factors Affecting Hydrogen Adsorption in Metal–Organic Frameworks: A Short Review

Nanomaterials ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1638
Author(s):  
Vladimír Zeleňák ◽  
Ivan Saldan
Keyword(s):  
Hydrogen Storage ◽  
Hydrogen Adsorption ◽  
Metal Organic Frameworks ◽  
Hydrogen Uptake ◽  
Short Review ◽  
High Rate ◽  
New Approach ◽  
Factors Affecting ◽  
Metal Organic ◽  
Near Future

Metal–organic frameworks (MOFs) have significant potential for hydrogen storage. The main benefit of MOFs is their reversible and high-rate hydrogen adsorption process, whereas their biggest disadvantage is related to their operation at very low temperatures. In this study, we describe selected examples of MOF structures studied for hydrogen adsorption and different factors affecting hydrogen adsorption in MOFs. Approaches to improving hydrogen uptake are reviewed, including surface area and pore volume, in addition to the value of isosteric enthalpy of hydrogen adsorption. Nanoconfinement of metal hydrides inside MOFs is proposed as a new approach to hydrogen storage. Conclusions regarding MOFs with incorporated metal nanoparticles, which may be used as nanoscaffolds and/or H2 sorbents, are summarized as prospects for the near future.

scholarly journals Stable metal–organic frameworks with low water affinity built from methyl-siloxane linkers

2020 ◽  
Vol 56 (57) ◽  
pp. 7905-7908
Author(s):  
Luke C. Delmas ◽  
Andrew J. P. White ◽  
David Pugh ◽  
Arwyn Evans ◽  
Mark Antonin Isbell ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
New Approach ◽  
Metal Organic ◽  
Water Affinity

A new approach to the development of MOF materials with low water affinity is presented using siloxane-derived linkers. The low water affinity is conferred by the linker without the requirement of any post-synthetic processing apart from activation.

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