Porous solid acid with high Surface area derived from emulsion templating and hypercrosslinking for efficient one-pot conversion of cellulose to 5-hydroxymethylfurfural

RSC Advances ◽  
2014 ◽  
Vol 4 (103) ◽  
pp. 59175-59184 ◽  
Author(s):  
Jianming Pan ◽  
Heping Gao ◽  
Yunlei Zhang ◽  
Jun Zeng ◽  
Weidong Shi ◽  
...  
Keyword(s):  
Surface Area ◽  
Solid Acid ◽  
High Surface ◽  
High Surface Area ◽  
Porous Solid ◽  
One Pot ◽  
Emulsion Templating

This work addressed efficient one-pot conversion of cellulose to 5-hydroxymethylfurfural by porous solid acid in the presence of [Emim]Cl.

scholarly journals Dopamine Assisted One-Step Pyrolysis of Glucose for the Preparation of Porous Carbon with A High Surface Area

Nanomaterials ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 854 ◽  
Author(s):  
Hanbo Xiao ◽  
Cheng-an Tao ◽  
Yujiao Li ◽  
Xianzhe Chen ◽  
Jian Huang ◽  
...  
Keyword(s):  
Surface Area ◽  
Porous Carbon ◽  
Carbon Materials ◽  
High Current Density ◽  
High Surface ◽  
High Surface Area ◽  
Energy Storage Materials ◽  
One Pot ◽  
Component Structure ◽  
Porous Carbon Materials

Herein, a facile dopamine assisted one-pot synthesis approach is proposed for the preparation of porous carbon with a specific surface area (SSA) up to 2593 m2/g through the direct pyrolysis of a mixture of glucose, NH4Cl, and dopamine hydrochloride (DAH). The glucose is adopted as the carbon source and foaming agent, NH4Cl is used as the blowing agent, and DAH is served as collaborative carbon precursor as well as the nitrogen source for the first time. The effect of dopamine on the component, structure, and SSA of the as-prepared porous carbon materials are systematically studied. The moderate addition of dopamine, which influences the condensation and polymerization of glucose, matches better with ammonium salt decomposition. The SSA of porous carbon increases first and then decreases with the increasing amount of dopamine. In our case, the porous carbon produced with 5 wt% dopamine (PC-5) achieves the maximum SSA of up to 2593 m2/g. Accordingly, it also shows the greatest electrochemical performance. The PC-5 shows a capacitance of 96.7 F/g calculated from the discharge curve at 1 A/g. It also has a good capacitive rate capacity, the specific capacitance can still maintain 80%, even at a high current density of 10 A/g. Moreover, PC-5 exhibits a good cycling stability of 98.1% capacitive retention after 1000 cycles. The proposed method may show promising prospects for preparing porous carbon materials as advanced energy storage materials, storage, and catalyst supports.

scholarly journals Impact of Thermal Treatment of Nb2O5 on Its Performance in Glucose Dehydration to 5-Hydroxymethylfurfural in Water

Nanomaterials ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1685
Author(s):  
Katarzyna Morawa Eblagon ◽  
Anna Malaika ◽  
Karolina Ptaszynska ◽  
Manuel Fernando R. Pereira ◽  
José Luís Figueiredo
Keyword(s):  
Thermal Treatment ◽  
Surface Area ◽  
Pure Water ◽  
High Surface ◽  
High Surface Area ◽  
Acid Sites ◽  
High Ratio ◽  
Total Acidity ◽  
One Pot ◽  
Niobic Acid

The cascade dehydration of glucose to 5-hydroxymethylfurfural (HMF) was carried out in water over a series of Nb2O5 catalysts, which were derived from the thermal treatment of niobic acid at 300 and 550 °C, under air or inert atmosphere. Amorphous niobic acid showed high surface area (366 m2/g) and large acidity (2.35 mmol/g). With increasing the temperature of the thermal treatment up to 550 °C, the amorphous Nb2O5 was gradually transformed into a pseudohexagonal phase, resulting in a decrease in surface area (27–39 m2/g) and total acidity (0.05–0.19 mmol/g). The catalysts’ performance in cascade dehydration of glucose realized in pure water was strongly influenced by the total acidity of these materials. A remarkable yield of 37% HMF in one-pot reaction in water was achieved using mesoporous amorphous niobium oxide prepared by thermal treatment of niobic acid at 300 °C in air. The best-performing catalyst displayed a total acidity lower than niobic acid (1.69 mmol/g) which afforded a correct balance between a high glucose conversion and limited further conversion of the target product to numerous polymers and humins. On the other hand, the treatment of niobic acid at 550 °C, independently of the atmosphere used during the sample preparation (i.e., air or N2), resulted in Nb2O5 catalysts with a high ratio of Lewis to Brønsted acid sites and poor total acidity. These materials excelled at catalyzing the isomerization step in the tandem process.

Zirconium Phosphate with a High Surface Area as a Water-Tolerant Solid Acid

2004 ◽  
Vol 94 (1/2) ◽  
pp. 45-47 ◽  
Author(s):  
Yuichi Kamiya ◽  
Shoko Sakata ◽  
Yusuke Yoshinaga ◽  
Ryuichiro Ohnishi ◽  
Toshio Okuhara
Keyword(s):  
Surface Area ◽  
Zirconium Phosphate ◽  
Solid Acid ◽  
High Surface ◽  
High Surface Area

One-pot aerobic oxidative sulfonamidation of aromatic thiols with ammonia by a dual-functional β-MnO2 nanocatalyst

2020 ◽  
Vol 56 (14) ◽  
pp. 2095-2098 ◽  
Author(s):  
Eri Hayashi ◽  
Yui Yamaguchi ◽  
Yusuke Kita ◽  
Keigo Kamata ◽  
Michikazu Hara
Keyword(s):  
High Activity ◽  
Surface Area ◽  
High Surface ◽  
High Surface Area ◽  
One Pot ◽  
Dual Functional ◽  
Aromatic Thiols ◽  
The One

High-surface-area β-MnO2 nanoparticles exhibited high activity for the one-pot oxidative sulfonamidation of thiols to sulfonamides using O2 and NH3.

One-Pot Procedure to Synthesize High Surface Area Alumina Nanofibers Using Supercritical Carbon Dioxide

Langmuir ◽  
2010 ◽  
Vol 26 (4) ◽  
pp. 2707-2713 ◽  
Author(s):  
Muhammad B. I. Chowdhury ◽  
Rouhong Sui ◽  
Rahima A. Lucky ◽  
Paul A. Charpentier
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Surface Area ◽  
High Surface ◽  
High Surface Area ◽  
One Pot ◽  
Alumina Nanofibers ◽  
Supercritical Carbon

scholarly journals The Geode Process I: Hollow Silica Microcapsules as a High Surface Area Substrate for Semiconductor Nanowire Growth

2019 ◽  
Author(s):  
Maritza Mujica ◽  
Gozde Tutuncuoglu ◽  
Amar Mohabir ◽  
Victor Breedveld ◽  
Sven Behrens ◽  
...  
Keyword(s):  
Surface Area ◽  
High Surface ◽  
High Surface Area ◽  
Silica Particles ◽  
Nanowire Growth ◽  
Si Nanowires ◽  
Hollow Silica ◽  
Semiconductor Nanowire ◽  
Interior Surface ◽  
Emulsion Templating

<div><div><div><p>We introduce and demonstrate critical steps toward the Geode process for the bottom-up synthesis of semiconductor nanowires. Central to the process is the design and fabrication of an unconventional, high surface area substrate: the interior surface of hollow silica microcapsules, assembled from silica particles via emulsion templating, and featuring porous walls to enable efficient gas transport. The interior surface of these hollow silica microcapsules is decorated with gold nanoparticles that seed nanowire growth via the vapor-liquid-solid (VLS) mechanism. We demonstrate the production of the necessary microcapsules and show how microcapsule structure and stability upon drying is influenced by the type of silica particles and use of a particle cross-linking agent. Finally, we demonstrate the synthesis of Si nanowires in the microcapsule interior.</p></div></div></div>

scholarly journals Mesoporous Crystalline Niobium Oxide with a High Surface Area: A Solid Acid Catalyst for Alkyne Hydration

2020 ◽  
Vol 12 (42) ◽  
pp. 47389-47396 ◽  
Author(s):  
Dinithi Rathnayake ◽  
Inosh Perera ◽  
Alireza Shirazi-Amin ◽  
Peter Kerns ◽  
Shanka Dissanayake ◽  
...  
Keyword(s):  
Surface Area ◽  
Niobium Oxide ◽  
Solid Acid ◽  
Solid Acid Catalyst ◽  
High Surface ◽  
High Surface Area ◽  
Acid Catalyst
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