Assembly of gold nanoparticles on graphene film via electroless deposition: spontaneous reduction of Au3+ ions by graphene film

RSC Advances ◽  
2015 ◽  
Vol 5 (7) ◽  
pp. 4964-4971 ◽  
Author(s):  
M. Amal Raj ◽  
S. Abraham John
Keyword(s):  
Gold Nanoparticles ◽  
Graphene Oxide ◽  
Oxide Film ◽  
Reduced Graphene Oxide ◽  
Electroless Deposition ◽  
Graphene Film ◽  
Spontaneous Reduction ◽  
Reduced Graphene ◽  
Electrochemically Reduced Graphene Oxide

Electrochemically reduced graphene oxide film catalyzed electroless deposition of gold nanoparticles.

scholarly journals Simultaneous Detection of Dihydroxybenzene Isomers Using Electrochemically Reduced Graphene Oxide-Carboxylated Carbon Nanotubes/Gold Nanoparticles Nanocomposite

Biosensors ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 321
Author(s):  
Angélica Domínguez-Aragón ◽  
Rocio B. Dominguez ◽  
Erasto Armando Zaragoza-Contreras
Keyword(s):  
Carbon Nanotubes ◽  
Gold Nanoparticles ◽  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Tap Water ◽  
Simultaneous Detection ◽  
3D Network ◽  
Reduced Graphene ◽  
Electrochemically Reduced Graphene Oxide ◽  
Carboxylated Carbon Nanotubes

An electrochemical sensor based on electrochemically reduced graphene oxide (ErGO), carboxylated carbon nanotubes (cMWCNT), and gold nanoparticles (AuNPs) (GCE/ErGO-cMWCNT/AuNPs) was developed for the simultaneous detection of dihidroxybenzen isomers (DHB) hydroquinone (HQ), catechol (CC), and resorcinol (RS) using differential pulse voltammetry (DPV). The fabrication and optimization of the system were evaluated with Raman Spectroscopy, SEM, cyclic voltammetry, and DPV. Under optimized conditions, the GCE/ErGO-cMWCNT/AuNPs sensor exhibited a linear concentration range of 1.2–170 μM for HQ and CC, and 2.4–400 μM for RS with a detection limit of 0.39 μM, 0.54 μM, and 0.61 μM, respectively. When evaluated in tap water and skin-lightening cream, DHB multianalyte detection showed an average recovery rate of 107.11% and 102.56%, respectively. The performance was attributed to the synergistic effects of the 3D network formed by the strong π–π stacking interaction between ErGO and cMWCNT, combined with the active catalytic sites of AuNPs. Additionally, the cMWCNT provided improved electrocatalytic properties associated with the carboxyl groups that facilitate the adsorption of the DHB and the greater amount of active edge planes. The proposed GCE/ErGO-cMWCNT/AuNPs sensor showed a great potential for the simultaneous, precise, and easy-to-handle detection of DHB in complex samples with high sensitivity.

scholarly journals Amperometric L-Lactate Biosensor Based upon a Gold Nanoparticles/Reduced Graphene Oxide/Polyallylamine Hydrochloride Modified Screen-Printed Graphite Electrode

Chemosensors ◽  
2021 ◽  
Vol 9 (4) ◽  
pp. 74
Author(s):  
Oana-Maria Istrate ◽  
Lucian Rotariu ◽  
Camelia Bala
Keyword(s):  
Gold Nanoparticles ◽  
Graphene Oxide ◽  
Lactic Acid ◽  
Reduced Graphene Oxide ◽  
Long Term Stability ◽  
Reduced Graphene ◽  
Electrochemically Reduced Graphene Oxide ◽  
Dehydrogenase Enzyme ◽  
Polyallylamine Hydrochloride ◽  
Screen Printed

This work describes a novel L-lactate biosensor based on the immobilization of L-lactate dehydrogenase enzyme on the screen-printed electrode modified with a ternary composite based on gold nanoparticles, electrochemically-reduced graphene oxide, and poly (allylamine hydrochloride). The enzyme was stabilized by crosslinking with glutaraldehyde. Applied working potential, pH and NAD+ concentration were optimized. The biosensor reports a specific sensitivity of 1.08 µA/mM·cm2 in a range up to 3 mM L-lactic acid with a detection limit of 1 µM. The operational and long-term stability as well as good selectivity allowed the L-lactic acid measurement in dairy products and wine samples.

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