Effective liquid phase hydrodechlorination of diclofenac catalysed by Pd/CeO2

RSC Advances ◽  
2015 ◽  
Vol 5 (24) ◽  
pp. 18702-18709 ◽  
Author(s):  
Ke Wu ◽  
Xiaojun Qian ◽  
Liangyan Chen ◽  
Zhaoyi Xu ◽  
Shourong Zheng ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Activated Carbon ◽  
Liquid Phase ◽  
Palladium Catalyst

Palladium catalyst supported on CeO2 exhibited much higher catalytic activity for the liquid phase hydrodechlorination of diclofenac than those on Al2O3, activated carbon and SiO2.

scholarly journals Synergy between Ionic Liquids and CuCl2 in Gas–Liquid Phase Reactions of Acetylene Hydrochlorination

Catalysts ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 504 ◽  
Author(s):  
Yi Yu ◽  
Yuxue Yue ◽  
Bolin Wang ◽  
Haihua He ◽  
Zhong-Ting Hu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Ionic Liquids ◽  
Activated Carbon ◽  
Liquid Phase ◽  
Dft Calculations ◽  
Synergetic Effect ◽  
Good Explanation ◽  
Experimental Results ◽  
Acetylene Hydrochlorination ◽  
Reaction Media

We studied the acetylene hydrochlorination in gas–liquid phase reactions using ionic liquids (IL) as the reaction media and CuCl2 as the catalyst. The Cu-IL catalyst showed strong synergy between the IL and the Cu(II) active catalytic species. For [PrMIm]Cl, the Cu-IL catalyst exhibited significant enhancement of the catalytic activity in comparison with the CuCl2 catalyst supported on activated carbon and the IL alone as the catalyst. We have also performed DFT calculations of the reaction process, which provides a good explanation of our experimental results and for the synergetic effect. Our result suggests that ILs may be used to improve the activity of other metallic catalysts for the hydrochlorination reaction of acetylene.

Granulated Carbon Nanotubes as the Catalyst Support for Pt for the Hydrogenation of Nitrobenzene

2010 ◽  
Vol 63 (1) ◽  
pp. 131 ◽  
Author(s):  
Shao Jin ◽  
Weizhong Qian ◽  
Yi Liu ◽  
Fei Wei ◽  
Dezeng Wang ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Mass Transfer ◽  
Catalytic Activity ◽  
Activated Carbon ◽  
Liquid Phase ◽  
Transfer Rate ◽  
High Selectivity ◽  
Mass Transfer Rate ◽  
Catalyst Support ◽  
Liquid Phase Hydrogenation

Granulated Pt/carbon nanotubes (CNTs) were found to have a much better catalytic activity in the liquid phase hydrogenation of nitrobenzene than Pt/activated carbon (AC). The granulated CNTs had much larger pores than the AC particles, which gave a faster mass transfer rate of H2 that helped produce aniline with high selectivity.

scholarly journals Role of CO2 During Oxidative Dehydrogenation of Propane Over Bulk and Activated-Carbon Supported Cerium and Vanadium Based Catalysts

2021 ◽  
Author(s):  
Petar Djinović ◽  
Janez Zavašnik ◽  
Janvit Teržan ◽  
Ivan Jerman
Keyword(s):  
Catalytic Activity ◽  
Activated Carbon ◽  
Oxidative Dehydrogenation ◽  
Active Phase ◽  
Lattice Oxygen ◽  
Chemisorbed Oxygen ◽  
Catalytically Active ◽  
Temperature Programmed ◽  
Propane Cracking

AbstractCeO2, V2O5 and CeVO4 were synthesised as bulk oxides, or deposited over activated carbon, characterized by XRD, HRTEM, CO2-TPO, C3H8-TPR, DRIFTS and Raman techniques and tested in propane oxidative dehydrogenation using CO2. Complete oxidation of propane to CO and CO2 is favoured by lattice oxygen of CeO2. The temperature programmed experiments show the ~ 4 nm AC supported CeO2 crystallites become more susceptible to reduction by propane, but less prone to re-oxidation with CO2 compared to bulk CeO2. Catalytic activity of CeVO4/AC catalysts requires a 1–2 nm amorphous CeVO4 layer. During reaction, the amorphous CeVO4 layer crystallises and several atomic layers of carbon cover the CeVO4 surface, resulting in deactivation. During reaction, V2O5 is irreversibly reduced to V2O3. The lattice oxygen in bulk V2O5 favours catalytic activity and propene selectivity. Bulk V2O3 promotes only propane cracking with no propene selectivity. In VOx/AC materials, vanadium carbide is the catalytically active phase. Propane dehydrogenation over VC proceeds via chemisorbed oxygen species originating from the dissociated CO2. Graphic Abstract

Equilibrium and Dynamic Adsorption of Bioethanol on Activated Carbon in the Liquid Phase

2019 ◽  
Vol 42 (2) ◽  
pp. 343-354 ◽  
Author(s):  
Meysam Hajilari ◽  
Ahmad Shariati ◽  
Mohammadreza Khosravi-Nikou
Keyword(s):  
Activated Carbon ◽  
Liquid Phase ◽  
Dynamic Adsorption

Liquid-Phase Hydrogenation to 2, 4-Tolylenediamine over Supported HY Catalysts

2012 ◽  
Vol 512-515 ◽  
pp. 2381-2385
Author(s):  
Xue Mei Zhang ◽  
Feng Xing Niu
Keyword(s):  
Catalytic Activity ◽  
Liquid Phase ◽  
Catalytic Hydrogenation ◽  
Active Component ◽  
Experimental Results ◽  
Mass Ratio ◽  
Liquid Phase Hydrogenation ◽  
Catalytic Test

We have successfully prepared a novel passivation Ni/HY catalyst by the technologies of macerate-precipitatio.The catalysts are comprised of two contents: HY as carrier, Ni as active component，and we put it into the process of preparating aromatic amines.The nature of the catalysts was discussed based on the characterization results of BET , IR , SEM , XRD , TEM ,TPD , XPS and TPR . The catalytic hydrogenation technology for 2,4-dinitrobenzene in liquid phase can be an attractive and elegant routine for production of 2,4-tolylenediamine. The catalytic activity is evaluated at 2.2 MPa, 90 °C, 750r/min, solvent with reaction materials mass ratio of 60, catalyst with reaction materials mass ratio of 0.1. In the catalytic test, The experimental results over the catalyst showed that 2,4-dinitrobenzene and 2,4-tolylenediamine conversion and selective of 99.88% and 99.16% were obtained respectively.It is found that the catalyst is highly dispersion, stable, and reusable. No obvious deactivation of the catalyst was observed after repeated using twelve times.

Nitrogen-doped carbon sheets derived from chitin as non-metal bifunctional electrocatalysts for oxygen reduction and evolution

RSC Advances ◽  
2015 ◽  
Vol 5 (69) ◽  
pp. 56121-56129 ◽  
Author(s):  
Haoran Yuan ◽  
Lifang Deng ◽  
Xixi Cai ◽  
Shungui Zhou ◽  
Yong Chen ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Activated Carbon ◽  
Oxygen Reduction ◽  
High Catalytic Activity ◽  
Nitrogen Doped ◽  
Bifunctional Electrocatalysts ◽  
Nitrogen Doped Carbon

Nitrogen-doped activated carbon sheets were derived from chitin, which exhibited remarkable activity for ORR and high catalytic activity towards OER.

Macroscopic graphite felt containing palladium catalyst for liquid-phase hydrogenation of cinnamaldehyde

2019 ◽  
Vol 244 ◽  
pp. 128-139 ◽  
Author(s):  
Zhenxin Xu ◽  
Cuong Duong-Viet ◽  
Yuefeng Liu ◽  
Walid Baaziz ◽  
Bing Li ◽  
...  
Keyword(s):  
Liquid Phase ◽  
Palladium Catalyst ◽  
Graphite Felt ◽  
Liquid Phase Hydrogenation
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