K2TiO(C2O4)2-mediated synthesis of rutile TiO2 mesocrystals and their ability to assist photodegradation of sulfosalicylic acid in water

RSC Advances ◽  
2014 ◽  
Vol 4 (90) ◽  
pp. 49280-49286 ◽  
Author(s):  
Lu-Lu Lai ◽  
Li-Liang Huang ◽  
Jin-Ming Wu
Keyword(s):  
Photocatalytic Activity ◽  
Low Temperature ◽  
Specific Surface ◽  
Charge Separation ◽  
Atmospheric Pressure ◽  
High Photocatalytic Activity ◽  
Large Specific Surface Area ◽  
Sulfosalicylic Acid ◽  
Temperature Solution ◽  
Solution Route

Flower-like rutile TiO2 mesocrystals were synthesized by a K2TiO(C2O4)2-mediated low temperature solution route under the atmospheric pressure, which exhibited high photocatalytic activity because of the large specific surface area as well as the high charge separation rate inherent from the single crystal nature.

Enhanced Photocatalytic Activity of α-Fe2O3 Prepared with the Assistance of Ionic Liquid

2014 ◽  
Vol 685 ◽  
pp. 123-126
Author(s):  
Yan Lu
Keyword(s):  
Photocatalytic Activity ◽  
Specific Surface ◽  
Charge Separation ◽  
High Photocatalytic Activity ◽  
X Ray Diffraction ◽  
X Ray ◽  
Separation Rate ◽  
Surface Photovoltage Spectroscopy ◽  
Induced Charge ◽  
Underlying Mechanisms

In this paper, α-Fe2O3 photocatalyst with high photocatalytic activity (IL-α-Fe2O3) was fabricated via hydrothermal routine using 1-ethyl-3- methylimidazolium dihydrophosphate ([EMIm]H2PO4). The specific surface area, structure, the photo-induced charge separation rate were characterized by Brunauer-Emmett-Teller (BET) measurements, X-ray diffraction (XRD), and surface photovoltage spectroscopy (SPS), respectively. The results show that adding ([EMIm]H2PO4 into the synthetic system alters the specific surface parameters and photo-induced charge separation rate. The photocatalytic activity for decolorization of methyl orange (MO) solution was investigated. The results show that the photocatalytic activity of IL-α-Fe2O3 is more than 2.5 times that of the reference α-Fe2O3 and the underlying mechanisms are discussed.

Greatly enhanced photocatalytic activity by organic flexible piezoelectric PVDF induced spatial electric field

2017 ◽  
Vol 7 (23) ◽  
pp. 5594-5601 ◽  
Author(s):  
Baoying Dai ◽  
Hengming Huang ◽  
Wei Wang ◽  
Yukai Chen ◽  
Chunhua Lu ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Electric Field ◽  
Charge Separation ◽  
High Photocatalytic Activity ◽  
Efficient Charge ◽  
Vital Factor

Efficient charge separation accelerated by a spatial electric field is a vital factor for semiconductor photocatalysts to achieve high photocatalytic activity.

Facile Preparation of P-25 Films Dip-Coated Nickel Foam and High Photocatalytic Activity for the Degradation of Quinoline and Industrial Wastewater

2011 ◽  
Vol 9 (1) ◽  
Author(s):  
Suiyi Zhu ◽  
Xia Yang ◽  
Gu-Ning Wang ◽  
Lei-Lei Zhang ◽  
He-Feng Zhu ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Aqueous Solutions ◽  
Specific Surface ◽  
Continuous Flow ◽  
Industrial Wastewater ◽  
Nickel Foam ◽  
High Photocatalytic Activity ◽  
Photocatalytic Reactor ◽  
X Ray ◽  
Three Phase

A kind of P-25 TiO2 films coated nickel foam was synthesized by a facile dip-coating/calcination route, and used to fabricate a continuous-flow three-phase photocatalytic reactor. The morphology, crystal phase structure, surface composition and specific surface area of P-25 films coated nickel foam were investigated by field emission scanning electron microscope (FE-SEM), X-ray diffractometer (XRD), X-ray photoelectron spectroscopy (XPS) and nitrogen adsorption-desorption measurements, respectively. The results indicated that the coated/ calcined P-25 films had the porous surface structure fabricated by nano-sized titanium dioxide consisted of two crystal phases and incorporated with a NiO interlayer. The increase of P-25 contents enhanced the specific surface area; however, 20 percent of initial P-25 sol would result in visible large cracks because of too high P-25 content and consequently cause the peeling of films. The photocatalytic activities of nickel foam with different coating amounts of P-25 for the degradation of quinoline aqueous solutions were investigated with a continuous-flow three-phase photocatalytic reactor based on the P-25 films coated nickel foam. The results suggested that nickel foam coated with 10 percent of P-25 sol had an optimal photocatalytic activity for the degradation of quinoline aqueous solutions. The continuous-flow three-phase photocatalytic reactor fabricated with P-25 films coated nickel foam with an optimal P-25 coating amount shows high photocatalytic activity and stability for the degradation of quinoline aqueous solutions and industrial wastewater. The treated industrial wastewater meets the international discharge standard.

Facile synthesis of novel Roe-like TiO2 hollow nanospheres with mesoporous cavity for improved photocatalytic activity

2017 ◽  
Vol 10 (03) ◽  
pp. 1750028 ◽  
Author(s):  
Yan Zhu ◽  
Xiaoxia Yan ◽  
Yuanxin Ge ◽  
Shumin Wang ◽  
Dongmei Deng ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Self Assembly ◽  
Charge Separation ◽  
Synergistic Effects ◽  
Assembly Process ◽  
Hollow Nanospheres ◽  
Facile Synthesis

A facile approach was developed to synthesize novel Roe-like TiO2 hollow nanospheres via a template-assisted self-assembly process. These TiO2 nanospheres possessing mesoporous cavity manifest significantly improved photocatalytic activity owing to the synergistic effects of increased charge separation, more efficient use of the light and specific surface area.

Enhancing visible light photocatalytic activity of bismuth vanadate with the loading of zinc oxide

2019 ◽  
Vol 12 (01) ◽  
pp. 1850110 ◽  
Author(s):  
Mengjun Liang ◽  
Lu Chen ◽  
Zhiyuan Yang ◽  
Zhen Zeng ◽  
Shuijin Yang
Keyword(s):  
Zinc Oxide ◽  
Photocatalytic Activity ◽  
Visible Light ◽  
Specific Surface ◽  
Visible Light Irradiation ◽  
Charge Separation ◽  
Facile Hydrothermal Method ◽  
Excellent Photocatalytic Activity ◽  
Efficient Charge ◽  
Visible Light Photocatalytic

ZnO/Bi4V2O[Formula: see text] nanocomposites were prepared via a facile hydrothermal method by loading different amounts of ZnO onto the surface of Bi4V2O[Formula: see text]. The resulting ZnO/Bi4V2O[Formula: see text] composites showed excellent photocatalytic activity than that of pure ZnO under visible light irradiation. When the ratio of ZnO to Bi4V2O[Formula: see text] was 1:1 (ZB2), the photocatalytic activity was best, which could degrade RhB almost completely within 30[Formula: see text]min. The enhanced photocatalytic activity of ZnO/Bi4V2O[Formula: see text] composites could be mainly ascribed to the efficient charge separation and the increased specific surface area. Based on the experimental and bandgap calculations, a possible photocatalytic mechanism was proposed.

ChemInform Abstract: Low-Temperature Solution Route to Molybdenum Nitride.

ChemInform ◽  
2010 ◽  
Vol 30 (5) ◽  
pp. no-no
Author(s):  
Hsin-Tien Chiu ◽  
Shiow-Huey Chuang ◽  
Gene-Hsiang Lee ◽  
Shie-Ming Peng
Keyword(s):  
Low Temperature ◽  
Molybdenum Nitride ◽  
Temperature Solution ◽  
Solution Route
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