Electron transport via phenyl–perfluorophenyl interaction in crystals of fluorine-substituted dibenzalacetones

RSC Advances ◽  
2014 ◽  
Vol 4 (91) ◽  
pp. 50188-50194 ◽  
Author(s):  
Ling Liu ◽  
Guochun Yang ◽  
Yun Geng ◽  
Yong Wu ◽  
Zhongmin Su
Keyword(s):  
Electron Transport ◽  
Charge Transport ◽  
Transport Properties ◽  
Molecular Crystal ◽  
Electronic Materials ◽  
Crystal Packing ◽  
Organic Electronic ◽  
Organic Electronic Materials

Although substitution with fluorine creates stability in organic electronic materials by altering the molecular crystal packing, the charge transport properties of the materials are significantly affected.

Using Automated Synthesis to Understand the Role of Side Chains on Molecular Charge Transport

2021 ◽  
Author(s):  
Songsong Li ◽  
Edward Jira ◽  
Nicholas Angello ◽  
Jialing Li ◽  
Hao Yu ◽  
...  
Keyword(s):  
Charge Transport ◽  
Density Functional ◽  
Electronic Materials ◽  
Side Chain ◽  
Automated Synthesis ◽  
Side Chains ◽  
Full Potential ◽  
Organic Electronic ◽  
Organic Electronic Materials

The development of next-generation organic electronic materials critically relies on understanding structure-function relationships in conjugated polymers. However, unlocking the full potential of organic materials requires access to their vast chemical space while efficiently managing the large synthetic workload to survey new materials. In this work, we use automated synthesis to prepare a library of conjugated oligomers with systematically varied side chain composition followed by single-molecule characterization of charge transport. Our results show that molecular junctions with long alkyl side chains exhibit a concentration-dependent bimodal conductance with an unexpectedly high conductance state that arises due to surface adsorption and backbone planarization, which is supported by a series of control experiments using asymmetric, planarized, and sterically hindered molecules. Density functional theory simulations and experiments using different anchors and alkoxy side chains highlight the role of side chain chemistry on charge transport. Overall, this work opens new avenues for using automated synthesis for the development and understanding of organic electronic materials.

scholarly journals Interfacial Charge Transport in Organic Electronic Materials: the Key to a New Electronics Technology

1999 ◽  
Author(s):  
D.L. Smith ◽  
I.H. Campbell ◽  
P.S. Davids ◽  
C.M. Heller ◽  
B.K. Laurich ◽  
...  
Keyword(s):  
Charge Transport ◽  
Electronic Materials ◽  
Organic Electronic ◽  
Organic Electronic Materials ◽  
Interfacial Charge

scholarly journals Biodegradation of bio-sourced and synthetic organic electronic materials towards green organic electronics

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Eduardo Di Mauro ◽  
Denis Rho ◽  
Clara Santato
Keyword(s):  
Organic Electronics ◽  
Electronic Materials ◽  
Chemical Elements ◽  
Electronic Devices ◽  
Polyphenylene Sulfide ◽  
Environmentally Benign ◽  
Organic Electronic ◽  
Synthetic Materials ◽  
Organic Electronic Materials ◽  
Thermophilic Conditions

AbstractUbiquitous use of electronic devices has led to an unprecedented increase in related waste as well as the worldwide depletion of reserves of key chemical elements required in their manufacturing. The use of biodegradable and abundant organic (carbon-based) electronic materials can contribute to alleviate the environmental impact of the electronic industry. The pigment eumelanin is a bio-sourced candidate for environmentally benign (green) organic electronics. The biodegradation of eumelanin extracted from cuttlefish ink is studied both at 25 °C (mesophilic conditions) and 58 °C (thermophilic conditions) following ASTM D5338 and comparatively evaluated with the biodegradation of two synthetic organic electronic materials, namely copper (II) phthalocyanine (Cu–Pc) and polyphenylene sulfide (PPS). Eumelanin biodegradation reaches 4.1% (25 °C) in 97 days and 37% (58 °C) in 98 days, and residual material is found to be without phytotoxic effects. The two synthetic materials, Cu–Pc and PPS, do not biodegrade; Cu–Pc brings about the inhibition of microbial respiration in the compost. PPS appears to be potentially phytotoxic. Finally, some considerations regarding the biodegradation test as well as the disambiguation of “biodegradability” and “bioresorbability” are highlighted.

Printable Organic Electronic Materials for Precisely Positioned Cell Attachment

Langmuir ◽  
2021 ◽  
Vol 37 (5) ◽  
pp. 1874-1881
Author(s):  
Jeffrey A. Horowitz ◽  
Xiaoyang Zhong ◽  
Samuel J. DePalma ◽  
Maria R. Ward Rashidi ◽  
Brendon M. Baker ◽  
...  
Keyword(s):  
Cell Attachment ◽  
Electronic Materials ◽  
Organic Electronic ◽  
Organic Electronic Materials

scholarly journals Reconfigurable sticker label electronics manufactured from nanofibrillated cellulose-based self-adhesive organic electronic materials

2013 ◽  
Vol 14 (11) ◽  
pp. 3061-3069 ◽  
Author(s):  
Jun Kawahara ◽  
Peter Andersson Ersman ◽  
Xin Wang ◽  
Göran Gustafsson ◽  
Hjalmar Granberg ◽  
...  
Keyword(s):  
Electronic Materials ◽  
Nanofibrillated Cellulose ◽  
Organic Electronic ◽  
Organic Electronic Materials

scholarly journals Fullerene Dissymmetrization as a Means to Achieve Single Enantiomer Electron Acceptors with Maximized Chiroptical Responsiveness

2020 ◽  
Author(s):  
Wenda Shi ◽  
Francesco Salerno ◽  
Alejandro Santana-Bonilla ◽  
Matthew Ward ◽  
Xueyan Hou ◽  
...  
Keyword(s):  
Electronic Materials ◽  
Light Response ◽  
Electron Acceptors ◽  
Fullerene Cage ◽  
Structure Property ◽  
Organic Electronic Devices ◽  
Organic Electronic ◽  
Structure Property Relationships ◽  
Organic Electronic Materials ◽  
Fast Light

<p>Solubilized fullerene derivatives have revolutionised the development of organic photovoltaic devices, acting as excellent electron acceptors. The addition of solubilizing addends to the fullerene cage results in a large number of isomers, which are generally employed as isomeric mixtures. Moreover, a significant number of these isomers are chiral, which further adds to the isomeric complexity. The opportunities presented by single isomer, and particularly single enantiomer, fullerenes in organic electronic materials and devices are poorly understood. Here we separate 10 pairs of enantiomers from the 19 structural isomers of bis[60]PCBM, using them to elucidate important chiroptical structure-property relationships and demonstrating their application to a single enantiomer circularly polarized (CP) light detecting device. We find that larger chiroptical responses occur through inherent chirality of the fullerene cage and particularly through transitions with low CT character. When used in a single enantiomer organic field-effect transistor device, we demonstrate the potential to discriminate CP light with a fast light response time and with a very high photocurrent dissymmetry factor (<i>g<sub>ph</sub></i> = ±1.35). Our study thus provides key strategies to design fullerenes with large chiroptical responses for use as single enantiomer components of organic electronic devices. We anticipate that our data will position chiral fullerenes as an exciting material class for the growing field of chiral electronic technologies.</p>

Sign in / Sign up

Export Citation Format

Share Document