Comprehensive study of carbon dioxide adsorption in the metal–organic frameworks M2(dobdc) (M = Mg, Mn, Fe, Co, Ni, Cu, Zn)

2014 ◽  
Vol 5 (12) ◽  
pp. 4569-4581 ◽  
Author(s):  
Wendy L. Queen ◽  
Matthew R. Hudson ◽  
Eric D. Bloch ◽  
Jarad A. Mason ◽  
Miguel I. Gonzalez ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Metal Organic Frameworks ◽  
Carbon Dioxide Adsorption ◽  
Metal Organic ◽  
Comprehensive Study

scholarly journals Poly(ionic liquid)-Modified Metal Organic Framework for Carbon Dioxide Adsorption

Polymers ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 370 ◽  
Author(s):  
Guangyuan Yang ◽  
Jialin Yu ◽  
Sanwen Peng ◽  
Kuang Sheng ◽  
Haining Zhang
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquid ◽  
Composite Materials ◽  
Metal Organic Frameworks ◽  
Carbon Dioxide Partial Pressure ◽  
Carbon Dioxide Adsorption ◽  
Solid Sorbent ◽  
Practical Applications ◽  
Metal Organic ◽  
Poly Ionic Liquid

The design and synthesis of solid sorbents for effective carbon dioxide adsorption are essential for practical applications regarding carbon emissions. Herein, we report the synthesis of composite materials consisting of amine-functionalized imidazolium-type poly(ionic liquid) (PIL) and metal organic frameworks (MOFs) through complexation of amino groups and metal ions. The carbon dioxide adsorption behavior of the synthesized composite materials was evaluated using the temperature-programmed desorption (TPD) technique. Benefiting from the large surface area of metal organic frameworks and high carbon dioxide diffusivity in ionic liquid moieties, the carbon dioxide adsorption capacity of the synthesized composite material reached 19.5 cm3·g−1, which is much higher than that of pristine metal organic frameworks (3.1 cm3·g−1) under carbon dioxide partial pressure of 0.2 bar at 25 °C. The results demonstrate that the combination of functionalized poly(ionic liquid) with metal organic frameworks can be a promising solid sorbent for carbon dioxide adsorption.

scholarly journals Carbon Dioxide Adsorption in Amine-Functionalized Mixed-Ligand Metal-Organic Frameworks of UiO-66 Topology

ChemSusChem ◽  
2014 ◽  
Vol 7 (12) ◽  
pp. 3382-3388 ◽  
Author(s):  
Jayashree Ethiraj ◽  
Elisa Albanese ◽  
Bartolomeo Civalleri ◽  
Jenny G. Vitillo ◽  
Francesca Bonino ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Metal Organic Frameworks ◽  
Mixed Ligand ◽  
Carbon Dioxide Adsorption ◽  
Amine Functionalized ◽  
Metal Organic

scholarly journals Cooperative Carbon Dioxide Adsorption in Alcoholamine‐ and Alkoxyalkylamine‐Functionalized Metal–Organic Frameworks

2020 ◽  
Vol 132 (44) ◽  
pp. 19636-19645
Author(s):  
Victor Y. Mao ◽  
Phillip J. Milner ◽  
Jung‐Hoon Lee ◽  
Alexander C. Forse ◽  
Eugene J. Kim ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Metal Organic Frameworks ◽  
Carbon Dioxide Adsorption ◽  
Metal Organic

Understanding Inflections and Steps in Carbon Dioxide Adsorption Isotherms in Metal-Organic Frameworks

2008 ◽  
Vol 130 (2) ◽  
pp. 406-407 ◽  
Author(s):  
Krista S. Walton ◽  
Andrew R. Millward ◽  
David Dubbeldam ◽  
Houston Frost ◽  
John J. Low ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Adsorption Isotherms ◽  
Metal Organic Frameworks ◽  
Carbon Dioxide Adsorption ◽  
Metal Organic
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