scholarly journals Amine α-heteroarylation via photoredox catalysis: a homolytic aromatic substitution pathway

2014 ◽  
Vol 5 (11) ◽  
pp. 4173-4178 ◽  
Author(s):  
Christopher K. Prier ◽  
David W. C. MacMillan
Keyword(s):  
Tertiary Amines ◽  
Photoredox Catalysis ◽  
Aromatic Substitution ◽  
Homolytic Aromatic Substitution

The direct α-heteroarylation of tertiary amines has been accomplished via photoredox catalysis to generate valuable benzylic amine pharmacophores.

A new era for homolytic aromatic substitution: replacing Bu3SnH with efficient light-induced chain reactions

2016 ◽  
Vol 14 (16) ◽  
pp. 3849-3862 ◽  
Author(s):  
Michael Gurry ◽  
Fawaz Aldabbagh
Keyword(s):  
Visible Light ◽  
Photoredox Catalysis ◽  
Aromatic Substitution ◽  
New Era ◽  
Chain Reactions ◽  
Radical Initiator ◽  
Aromatic Heterocycles ◽  
Recent Advances ◽  
Homolytic Aromatic Substitution

Recent advances such as visible-light photoredox catalysis have largely superseded radical initiator-mediated substitutions onto arenes and aromatic heterocycles.

Reversibility of homolytic aromatic substitution: the reaction of p-xylene with phenyl radicals

1974 ◽  
pp. 987 ◽  
Author(s):  
Roberto Henriquez ◽  
Alistair R. Morgan ◽  
Peter Mulholland ◽  
Derek C. Nonhebel ◽  
George G. Smith
Keyword(s):  
Aromatic Substitution ◽  
Phenyl Radicals ◽  
Homolytic Aromatic Substitution
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