Synthesis, characterization and photovoltaic properties of benzo[1,2-b:4,5-b′]dithiophene-bridged molecules

RSC Advances ◽  
2014 ◽  
Vol 4 (108) ◽  
pp. 63260-63267 ◽  
Author(s):  
Xinli Liu ◽  
Shusheng Li ◽  
Jinhua Li ◽  
Jian Wang ◽  
Zhan'ao Tan ◽  
...  

Four benzo[1,2-b:4,5-b′]dithiophene (BDT) centred small molecules with different acceptor and end-capping groups were synthesized as the donor materials for organic solar cells.

2015 ◽  
Vol 17 (14) ◽  
pp. 8894-8900 ◽  
Author(s):  
Dan Deng ◽  
Yajie Zhang ◽  
Lingyun Zhu ◽  
Jianqi Zhang ◽  
Kun Lu ◽  
...  

Three subtle structural changed end-capped acceptors with increased electron withdrawing ability were synthesized and introduced into a planar conjugated backbone. The relationship between molecules bearing the three end-capped acceptors and their photovoltaic properties was studied.


2019 ◽  
Vol 170 ◽  
pp. 107595 ◽  
Author(s):  
Min Li ◽  
Zuojia Li ◽  
Zhen Yang ◽  
Zuoji Liu ◽  
Kai Zhang ◽  
...  

2018 ◽  
Vol 6 (26) ◽  
pp. 12493-12505 ◽  
Author(s):  
Min Li ◽  
Zhongbin Qiu ◽  
Guangjun Zhang ◽  
Yu Liu ◽  
Lin Xiong ◽  
...  

Three novel narrow band gap small molecules (SMs) with D(A–Ar)2 molecular frameworks, based on fluorinated 2,2′-bithiophene (FBT) as an electron-donating (D) central core coupled with different electron-acceptor (A) bridge units, and 2-octylthiophene (Ar) units as end-capping units, were designed and synthesized for application as donor materials in solution-processed SM-OSCs. Under optimized conditions, a high PCE of 9.00% with a very high Jsc of 16.14 mA cm−2 and a FF of 73.52% for FBT(TDPP-T)2/PC71BM is obtained in single layer OSCs, which is among the highest reported for D(A–Ar)2-type SM based solar cells with a PCE up to 9% so far.


2017 ◽  
Vol 5 (19) ◽  
pp. 4742-4751 ◽  
Author(s):  
Susana Arrechea ◽  
Ana Aljarilla ◽  
Pilar de la Cruz ◽  
Manish Kumar Singh ◽  
Ganesh D. Sharma ◽  
...  

Using cyclopentadithiophene as bridge in A–D–A porphyrin-based small molecules, and PC71BM as acceptor in BHJ solar cells PCE of 7.93%, is achieved after SVA.


2016 ◽  
Vol 4 (6) ◽  
pp. 2252-2262 ◽  
Author(s):  
Jin-Liang Wang ◽  
Fei Xiao ◽  
Jun Yan ◽  
Kai-Kai Liu ◽  
Zheng-Feng Chang ◽  
...  

Here we report the synthesis of a pair of D1–A-bridge–D2-bridge–A–D1 type small molecules, which have different π-conjugated bridges and investigated the effects on their photovoltaic properties.


2014 ◽  
Vol 10 ◽  
pp. 2683-2695 ◽  
Author(s):  
Diego Cortizo-Lacalle ◽  
Calvyn T Howells ◽  
Upendra K Pandey ◽  
Joseph Cameron ◽  
Neil J Findlay ◽  
...  

Two novel triads based on a diketopyrrolopyrrole (DPP) central core and two 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) units attached by thiophene rings have been synthesised having high molar extinction coefficients. These triads were characterised and used as donor materials in small molecule, solution processable organic solar cells. Both triads were blended with PC71BM as an acceptor in different ratios by wt % and their photovoltaic properties were studied. For both the triads a modest photovoltaic performance was observed, having an efficiency of 0.65%. Moreover, in order to understand the ground and excited state properties and vertical absorption profile of DPP and BODIPY units within the triads, theoretical DFT and TDDFT calculations were performed.


2021 ◽  
Vol 1198 ◽  
pp. 113176
Author(s):  
Sadaf Bibi ◽  
Rasheed Ahmad Khera ◽  
Afifa Farhat ◽  
Javed Iqbal

Author(s):  
Venkatesh Piradi ◽  
Feng Yan ◽  
Xunjin Zhu ◽  
Wai-Yeung Raymond Wong

Organic solar cells (OSCs) have been considered as a promising cost-effective alternative to silicon-based solar cell counterparts due to their lightweight, mechanical flexibility, and easy fabrication features. Over the past...


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