Facile synthesis of Bi2S3–C composite microspheres as low-cost counter electrodes for dye-sensitized solar cells

RSC Advances ◽  
2014 ◽  
Vol 4 (101) ◽  
pp. 57412-57418 ◽  
Author(s):  
Xue-Qin Zuo ◽  
Xiao Yang ◽  
Lei Zhou ◽  
Bo Yang ◽  
Guang Li ◽  
...  

The synergistic effect of the combination of conductive carbon and Bi2S3 can significantly improve the photovoltaic performance of DSSCs.

Materials ◽  
2021 ◽  
Vol 14 (21) ◽  
pp. 6563
Author(s):  
Md. Mahbubur Rahman

Novel nickel nitroprusside (NNP) nanoparticles with incorporated graphene nanoplatelets (NNP/GnP) were used for the first time as a low-cost and effective counter electrode (CE) for dye-sensitized solar cells (DSSCs). NNP was synthesized at a low-temperature (25 °C) solution process with suitable purity and crystallinity with a size range from 5 to 10 nm, as confirmed by different spectroscopic and microscopic analyses. The incorporation of an optimized amount of GnP (0.2 wt%) into the NNP significantly improved the electrocatalytic behavior for the redox reaction of iodide (I-)/tri-iodide (I3-) by decreasing the charge-transfer resistance at the CE/electrolyte interface, lower than the NNP- and GnP-CEs, and comparable to the Pt-CE. The NNP/GnP nanohybrid CE when applied in DSSC exhibited a PCE of 6.13% (under one sun illumination conditions) with the Jsc, Voc, and FF of 14.22 mA/cm2, 0.628 V, and 68.68%, respectively, while the PCE of the reference Pt-CE-based DSSC was 6.37% (Jsc = 14.47 mA/cm2, Voc = 0.635 V, and FF = 69.20%). The low cost of the NNP/GnP hybrid CE with comparable photovoltaic performance to Pt-CE can be potentially exploited as a suitable replacement of Pt-CE in DSSCs.


2017 ◽  
Vol 2017 ◽  
pp. 1-8
Author(s):  
Saeid Vafaei ◽  
Kazuhiro Manseki ◽  
Soki Horita ◽  
Masaki Matsui ◽  
Takashi Sugiura

We present for the first time a synthetic method of obtaining 1D TiO2 nanorods with sintering methods using bundle-shaped 3D rutile TiO2 particles (3D BR-TiO2) with the dimensions of around 100 nm. The purpose of this research is (i) to control crystallization of the mixture of two kinds of TiO2 semiconductor nanocrystals, that is, 3D BR-TiO2 and spherical anatase TiO2 (SA-TiO2) on FTO substrate via sintering process and (ii) to establish a new method to create photoanodes in dye-sensitized solar cells (DSSCs). In addition, we focus on the preparation of low-cost and environmentally friendly titania electrode by adopting the “water-based” nanofluids. Our results provide useful guidance on how to improve the photovoltaic performance by reshaping the numerous 3D TiO2 particles to 1D TiO2-based electrodes with sintering technique.


2012 ◽  
Vol 65 (9) ◽  
pp. 1203 ◽  
Author(s):  
Qianqian Li ◽  
Zhongxing Jiang ◽  
Jingui Qin ◽  
Zhen Li

Due to their high conversion efficiency and low cost of production, dye-sensitized solar cells based on organic dyes have attracted considerable attention. By utilizing various heterocycles as construction blocks for organic dyes, the performance of solar cells was optimized to exhibit good light-harvesting features and suppress interfacial recombinations. The aim of this review is to highlight recent progress in the molecular design of heterocyclic-functionalized organic dyes for efficient dye-sensitized solar cells, and special attention has been paid to the relationship between chemical structure and the photovoltaic performance of dye-sensitized solar cells based on these dyes.


2016 ◽  
Vol 2016 ◽  
pp. 1-13 ◽  
Author(s):  
F. M. Al-Marzouki ◽  
S. Abdalla ◽  
S. Al-Ameer

Dye sensitized solar cells (DSSCs) are very sensitive to electrodes, due to either high cost or easy corrosion problems. To minimize these factors, we present DSSCs with cheap carbon nanotubes as counter electrodes. In addition, we suggest replacing the electrolyte (in typical DSSCs) with a solid film of powdered CsSnI3. The electrical behavior (I-Vcharacteristics) of the proposed device has been measured for different shading conditions. In the light of a theoretical model based on the presence of two diodes, the experimental data have been explained, taking into account a new equivalent circuit for the DSSC. These DSSCs may receive different levels of sun radiation, which stimulates the study of partial shading; so, we have studied the effect of different shadow rates on the solar conversion efficiency of a unit of 4-W-connected DSSCs. The validity of the present model has been examined by fitting it intoI-Vcharacteristics at different shading rates.


2013 ◽  
Vol 29 (11) ◽  
pp. 2339-2344 ◽  
Author(s):  
ZHU Lei ◽  
◽  
QIANG Ying-Huai ◽  
ZHAO Yu-Long ◽  
GU Xiu-Quan ◽  
...  

2020 ◽  
Vol 4 (7) ◽  
pp. 3604-3612
Author(s):  
Haifeng Xu ◽  
Zhong Jin

The rational design of high-performance yet low-cost counter electrodes (CEs) with exceptional catalytic activity for the I−/I3− redox couple and excellent corrosion resistance is of great importance for dye-sensitized solar cells (DSSCs).


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