Polymer impregnated sulfonated carbon composite solid acid catalyst for alkylation of phenol with methyl-tert-butyl ether

RSC Advances ◽  
2015 ◽  
Vol 5 (5) ◽  
pp. 3286-3290 ◽  
Author(s):  
Praveen K. Khatri ◽  
Manvi Manchanda ◽  
Indrajit K. Ghosh ◽  
Suman L. Jain
Keyword(s):  
Composite Material ◽  
Alkylating Agent ◽  
Solid Acid ◽  
Solid Acid Catalyst ◽  
Acid Catalyst ◽  
Carbon Composite ◽  
Methyl Tert Butyl Ether ◽  
Butyl Ether ◽  
Autogenous Pressure ◽  
Composite Solid

A polymer impregnated sulfonated carbon composite solid acid catalyst was synthesized via sulfonation of a composite material and used for the alkylation of phenol using methyl-tert-butyl ether as an alkylating agent in a pressure reactor under autogenous pressure.

A Novel Sulfonated Carbon Composite Solid Acid Catalyst for Biodiesel Synthesis

2008 ◽  
Vol 123 (1-2) ◽  
pp. 1-6 ◽  
Author(s):  
Xunhua Mo ◽  
Edgar Lotero ◽  
Changqing Lu ◽  
Yijun Liu ◽  
James G. Goodwin
Keyword(s):  
Solid Acid ◽  
Solid Acid Catalyst ◽  
Acid Catalyst ◽  
Carbon Composite ◽  
Biodiesel Synthesis ◽  
Composite Solid

Sulfonated polymer impregnated carbon composite as a solid acid catalyst for the selective synthesis of furfural from xylose

2015 ◽  
Vol 56 (10) ◽  
pp. 1203-1206 ◽  
Author(s):  
Praveen K. Khatri ◽  
Neha Karanwal ◽  
Savita Kaul ◽  
Suman L. Jain
Keyword(s):  
Solid Acid ◽  
Solid Acid Catalyst ◽  
Acid Catalyst ◽  
Carbon Composite ◽  
Selective Synthesis

scholarly journals Sulfonated Mesoporous Silica-Carbon Composite Derived from a Silicate-Polyethylene Glycol Gel and Its Application as Solid Acid Catalysts

2021 ◽  
Vol 17 (1) ◽  
pp. 13-21
Author(s):  
Shofiyya Julaika ◽  
Agus Farid Fadli ◽  
Widiyastuti Widiyastuti ◽  
Heru Setyawan
Keyword(s):  
Acetic Acid ◽  
Polyethylene Glycol ◽  
Mesoporous Silica ◽  
Surface Area ◽  
Sodium Silicate ◽  
Solid Acid ◽  
Solid Acid Catalyst ◽  
Acid Catalyst ◽  
Carbon Composite ◽  
Esterification Reaction

Solid acid catalyst is a promising alternative to the counterpart homogeneous acid for esterification reaction from the viewpoint of reusability and environmental concerns. This work aims to develop sulfonated mesoporous silica-carbon composite as solid acid catalyst for the esterification. The catalyst was synthesized from sodium silicate as the silica precursor and polyethylene glycol (PEG) as both carbon precursor and template via a sol-gel route in an aqueous system. Then, it was carbonized to produce mesoporous silica-carbon composite. Using the proposed method, the surface area of the silica-carbon composite could reach as high as 1074.21 m2/g. Although the surface area decreased to 614.02 m²/g when it was functionalized with sulfonate groups, the composite had a high ionic capacity of 5.3 mEq/g and exhibited high catalytic activity for esterification reaction of acetic acid with ethanol. At a reaction temperature of 80 °C, the acetic acid conversion reached 76.55% in 4 h. In addition, the catalyst had good reusability, which can be comparable with the commercial catalyst Foltrol F-007. It appears that the sulfonated silica-carbon composite prepared from sodium silicate using PEG as the carbon source a promising candidate as catalyst for esterification and the related area. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 

scholarly journals Development of TiO2-Carbon Composite Acid Catalyst for Dehydration of Fructose to 5-Hydroxymethylfurfural

Catalysts ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 126 ◽  
Author(s):  
Morongwa Songo ◽  
Richard Moutloali ◽  
Suprakas Ray
Keyword(s):  
Solid Acid ◽  
Solid Acid Catalyst ◽  
Acid Catalyst ◽  
Direct Conversion ◽  
Carbon Composite ◽  
Industrial Applications ◽  
Optimum Conditions ◽  
X Ray Diffraction ◽  
Catalytic Cycles ◽  
Microwave Assisted Method

A TiO2-Carbon (TiO2C) composite was prepared using the microwave-assisted method and sulfonated using fuming sulfuric acid to produce a TiO2C solid acid catalyst. The prepared solid acid catalyst was characterised using scanning electron microscopy, Brunauer-Emmett-Teller analysis, Fourier transform infrared spectroscopy, and X-ray diffraction. Crystallinity analysis confirmed that TiO2C has an anatase structure, while analysis of its morphology showed a combination of spheres and particles with a diameter of 50 nm. The TiO2C solid acid catalyst was tested for use in the catalytic dehydration of fructose to 5-hydroxymethylfurfural (5-HMF). The effect of reaction time, reaction temperature, catalyst dosage, and solvent were investigated against the 5-HMF yield. The 5-HMF yield was found to be 90% under optimum conditions. The solid acid catalyst is very stable and can be reused for four catalytic cycles. Hence, the material has great potential for use in industrial applications and can be used for the direct conversion of fructose to 5-HMF because of its high activity and high reusability.

Synthesis and Characterization of Heterogeneous Solid Acid Catalyst from Alstonia Scolaris Stalks for Biodiesel Production using Waste Cooking Oil

2020 ◽  
Vol 10 ◽  
Author(s):  
Charishma Venkata Sai Anne ◽  
Karthikeyan S. ◽  
Arun C.
Keyword(s):  
Reaction Time ◽  
Solid Acid ◽  
Solid Acid Catalyst ◽  
Acid Catalyst ◽  
Waste Cooking Oil ◽  
Biodiesel Production ◽  
Wood Biomass ◽  
Waste Wood ◽  
X Ray ◽  
Cooking Oil

Background: Waste biomass derived reusable heterogeneous acid based catalysts are more suitable to overcome the problems associated with homogeneous catalysts. The use of agricultural biomass as catalyst for transesterification process is more economical and it reduces the overall production cost of biodiesel. The identification of an appropriate suitable catalyst for effective transesterification will be a landmark in biofuel sector Objective: In the present investigation, waste wood biomass was used to prepare a low cost sulfonated solid acid catalyst for the production of biodiesel using waste cooking oil. Methods: The pretreated wood biomass was first calcined then sulfonated with H2SO4. The catalyst was characterized by various analyses such as, Fourier-transform infrared spectroscopy (FTIR), Scanning Electron Microscopy (SEM), Energy Dispersive X-Ray Spectroscopy (EDS) and X-ray diffraction (XRD). The central composite design (CCD) based response surface methodology (RSM) was applied to study the influence of individual process variables such as temperature, catalyst load, methanol to oil molar ration and reaction time on biodiesel yield. Results: The obtained optimized conditions are as follows: temperature (165 ˚C), catalyst loading (1.625 wt%), methanol to oil molar ratio (15:1) and reaction time (143 min) with a maximum biodiesel yield of 95 %. The Gas chromatographymass spectrometry (GC-MS) analysis of biodiesel produced from waste cooking oil was showed that it has a mixture of both monounsaturated and saturated methyl esters. Conclusion: Thus the waste wood biomass derived heterogeneous catalyst for the transesterification process of waste cooking oil can be applied for sustainable biodiesel production by adding an additional value for the waste materials and also eliminating the disposable problem of waste oils.

scholarly journals Production of cellulose nanofibrils and films from elephant grass using deep eutectic solvents and a solid acid catalyst

RSC Advances ◽  
2021 ◽  
Vol 11 (23) ◽  
pp. 14071-14078
Author(s):  
Xi-Que Wu ◽  
Pan-Dao Liu ◽  
Qun Liu ◽  
Shu-Ying Xu ◽  
Yu-Cang Zhang ◽  
...  
Keyword(s):  
Solid Acid ◽  
Solid Acid Catalyst ◽  
Cellulose Nanofibrils ◽  
Acid Catalyst ◽  
Deep Eutectic Solvents ◽  
Elephant Grass ◽  
Film Forming ◽  
New Strategy

A new strategy was developed to produce cellulose nanofibrils and films from elephant grass using deep eutectic solvents and a recyclable solid acid catalyst with assistance of ultrasonic disintegration and a suction filtration film forming method.

scholarly journals ZnAlMCM-41; a very ecofriendly and reusable solid acid catalyst for highly selective synthesis of 1, 3-dioxanes by Prins cyclization of olefins

2021 ◽  
Author(s):  
Manickam Selvaraj ◽  
Mohammed A. Assiri ◽  
Hari Singh ◽  
Jimmy Nelson Appaturi ◽  
Subrahmanyam Ch ◽  
...  
Keyword(s):  
Liquid Phase ◽  
Solid Acid ◽  
Solid Acid Catalyst ◽  
Acid Catalyst ◽  
Selective Synthesis ◽  
Comparison Study ◽  
Catalytic Method ◽  
Prins Cyclization ◽  
Heterogeneous Catalytic

Prins cyclization of styrene (SE) with paraformaldehyde (PFCHO) was conducted with mesoporous ZnAlMCM-41 catalysts for synthesis of 4-phenyl-1,3-dioxane (4-PDO) under a liquid phase heterogeneous catalytic method. For comparison study, the...

scholarly journals Concatenated Batch and Continuous Flow Procedures for the Upgrading of Glycerol-Derived Aminodiols via N-Acetylation and Acetalization Reactions

Catalysts ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 21
Author(s):  
Davide Rigo ◽  
Nadia Alessandra Carmo Dos Santos ◽  
Alvise Perosa ◽  
Maurizio Selva
Keyword(s):  
Continuous Flow ◽  
Solid Acid ◽  
Solid Acid Catalyst ◽  
Acid Catalyst ◽  
Catalyst Free ◽  
Amide Derivatives ◽  
Amide Acetal ◽  
Enol Ester ◽  
Isopropenyl Acetate

An unprecedented two-step sequence was designed by combining batch and continuous flow (CF) protocols for the upgrading of two aminodiol regioisomers derived from glycerol, i.e., 3-amino-1,2-propanediol and 2-amino-1,3-propanediol (serinol). Under batch conditions, at 80–90 °C, both substrates were quantitatively converted into the corresponding amides through a catalyst-free N-acetylation reaction mediated by an innocuous enol ester as isopropenyl acetate (iPAc). Thereafter, at 30–100 °C and 1–10 atm, the amide derivatives underwent a selective CF-acetalisation in the presence of acetone and a solid acid catalyst, to afford the double-functionalized (amide-acetal) products.

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