scholarly journals Organophosphorus chemical warfare agent simulant DMMP promotes structural reinforcement of urea-based chiral supramolecular gels

RSC Advances ◽  
2015 ◽  
Vol 5 (16) ◽  
pp. 12287-12292 ◽  
Author(s):  
Francesca Piana ◽  
Marco Facciotti ◽  
Giuseppe Pileio ◽  
Jennifer R. Hiscock ◽  
Wim Van Rossom ◽  
...  
Keyword(s):  
Chemical Warfare Agent ◽  
Chemical Warfare ◽  
Gel Structure ◽  
Supramolecular Gel ◽  
Structural Reinforcement ◽  
Supramolecular Gels

The addition of a certain amount of organophosphorus chemical warfare agent simulant DMMP promotes strengthening of the urea-based supramolecular gel structure.

Photoresponsive supramolecular gels based on amphiphiles with azobenzene and maltose or polyethyleneglycol polar head

2015 ◽  
Vol 39 (5) ◽  
pp. 4009-4019 ◽  
Author(s):  
María José Clemente ◽  
Rosa María Tejedor ◽  
Pilar Romero ◽  
Juliette Fitremann ◽  
Luis Oriol
Keyword(s):  
External Stimulus ◽  
Gel Structure ◽  
Supramolecular Gel ◽  
Polar Head ◽  
Supramolecular Gels ◽  
Reversible Gel

Photoresponsive supramolecular gelators have been synthesized using PEG or d-maltose as polar head. Incorporation of azobenzene photoresponsive moieties allows controlling the supramolecular gel structure, including a reversible gel–sol transition using light as external stimulus.

scholarly journals Supramolecular gels for the remediation of reactive organophosphorus compounds

RSC Advances ◽  
2014 ◽  
Vol 4 (85) ◽  
pp. 45517-45521 ◽  
Author(s):  
Jennifer R. Hiscock ◽  
Isabelle L. Kirby ◽  
Julie Herniman ◽  
G. John Langley ◽  
Alistair J. Clark ◽  
...  
Keyword(s):  
Organophosphorus Compounds ◽  
Chemical Warfare Agent ◽  
Chemical Warfare ◽  
Supramolecular Gels

Pyridine-based gels formed with a cyclohexyl diamide gelator have been shown to undergo a gel–sol transition upon addition of the organophosphorus (OP) chemical warfare agent (CWA) simulant diethyl chlorophosphate (DCP).

Heat Exchange During Encapsulation in a Chemical Warfare Agent Protective Patient Wrap in Four Hot Environments

1987 ◽  
Author(s):  
Lou A. Stephenson ◽  
Margaret A. Kolka ◽  
Anne E. Allan ◽  
William R. Santee
Keyword(s):  
Heat Exchange ◽  
Chemical Warfare Agent ◽  
Chemical Warfare ◽  
Hot Environments

Evaluation of Silver-Exchanged Zeolites Under Development by University of Maine for Chemical Warfare Agent Decontamination Applications

2007 ◽  
Author(s):  
Mark D. Brickhouse ◽  
Teri A. Lalain ◽  
Terrence G. D'Onofrio ◽  
Lawrence R. Procell ◽  
Zachary B. Zander
Keyword(s):  
Chemical Warfare Agent ◽  
Chemical Warfare

Optimization of quantum-dot light source and detection of the simulants of chemical warfare agent

2021 ◽  
Vol 114 ◽  
pp. 110935
Author(s):  
Suhui Wang ◽  
Xu Zhang ◽  
Genwei Zhang ◽  
Tengxiao Guo ◽  
Xuequan Ding
Keyword(s):  
Quantum Dot ◽  
Light Source ◽  
Chemical Warfare Agent ◽  
Chemical Warfare

scholarly journals Acid is a potential interferent in fluorescent sensing of chemical warfare agent vapors

2021 ◽  
Vol 4 (1) ◽  
Author(s):  
Shengqiang Fan ◽  
Genevieve H. Dennison ◽  
Nicholas FitzGerald ◽  
Paul L. Burn ◽  
Ian R. Gentle ◽  
...  
Keyword(s):  
Chemical Warfare Agents ◽  
Chemical Warfare Agent ◽  
Chemical Warfare ◽  
Standard Laboratory ◽  
Care Needs ◽  
Fluorescent Sensing ◽  
Sensing Systems ◽  
Sensing Material ◽  
Fluorescence Change ◽  
Warfare Agents

AbstractA common feature of fluorescent sensing materials for detecting chemical warfare agents (CWAs) and simulants is the presence of nitrogen-based groups designed to nucleophilically displace a phosphorus atom substituent, with the reaction causing a measurable fluorescence change. However, such groups are also basic and so sensitive to acid. In this study we show it is critical to disentangle the response of a candidate sensing material to acid and CWA simulant. We report that pyridyl-containing sensing materials designed to react with a CWA gave a strong and rapid increase in fluorescence when exposed to Sarin, which is known to contain hydrofluoric acid. However, when tested against acid-free diethylchlorophosphate and di-iso-propylfluorophosphate, simulants typically used for evaluating novel G-series CWA sensors, there was no change in the fluorescence. In contrast, simulants that had been stored or tested under a standard laboratory conditions all led to strong changes in fluorescence, due to acid impurities. Thus the results provide strong evidence that care needs to be taken when interpreting the results of fluorescence-based solid-state sensing studies of G-series CWAs and their simulants. There are also implications for the application of these pyridyl-based fluorescence and other nucleophilic/basic sensing systems to real-world CWA detection.

scholarly journals Modified-TiO2 Photocatalyst Supported on β-SiC Foams for the Elimination of Gaseous Diethyl Sulfide as an Analog for Chemical Warfare Agent: Towards the Development of a Photoreactor Prototype

Catalysts ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 403
Author(s):  
Armelle Sengele ◽  
Didier Robert ◽  
Nicolas Keller ◽  
Valérie Keller
Keyword(s):  
Photocatalytic Oxidation ◽  
Chemical Warfare Agents ◽  
Chemical Warfare Agent ◽  
Chemical Warfare ◽  
Diethyl Sulfide ◽  
Tio2 Photocatalysts ◽  
Doped Tio2 ◽  
Model Molecule ◽  
Warfare Agents ◽  
Oxidation Efficiency

In the context of the increase in chemical threat due to warfare agents, the development of efficient methods for destruction of Chemical Warfare Agents (CWAs) are of first importance both for civilian and military purposes. Amongst possible methods for destruction of CWAs, photocatalytic oxidation is an alternative one. The present paper reports on the preparation of Ta and Sn doped TiO2 photocatalysts immobilized on β-SiC foams for the elimination of diethyl sulfide (DES) used as a model molecule mimicking Yperite (Mustard Gas) in gaseous phase. Photo-oxidation efficiency of doped TiO2 catalyst has been compared with TiO2-P25. Here, we demonstrate that the Sn doped-TiO2 with a Polyethylene glycol (PEG)/TiO2 ratio of 7 exhibits the best initial activity (up to 90%) but is deactivates more quickly than Ta doped-TiO2 (40% after 800 min). The activity of the catalysts is strongly influenced by the adsorption properties of the support, as β-SiC foams adsorb DES and other sulfur compounds. This adsorption makes it possible to limit the poisoning of the catalysts and to maintain an acceptable conversion rate even after ten hours under continuous DES flow. Washing with NaOH completely regenerates the catalyst after a firs treatment and even seems to “wash” it by removing impurities initially present on the foams.

Sign in / Sign up

Export Citation Format

Share Document