Investigation into the reactivity of 16-electron complexes Cp#Co(S2C2B10H10) (Cp# = Cp, Cp*) towards methyl diazoacetate and toluenesulphonyl azide

RSC Advances ◽  
2014 ◽  
Vol 4 (106) ◽  
pp. 61799-61808 ◽  
Author(s):  
Wei Zhong ◽  
Mingshi Xie ◽  
Yizhi Li ◽  
Hong Yan
Keyword(s):  
Sandwich Complex ◽  
Methyl Diazoacetate ◽  
Three Component Reaction ◽  
Two Component ◽  
Half Sandwich ◽  
Formation Of Complexes

A three-component reaction of the 16-electron half-sandwich complex Cp*Co(S2C2B10H10) (2) with both methyl diazoacetate (MDA) and toluenesulphonyl azide (TsN3) led to the formation of complexes 3 and 4, while a two-component reaction of complex 2 with MDA afforded products 5–7.

scholarly journals Uranium(iv) cyclobutadienyl sandwich compounds: synthesis, structure and chemical bonding

2020 ◽  
Vol 56 (6) ◽  
pp. 944-947 ◽  
Author(s):  
Nikolaos Tsoureas ◽  
Akseli Mansikkamäki ◽  
Richard A. Layfield
Keyword(s):  
Chemical Bonding ◽  
Molecular Structures ◽  
Sandwich Complexes ◽  
Sandwich Complex ◽  
Sandwich Compounds ◽  
Bonding Properties ◽  
Half Sandwich

The synthesis, molecular structures and bonding properties of two uranium(iv) cyclobutadienyl half-sandwich complexes and a doubly activated cyclobutadienyl sandwich complex are described.

[(C9H7)YbI(DME)2], the First Indenyl Half-Sandwich Complex of Divalent Ytterbium

2001 ◽  
Vol 2001 (12) ◽  
pp. 3055-3058 ◽  
Author(s):  
Alexander A. Trifonov ◽  
Eugenii N. Kirillov ◽  
Sebastian Dechert ◽  
Herbert Schumann ◽  
Mikhail N. Bochkarev
Keyword(s):  
Sandwich Complex ◽  
Half Sandwich

Electronic structure of a beryllium half-sandwich complex, Be(η5 -C5 H5 )

2012 ◽  
Vol 112 (18) ◽  
pp. 2981-2985
Author(s):  
Olga Dolgounitcheva ◽  
V. G. Zakrzewski ◽  
J. V. Ortiz
Keyword(s):  
Electronic Structure ◽  
Sandwich Complex ◽  
Half Sandwich

Synthese und Molekülstruktur der dreikernigen Cluster-Verbindung (η5C5Me5)IrFe2(CO)9 / Synthesis and Molecular Structure of the Trinuclear Cluster Compound (η5-C5Me5)IrFe2(CO)9

1981 ◽  
Vol 36 (9) ◽  
pp. 1053-1059 ◽  
Author(s):  
Ernst Guggolz ◽  
Manfred L. Ziegler ◽  
Willibald Kalcher ◽  
Johann Plank ◽  
Doris Riedel ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Cluster Compound ◽  
The Novel ◽  
X Ray Diffraction ◽  
Sandwich Complex ◽  
X Ray ◽  
Trinuclear Cluster ◽  
Half Sandwich

Abstract Reaction of triirondodecacarbonyl (1) with the dinuclear chloroiridium complex [(η5 -C5Me5)Ir(μ-Cl)Cl]2 (2) in benzene at 50 °C yields the novel mixed iron iridium cluster of composition (η5 -C5Me5)IrFe2(CO)9 (8) the molecular structure of which has been established by X-ray diffraction methods. The mononuclear half-sandwich complex (η5 -C5Me5)Ir(CO)2 (4) present in the reaction mixture was found to represent the immediate precursor of the cluster compound 8.

Reactivity of the 16e (p-cymene)Ru half-sandwich complex containing a chelating 1,2-dicarba-closo-dodecaborane-1,2-dithiolate ligand towards diynes

2011 ◽  
Vol 40 (26) ◽  
pp. 6992 ◽  
Author(s):  
Zhi-Wei Xu ◽  
Lei Han ◽  
Cheng Ji ◽  
Rui Zhang ◽  
Xu-Jie Shen ◽  
...  
Keyword(s):  
Sandwich Complex ◽  
Half Sandwich
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