Applications of dynamic electrochemical impedance spectroscopy (DEIS) to evaluate protective coatings formed on AZ31 magnesium alloy

RSC Advances ◽  
2015 ◽  
Vol 5 (37) ◽  
pp. 29589-29593 ◽  
Author(s):  
A. Srinivasan ◽  
Kwang Seon Shin ◽  
N. Rajendran
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Magnesium Alloy ◽  
Impedance Spectroscopy ◽  
Phase Angle ◽  
Electrochemical Impedance ◽  
Protective Coatings ◽  
Az31 Magnesium Alloy ◽  
Applied Potential ◽  
Dynamic Electrochemical Impedance Spectroscopy

Increase in magnitude (IZI) and phase angle maximum values with applied potential reveal the protective nature of the coating.

Dynamic electrochemical impedance spectroscopy (DEIS) studies of AZ31 magnesium alloy in simulated body fluid solution

RSC Advances ◽  
2014 ◽  
Vol 4 (53) ◽  
pp. 27791-27795 ◽  
Author(s):  
A. Srinivasan ◽  
Kwang Seon Shin ◽  
N. Rajendran
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Magnesium Alloy ◽  
Impedance Spectroscopy ◽  
Simulated Body Fluid ◽  
Body Fluid ◽  
Electrochemical Impedance ◽  
Simulated Body Fluid Solution ◽  
Az31 Magnesium Alloy ◽  
Fluid Solution ◽  
Dynamic Electrochemical Impedance Spectroscopy

The change in impedance values as a function of potential indicated the transformation of Mg from its passive to active state.

Analysis on the Anodizing Process of AZ31 Magnesium Alloy in an Environmental Friendly Alkaline Electrolyte

2014 ◽  
Vol 665 ◽  
pp. 128-131
Author(s):  
Zhong Ping Xiong ◽  
Yu Jun Si ◽  
Min Jiao Li
Keyword(s):  
Corrosion Resistance ◽  
Electrochemical Impedance Spectroscopy ◽  
Magnesium Alloy ◽  
Impedance Spectroscopy ◽  
Electrochemical Impedance ◽  
Az31 Magnesium Alloy ◽  
Alkaline Electrolyte ◽  
Environmental Friendly ◽  
Voltage Transient ◽  
A Current

AZ31 magnesium alloy was anodized in an environmental friendly electrolyte containing 50 g/l NaOH + 40 g/l Na2B4O7·10H2O + 60 g/l Na2SiO3·9H2O. The voltage transient was recorded in anodizing process. The surface morphology of anodizing film was examined by SEM. The corrosion resistance of the anodizing film was characterized by electrochemical impedance spectroscopy and potentiodynamic polarization techniques. The results show that the anodizing process can be divided to four stages according to the voltage transient. The anodizing film obtained at a current density of 20 mA·cm-2 for 15 minutes has the optimum corrosion resistance.

Investigation of corrosion behavior of polypyrrole-coated Ti using dynamic electrochemical impedance spectroscopy (DEIS)

RSC Advances ◽  
2016 ◽  
Vol 6 (83) ◽  
pp. 80275-80285 ◽  
Author(s):  
Bhavana Rikhari ◽  
S. Pugal Mani ◽  
N. Rajendran
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Simulated Body Fluid ◽  
Corrosion Behavior ◽  
Body Fluid ◽  
Electrochemical Impedance ◽  
Sbf Solution ◽  
Dynamic Electrochemical Impedance Spectroscopy

In the present work, dynamic electrochemical impedance spectroscopy (DEIS) was used to investigate the corrosion behavior of polypyrrole (PPy)-coated titanium (Ti) in simulated body fluid (SBF) solution.

Evaluation of the corrosion behavior of a TiN-coated 316L SS bipolar plate using dynamic electrochemical impedance spectroscopy

2018 ◽  
Vol 42 (17) ◽  
pp. 14394-14409 ◽  
Author(s):  
S. Pugal Mani ◽  
Bhavana Rikhari ◽  
Perumal Agilan ◽  
N. Rajendran
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Fuel Cell ◽  
Impedance Spectroscopy ◽  
Corrosion Behavior ◽  
Proton Exchange Membrane ◽  
Electrochemical Impedance ◽  
Bipolar Plate ◽  
Proton Exchange ◽  
Exchange Membrane ◽  
Dynamic Electrochemical Impedance Spectroscopy

In the present investigation, the corrosion behavior of TiN-coated 316L SS was evaluated for use in a proton-exchange membrane fuel cell using dynamic electrochemical impedance spectroscopy (DEIS).

Electrochemical Characteristics of Al-Based Coating on Magnesium Alloy Fabricated by Supersonic Particles Deposition

2013 ◽  
Vol 756-759 ◽  
pp. 85-88
Author(s):  
Xiao Ming Wang ◽  
Sheng Zhu ◽  
Qing Chang ◽  
Guo Feng Han
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Magnesium Alloy ◽  
Impedance Spectroscopy ◽  
Current Density ◽  
Corrosion Current Density ◽  
Corrosion Potential ◽  
Electrochemical Impedance ◽  
Corrosion Current ◽  
Electrochemical Characteristics ◽  
Order Of Magnitude

Al-based coating on ZM5 magnesium alloy was prepared by Supersonic Particles Deposition (SPD). Electrochemical working station was utilized to test polarization curve, corrosion potential and electrochemical impedance spectroscopy etc. The results indicted that corrosion potential of Al-Si coating was about-767.6mV, much higher than that of ZM5 Mg-substrate; And corrosion current density of the coating sample decreased three order of magnitude than that of the uncoated. Compared to Mg-substrate, the radius of capacitive impedance arc of the coating enlarged and impedance modulus improved two order of magnitude.

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